1,3-Bis(3-aminopropyl)tetramethyldisiloxane

1,3-Bis(3-aminopropyl)tetramethyldisiloxane 구조식 이미지
카스 번호:
2469-55-8
상품명:
1,3-Bis(3-aminopropyl)tetramethyldisiloxane
동의어(영문):
1,3-BIS(3-AMINOPROPYL)-1,1,3,3-TETRAMETHYLDISILOXANE;1,3-Bis(3-aminopropyl)-1,1,3,3-tetramethyldislloxane;b1710;DK236;DK694;ar96447;DKFELEX0177;Amino Capper;BIS(AMINOPROPYL)TETRA;oxybis((3-aminopropyl)dimethyl-silan
CBNumber:
CB2364269
분자식:
C10H28N2OSi2
포뮬러 무게:
248.51
MOL 파일:
2469-55-8.mol
MSDS 파일:
SDS

1,3-Bis(3-aminopropyl)tetramethyldisiloxane 속성

끓는 점
132 °C11 mm Hg(lit.)
밀도
0.901 g/mL at 20 °C(lit.)
증기압
0.27Pa at 20℃
굴절률
n20/D 1.451
인화점
91°C
저장 조건
Inert atmosphere,2-8°C
물리적 상태
투명한 액체
산도 계수 (pKa)
10.96±0.10(Predicted)
Specific Gravity
0.897
색상
Colorless to Light yellow to Light orange
수용성
물에 약간 용해됩니다.
감도
Air Sensitive
Hydrolytic Sensitivity
4: no reaction with water under neutral conditions
BRN
1760876
InChIKey
GPXCORHXFPYJEH-UHFFFAOYSA-N
LogP
1.3 at 20℃
CAS 데이터베이스
2469-55-8(CAS DataBase Reference)
EPA
1-Propanamine, 3,3'-(1,1,3,3-tetramethyl-1,3-disiloxanediyl)bis- (2469-55-8)
안전
  • 위험 및 안전 성명
  • 위험 및 사전주의 사항 (GHS)
위험품 표기 C
위험 카페고리 넘버 34
안전지침서 26-28-36/37/39-45-36/37/38
유엔번호(UN No.) UN 3267 8/PG 2
WGK 독일 3
RTECS 번호 JM9235000
F 고인화성물질 10-21
TSCA Yes
위험 등급 8
포장분류 III
HS 번호 29319090
독성 LD50 ipr-mus: 80 mg/kg RCRVAB 38,975,69
기존화학 물질 KE-33582
그림문자(GHS): GHS hazard pictograms
신호 어: Danger
유해·위험 문구:
암호 유해·위험 문구 위험 등급 범주 신호 어 그림 문자 P- 코드
H227 가연성 액체 인화성 액체 구분 4 경고 P210, P280, P370+P378, P403+P235,P501
H314 피부에 심한 화상과 눈에 손상을 일으킴 피부부식성 또는 자극성물질 구분 1A, B, C 위험 GHS hazard pictograms P260,P264, P280, P301+P330+ P331,P303+P361+P353, P363, P304+P340,P310, P321, P305+ P351+P338, P405,P501
예방조치문구:
P210 열·스파크·화염·고열로부터 멀리하시오 - 금연 하시오.
P260 분진·흄·가스·미스트·증기·...·스프레이를 흡입하지 마시오.
P264 취급 후에는 손을 철저히 씻으시오.
P264 취급 후에는 손을 철저히 씻으시오.
P280 보호장갑/보호의/보안경/안면보호구를 착용하시오.
P303+P361+P353 피부(또는 머리카락)에 묻으면 오염된 모든 의복은 벗거나 제거하시오 피부를 물로 씻으시오/샤워하시오.
P305+P351+P338 눈에 묻으면 몇 분간 물로 조심해서 씻으시오. 가능하면 콘택트렌즈를 제거하시오. 계속 씻으시오.
P370+P378 화재 시 불을 끄기 위해 (Section 5. 폭발, 화재시 대처방법의 적절한 소화제)을(를) 사용하시오.
P403+P235 환기가 잘 되는 곳에 보관하고 저온으로 유지하시오.
P405 밀봉하여 저장하시오.
P501 ...에 내용물 / 용기를 폐기 하시오.
NFPA 704
2
3 0

1,3-Bis(3-aminopropyl)tetramethyldisiloxane C화학적 특성, 용도, 생산

화학적 성질

Clear colorless to pale yellow liquid

용도

1,3-Bis(3-aminopropyl)tetramethyldisiloxane is an endcapper for the synthesis of aminopropyl-terminated silicone fluids and for the production of silicone-epoxy and silicone polyimide copolymers especially useful in electronics applications. A unique manufacturing process insures that It has only gamma - aminopropyl substitution and none of the beta isomer. This is expected to give better reactivity in copolymer synthesis and improved heat stability.
1,3-Bis(3-aminopropyl)tetramethyldisiloxane is an alkaline material due to its amine reactive groups. Care should be exercised in handling it to prevent contact with skin and eyes. Wear safety glasses with side shields and rubber gloves when handling.

생산 방법

A glass flask with a stirrer, reflux condenser, thermometer, and dropping funnel was charged with N, N-bis(trimethylsilyl)allylamine. A 4% isopropyl alcohol solution of H2 PtCl6.6H2 O. From the funnel, dimethyl ethoxy silane was added dropwise to the flask at 70° C. over 3 hours for hydrosilylation reaction. The reaction solution was ripened for one hour at the temperature. After adding ethanol and dodecylbenzenesulfonic acidd, the reaction solution was refluxed for 6 hours, completing the desilylation reaction. The reaction solution was transferred to a distillation apparatus where the ethanol and trimethyl ethoxy silane were distilled under atmospheric pressure. Water was added to the remainder, which was refluxed for 2 hours. Vacuum distillation was then carried out to collect 1,3-Bis(3-aminopropyl)tetramethyldisiloxane.

Safety Profile

Poison by intraperitoneal route. When heated to decomposition it emits toxic vapors of NOx.

1,3-Bis(3-aminopropyl)tetramethyldisiloxane 준비 용품 및 원자재

원자재

준비 용품


1,3-Bis(3-aminopropyl)tetramethyldisiloxane 공급 업체

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