아크릴로일 모폴린
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아크릴로일 모폴린 속성
- 녹는점
- −35 °C(lit.)
- 끓는 점
- 158°C 50mm
- 밀도
- 1.122 g/mL at 25 °C(lit.)
- 증기압
- 1.03-1.64Pa at 25-29.9℃
- 굴절률
- n
20/D 1.512(lit.)
- 인화점
- >230 °F
- 저장 조건
- 2-8°C
- 용해도
- 물에 용해됨
- 물리적 상태
- 액체
- 산도 계수 (pKa)
- -1.08±0.20(Predicted)
- 색상
- 무색~황색
- 수용성
- 1000g/L at 20℃
- 감도
- Light Sensitive
- BRN
- 119302
- InChIKey
- XLPJNCYCZORXHG-UHFFFAOYSA-N
- LogP
- -0.46 at 20.5-21℃
- CAS 데이터베이스
- 5117-12-4(CAS DataBase Reference)
안전
- 위험 및 안전 성명
- 위험 및 사전주의 사항 (GHS)
위험품 표기 | Xn | ||
---|---|---|---|
위험 카페고리 넘버 | 22-41-43-48/22 | ||
안전지침서 | 23-26-36/37/39 | ||
WGK 독일 | 2 | ||
TSCA | Yes | ||
HS 번호 | 29349990 | ||
기존화학 물질 | 2000-3-1524 |
아크릴로일 모폴린 C화학적 특성, 용도, 생산
용도
접착제, 자외선 경화 수지, 산업용 코팅, UV 인쇄 잉크, 오일 회수 폴리머, 의약 및 필수 화학 물질에 사용됩니다.화학적 성질
4-Acryloylmorpholine has a melting point of ?35 °C and is clear liquid at room temperature. At 25 °C, it has a density of 1.122 g/mL. It needs to be stored at 2-8°C.용도
4-Acryloylmorpholine is used in adhesives, UV curable resins, industrial coatings, UV printing ink, oil recovery polymer, medicinal and commodity chemicals.화학 반응
Using cobalt catalysis, diethylzinc promotes the conjugate reduction of 4-acryloylmorpholine to produce the corresponding ethylzinc enolate, which reacts with N-tosyl aldimines to afford β-aminoamides[1].![4-Acryloylmorpholine reaction 4-Acryloylmorpholine reaction](/NewsImg/2024-05-13/6385119040363662756110858.png)
Synthesis
A solution of 0.04 mol of the corresponding amine in 20 ml of anhydrous methylene chloride was slowly added at 0-5??C to 0.02 mol of acryloyl chloride in 20 ml of anhydrous methylene chloride. The mixture was stirred for 3 h at room temperature in an inert atmosphere, and the precipitate was filtered off and washed with methylene chloride (2 ?á 10 ml). The organic layer was washed in succession with 5 ml of water and 5 ml of a saturated solution of NaHCO3 and dried over Na2SO4, the solvent was removed under reduced pressure, and the residue was purified by column chromatography on silica gel using hexane-ethyl acetate (5 : 1 to 1 : 1) as eluent. 4-Acryloylmorpholine, Yield 1.78 g (63%). IR spectrum, |í, cm-1: 2857, 1647, 1612, 1439, 1263, 1238, 1115, 1038, 953. 1H NMR spectrum, |?, ppm: 3.51-3.73 m (8H, NCH2CH2O), 5.72 d.d (1H, 3-Hcis, 3J = 10.6, 2J = 1.9 Hz), 6.29 d.d (1H, 3-Htrans, 3J = 16.7, 2J = 1.9 Hz), 6.57 d.d (1H, 2-H, J = 16.7, 10.6 Hz). 13C NMR spectrum, |?C, ppm: 41.74 and 45.66 (CH2N), 66.22 (CH2O), 126.64 (C2), 127.69 (C3), 164.92 (C1). Mass spectrum, m/z (Irel, %): 141 (36) [M]+, 140 (12), 126 (58), 112 (22), 111 (15), 110 (15), 109 (12), 98 (10), 96 (26), 86 (72), 83 (13), 70 (14), 68 (14), 57 (17), 56 (86), 55 (100), 42 (23).![Synthesis_5117-12-4](https://www.chemicalbook.com/NewsImg/2022-10-10/6380099097699065725248702.jpg)
아크릴로일 모폴린 준비 용품 및 원자재
원자재
준비 용품
아크릴로일 모폴린 공급 업체
글로벌( 290)공급 업체
공급자 | 전화 | 이메일 | 국가 | 제품 수 | 이점 |
---|---|---|---|---|---|
Anhui Royal Chemical Co., Ltd. | +86-25-86655873 +8613962173137 |
marketing@royal-chem.com | China | 189 | 55 |
Gansu Jinyuantai New Material Co., Ltd. | +86-025-86618065 +86-13914714331 |
sales@jinyuantaichem.com | China | 73 | 58 |
Yancheng Green Chemicals Co.,Ltd | +undefined-86-25-86655873 |
info@royal-chem.com | China | 114 | 58 |
Qingdao RENAS Polymer Material Co., Ltd. | +86-0532-86867058 +86-18562606086 |
sales@qdrenas.com | China | 190 | 58 |
Hebei Guanlang Biotechnology Co,.LTD | +8619930503252 |
daisy@crovellbio.com | China | 5828 | 58 |
Shaanxi Haibo Biotechnology Co., Ltd | +undefined18602966907 |
qinhe02@xaltbio.com | China | 1000 | 58 |
Hebei Zhuanglai Chemical Trading Co.,Ltd | +8613343047651 |
admin@zlchemi.com | China | 3002 | 58 |
Shandong Deshang Chemical Co., Ltd. | +86-0531-8875-2665 +8613153039501 |
info@deshangchem.com | China | 619 | 58 |
Capot Chemical Co.,Ltd. | 571-85586718 +8613336195806 |
sales@capotchem.com | China | 29798 | 60 |
Henan Tianfu Chemical Co.,Ltd. | +86-0371-55170693 +86-19937530512 |
info@tianfuchem.com | China | 21668 | 55 |
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AURORA 1080
SALOR-INT L202282-1EA
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