디클로로(1,4-)-2-부텐 C화학적 특성, 용도, 생산
화학적 성질
The 1,4-dichloro-2-butenes are colorless
liquids. Some have a distinct odor. (cis-isomer)
일반 설명
A clear colorless liquid. Burns, though may be difficult to ignite. Corrosive to tissue. Denser than water and insoluble in water. Vapors heavier than air. Used to make other chemicals.
공기와 물의 반응
Highly flammable. Reacts slowly with water to form hydrochloric acid. Insoluble in water.
반응 프로필
Halogenated unsaturated aliphatic compounds, such as TRANS-1,4-DICHLORO-2-BUTENE, are moderately or very reactive. Reactivity generally decreases with increased degree of substitution of halogen for hydrogen atoms. Low molecular weight haloalkanes are highly flammable and can react with some metals to form dangerous products. Materials in this group are incompatible with strong oxidizing and reducing agents. Also, they are incompatible with many amines, nitrides, azo/diazo compounds, alkali metals, and epoxides.
건강위험
Inhalation of vapor irritates nose and throat. Contact with eyes causes intense irritation and tears. Contact of liquid with skin causes severe blistering and dermatitis. Ingestion causes severe irritation of mouth and stomach.
화재위험
Special Hazards of Combustion Products: Decomposition vapors contain phosgene and hydrogen chloride gases; both are toxic and irritating.
화학 반응
Reactivity with Water Reacts slowly to form hydrochloric acid; Reactivity with Common Materials: Corrodes metal when wet; Stability During Transport: Stable; Neutralizing Agents for Acids and Caustics: Not pertinent; Polymerization: Not pertinent; Inhibitor of Polymerization: Not pertinent.
Safety Profile
Confirmed carcinogen
with experimental carcinogenic and
neoplastigenic data. Poison by ingestion,
inhalation, and intravenous routes.
Moderately toxic by skin contact. An experimental teratogen. Other experimental
reproductive effects. Mutation data
reported. A severe skin and eye irritant.
When heated to decomposition it emits
toxic fumes of Cl-. See also
CHLORINATED HYDROCARBONS,
ALIPHATIC .
잠재적 노출
DC occurs as a by-product in chloroprene manufacture and may be used as a chemical
intermediate
운송 방법
UN3384 Toxic by inhalation liquid, flammable, n.
o.s. with an LC50 ≦ 1000 ml/m3 and saturated vapor
concentration ≧to 10 LC50, Hazard class: 6.1; Labels:
6.1-Poisonous materials, 3-Flammable liquid, Technical Name
Required, Inhalation Hazard Zone B. UN2920 Corrosive
liquids, flammable, n.o.s., Hazard class: 8; Labels: 8-Corrosive
material, 3-Flammable liquid. The code “D” identifies proper
shipping names which are appropriate for
describing materials for domestic transportation but may be
inappropriate for international transportation under the provisions of international regulations, e.g., IMO, ICAO). An alternate proper shipping name may be selected when either
domestic or international transportation is involved
비 호환성
Vapors may form explosive mixture
with air. Incompatible with oxidizers (chlorates, nitrates, peroxides, permanganates, perchlorates, chlorine, bromine, fluorine, etc.); contact may cause fires or explosions. Keep away
from alkaline materials, strong bases, strong acids, oxoacids,
and epoxides. (cis-isomer): Reacts slowly with water forming hydrogen chloride. Attacks metals and may form other,
more dangerous materials; attacks some plastics.
폐기물 처리
High-temperature incineration
with hydrochloric acid scrubbing. Consult with environmental regulatory agencies for guidance on
acceptable disposal practices. Generators of waste containing this contaminant (≥100 kg/mo) must conform with
EPA regulations governing storage, transportation, treatment, and waste disposal.
디클로로(1,4-)-2-부텐 준비 용품 및 원자재
원자재
준비 용품
