tigloidine

tigloidine 구조식 이미지
카스 번호:
495-83-0
상품명:
tigloidine
동의어(영문):
Tigloidin;Tiglyssin;tigloidine;Tigloyltropine;Tigloyltropeine;Tiglylpseudotropine;3α-Tigloyloxytropane;Tigloyl pseudotropine;2-Methylcrotonic acid (1R,5S)-tropan-3β-yl ester;2-Butenoic acid, 2-methyl-, (3-exo)-8-methyl-8-azabicyclo[3.2.1]oct-3-yl ester, (2E)-
CBNumber:
CB2898322
분자식:
C13H21NO2
포뮬러 무게:
223.314
MOL 파일:
495-83-0.mol

tigloidine 속성

끓는 점
290.2±33.0 °C(Predicted)
밀도
1.06±0.1 g/cm3(Predicted)
저장 조건
Store at -20°C
용해도
Soluble in Chloroform,Dichloromethane,Ethyl Acetate,DMSO,Acetone,etc.
물리적 상태
기름
산도 계수 (pKa)
10.03±0.40(Predicted)
색상
Light yellow to yellow

안전

tigloidine C화학적 특성, 용도, 생산

개요

A tropine alkaloid isolated from Duboisia rnyoporoides, this base is a colourless syrup which yields crystalline salts. The hydrobromide forms colourless, tabular crystals m.p. 234-5°C and is optically inactive; the aurichloride crystallizes as yellow plates, m.p. 213.5- 2140 C; the picrate as yellow rectangular plates, m.p. 239°C and the methiodide as square plates, m.p. 244-5°C. The alkaloid is unsaturated and the hydro bromide, on hydrogenation, furnishes dihydrotigloidine, giving a picrate, m.p. l34-5°C. When treated with bromine in CHC13 it forms dibromodihydrotigloidine, m.p. 187°C (dec.). The free base may be hydrolyzed by boiling with H20 when it furnishes pseudotropine and tiglic acid. The base is therefore the tiglyl ester of pseudotropine. By comparison, tiglyltropine gives a hydrobromide with m.p. 207°C and a picrate, m.p. 200°C.

참고 문헌

Barger, Martin, Mitchel1.,J. Chern. Soc., 1820 (1937)

tigloidine 준비 용품 및 원자재

원자재

준비 용품


tigloidine 공급 업체

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