이소프탈산

이소프탈산
이소프탈산 구조식 이미지
카스 번호:
121-91-5
한글명:
이소프탈산
동의어(한글):
이소프탈산;아이소프탈산;아이소프탈산;m-벤젠다이카르복실 산;m-프탈 산;벤젠-1,3-다이카르복실 산;아이소프탈 산
상품명:
Isophthalic acid
동의어(영문):
1,3-BENZENEDICARBOXYLIC ACID;Isophthalic;isophthalate;M-PHTHALIC ACID;1,3-phthalicacid;1,3-dicarboxybenzene;IPA)Isophthalic;sophthalic acid;ISOPHTHALIC ACID;META-PHTHALICACID
CBNumber:
CB3262667
분자식:
C8H6O4
포뮬러 무게:
166.13
MOL 파일:
121-91-5.mol
MSDS 파일:
SDS

이소프탈산 속성

녹는점
341-343 °C (lit.)
끓는 점
214.32°C (rough estimate)
밀도
1,54 g/cm3
증기압
0Pa at 25℃
굴절률
1.5100 (estimate)
저장 조건
Sealed in dry,Room Temperature
용해도
0.12g/L
산도 계수 (pKa)
3.54(at 25℃)
물리적 상태
결정성 분말
색상
흰색에서 황백색까지
수소이온지수(pH)
3.33(1 mM solution);2.76(10 mM solution);2.24(100 mM solution)
수용성
0.01 g/100 mL (25 ºC)
Merck
14,5197
BRN
1909332
Dielectric constant
1.4(Ambient)
안정성
안정적인. 강한 산화제, 강한 염기와 호환되지 않습니다.
InChIKey
QQVIHTHCMHWDBS-UHFFFAOYSA-N
LogP
1.66 at 25℃
CAS 데이터베이스
121-91-5(CAS DataBase Reference)
NIST
1,3-Benzenedicarboxylic acid(121-91-5)
EPA
Isophthalic acid (121-91-5)
안전
  • 위험 및 안전 성명
  • 위험 및 사전주의 사항 (GHS)
위험품 표기 Xi
위험 카페고리 넘버 36/37/38
안전지침서 24/25-36-26
WGK 독일 2
RTECS 번호 NT2007000
자연 발화 온도 1198 °F
TSCA Yes
HS 번호 29173980
유해 물질 데이터 121-91-5(Hazardous Substances Data)
기존화학 물질 KE-02189
그림문자(GHS): GHS hazard pictograms
신호 어: Warning
유해·위험 문구:
암호 유해·위험 문구 위험 등급 범주 신호 어 그림 문자 P- 코드
H315 피부에 자극을 일으킴 피부부식성 또는 자극성물질 구분 2 경고 GHS hazard pictograms P264, P280, P302+P352, P321,P332+P313, P362
H319 눈에 심한 자극을 일으킴 심한 눈 손상 또는 자극성 물질 구분 2A 경고 GHS hazard pictograms P264, P280, P305+P351+P338,P337+P313P
H335 호흡 자극성을 일으킬 수 있음 특정 표적장기 독성 - 1회 노출;호흡기계 자극 구분 3 경고 GHS hazard pictograms
예방조치문구:
P261 분진·흄·가스·미스트·증기·...·스프레이의 흡입을 피하시오.
P305+P351+P338 눈에 묻으면 몇 분간 물로 조심해서 씻으시오. 가능하면 콘택트렌즈를 제거하시오. 계속 씻으시오.
NFPA 704
0
0 0

이소프탈산 MSDS


1,3-Benzenedicarboxylic acid

이소프탈산 C화학적 특성, 용도, 생산

개요

Isophthalic acid is an organic compound with the formula C6H4(CO2H)2. This colourless solid is an isomer of phthalic acid and terephthalic acid. These aromatic dicarboxylic acids are used as precursors (in form of acyl chlorides) to commercially important polymers, e.g. the fire-resistant material Nomex. Mixed with terephthalic acid, iso phthalic acid is used in the production of resins for drink bottles. The high-performance polymer poly benzimidazole is produced from iso phthalic acid.

화학적 성질

Isophthalic acid is a white crystalline powder or needle-like crystals and it’s an isomer of phthalic acid and terephthalic acid.It is insoluble in cold water but soluble in oxygenated solvents and alcohol. It is combustible and finely dispersed particles will form explosive mixtures in air.
Isophthalic acid
Isophthalic Acid (PIA) is mainly used in the production of bottle PET, also used in the production of alkyd resin, polyester resin, also used in the production of photosensitive materials, pharmaceutical intermediates and so on.
One of the largest applications for PIA is in unsaturated polyester resins for high-quality gel coats. The hardness, stain and detergent resistance characteristics of PIA are ideal for polyester solid-surface countertops that are an inexpensive alternative to acrylics.

용도

Purified Isophthalic Acid (PIA) is mainly used as intermediate for high performance UPR, resins for coatings, high solids paints, gel coats, modifier of PET for bottles. Product Data Sheet

제조 방법

Iso phthalic acid is produced on the billion kilogram per year scale by oxidizing meta-xylene using oxygen . The process employs a cobalt-manganese catalyst. In the laboratory, chromic acid can be used as the oxidant. It also arises by fusing potassium meta-sulpho benzoate , or meta - brom benzoate with potassium formate (terephthalic acid is also formed in the last case).
The barium salt (as its hexa hydrate) is very soluble (a distinction between phthalic and terephthalic acids). Uvitic acid, 5- methylisophthalic acid, is obtained by oxidizing mesitylene or by condensing pyroracemic acid with baryta water.

정의

ChEBI: A benzenedicarboxylic acid that is benzene substituted by carboxy groups at position 1 and 3. One of three possible isomers of benzenedicarboxylic acid, the others being phthalic and terephthalic acids.

일반 설명

White solid with a slight unpleasant odor. Sinks in water.

공기와 물의 반응

Dust forms explosive mixture in air [USCG, 1999].

건강위험

May cause slight to moderate irritation of eyes, skin, and mucous membranes on prolonged contact. Ingestion may cause gastrointestinal irritation.

화재위험

Behavior in Fire: Dust forms explosive mixture in air.

Purification Methods

Crystallise the acid from aqueous EtOH. [Beilstein 9 IV 3292.]

이소프탈산 준비 용품 및 원자재

원자재

준비 용품


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