2,3-디클로로-1,4-나프토퀴논
|
|
2,3-디클로로-1,4-나프토퀴논 속성
- 녹는점
- 194-197 °C (lit.)
- 끓는 점
- 275 °C (2 mmHg)
- 밀도
- 1.4057 (rough estimate)
- 증기압
- 0Pa at 20℃
- 굴절률
- 1.5410 (estimate)
- 인화점
- 275°C/2mm
- 저장 조건
- Store below +30°C.
- 물리적 상태
- 미세 결정성 분말
- 색상
- 노란색
- 수용성
- 0.008g/L
- Merck
- 14,3045
- BRN
- 1073511
- LogP
- 2.9 at 23℃
- CAS 데이터베이스
- 117-80-6(CAS DataBase Reference)
안전
- 위험 및 안전 성명
- 위험 및 사전주의 사항 (GHS)
위험품 표기 | Xn,N | ||
---|---|---|---|
위험 카페고리 넘버 | 22-36/38-50/53 | ||
안전지침서 | 26-60-61 | ||
유엔번호(UN No.) | UN 2811 6.1/PG 3 | ||
WGK 독일 | 3 | ||
RTECS 번호 | QL7525000 | ||
TSCA | Yes | ||
위험 등급 | 6.1 | ||
포장분류 | III | ||
HS 번호 | 29147090 | ||
유해 물질 데이터 | 117-80-6(Hazardous Substances Data) | ||
독성 | LD50 orally in rats: 1300 mg/kg (Bailey, White) | ||
기존화학 물질 | KE-10157 |
2,3-디클로로-1,4-나프토퀴논 C화학적 특성, 용도, 생산
화학적 성질
YELLOW FINE CRYSTALLINE POWDER용도
Fungicide for agriculture and textiles; herbicide.일반 설명
2,3-Dichloro-1,4-naphthoquinone is a yellow crystalline solid dissolved in a water-emulsifiable liquid carrier. Can cause illness by inhalation, skin absorption and/or ingestion. The primary hazard is the threat to the environment. Immediate steps should be taken to limit its spread to the environment. Can easily penetrate the soil and contaminate groundwater and nearby streams. Used as a fungicide.공기와 물의 반응
Insoluble in water.반응 프로필
2,3-Dichloro-1,4-naphthoquinone is a halogenated ketone. Ketones are reactive with many acids and bases liberating heat and flammable gases (e.g., H2). The amount of heat may be sufficient to start a fire in the unreacted portion of the ketone. Ketones react with reducing agents such as hydrides, alkali metals, and nitrides to produce flammable gas (H2) and heat. Ketones are incompatible with isocyanates, aldehydes, cyanides, peroxides, and anhydrides. They react violently with aldehydes, HNO3, HNO3 + H2O2, and HClO4.건강위험
INHALATION: Irritation to mucous membrane. EYES: Irritation. SKIN: Irritation. INGESTION: Can cause CNS depression.화재위험
Special Hazards of Combustion Products: Highly toxic fumes are imminent.농업용
Fungicide: Not currently registered in the U.S. Not approved for use in the EU. Dichlone is used as a fungicide for foliage and to control blue algae in ponds, swimming pools and lakes. As a substitute for copper and sulfur to control rot on fruit trees, vegetables, field crops, ornamentals, resident and commercial outdoor areas.상품명
ALGISTAT®; COMPOUND 604®; PHYGON®; PHYGON® PASTE; PHYGON® SEED PROTECTANT; PHYGON® XL; QUINTAR®; QUINTAR® 540F; SANQUINON®; UNIROYAL® 604; USR® 604; U.S. RUBBER® 604Safety Profile
Poison by ingestion and intraperitoneal routes. Mildly toxic by skin contact. A skin, eye, and mucous membrane irritant. Large doses can cause central nervous system depression. Questionable carcinogen with experimental carcinogenic and neoplastigenic data. A fungcide and algicide. When heated to decomposition it emits toxic fumes of Cl-. See also CHLORIDES.환경귀착
Plant. In plants, dichlone loses both chlorine atoms and are replaced by sulphydryl groups to give a substituted dimercapto compound (Hartley and Kidd, 1987).Photolytic. The UV absorption band for dichlone is 330 nm (Gore et al., 1971). Irradiation of dichlone in a variety of organic solvents (benzene, isopropanol, ethanol) using UV light produced a number of dehalogenated compounds. In the absence or presence of oxygen, 2-chloro-1,4-naphthoquinone, 1,4-naphthoquinone and 1,4-naphthalenediol were produced. Further irradiation in the presence of oxygen yielded phthalic acid and phthalic anhydride as the major products. In a mixture of benzene and isopropanol, dichlone degraded to the minor products: 2-chloro-3-hydroxy-1,4-naphthoquinone, 2- chloro-3-phenoxy-1,4-naphthoquinone, 2,3-dichloro-4-hydroxy-1-keto-2-phenyl-1,2- dihydronaphthalene and isopropyl-1-chloro-2,3-dioxo-1-indanecarboxylate (Ide et al., 1979).
Chemical/Physical. Emits toxic fumes of chlorine when heated to decomposition (Sax and Lewis, 1987).
Purification Methods
Crystallise the quinone from EtOH. [Beilstein 7 IV 2426.]2,3-디클로로-1,4-나프토퀴논 준비 용품 및 원자재
원자재
발연황산
dilute sulphuric acid
염화제이철무수물
Naphthionic acid
1,4-나프토퀴논
브롬
철분
M-디니트로벤젠
1,4-Naphthalenedione,2,3-dichloro-2,3-dihydro-
9,10-디메톡시안트라센
2-Chloro-1,4-naphthoquinone
준비 용품
2,3-디클로로-1,4-나프토퀴논 공급 업체
글로벌( 284)공급 업체
공급자 | 전화 | 이메일 | 국가 | 제품 수 | 이점 |
---|---|---|---|---|---|
Hebei Guanlang Biotechnology Co,.LTD | +8619930503252 |
daisy@crovellbio.com | China | 5828 | 58 |
Henan Tianfu Chemical Co.,Ltd. | +86-0371-55170693 +86-19937530512 |
info@tianfuchem.com | China | 21668 | 55 |
career henan chemical co | +86-0371-86658258 +8613203830695 |
sales@coreychem.com | China | 29894 | 58 |
SHANDONG ZHI SHANG CHEMICAL CO.LTD | +86 18953170293 |
sales@sdzschem.com | China | 2931 | 58 |
Hubei Jusheng Technology Co.,Ltd. | 18871490254 |
linda@hubeijusheng.com | CHINA | 28180 | 58 |
Xiamen AmoyChem Co., Ltd | +86-592-6051114 +8618959220845 |
sales@amoychem.com | China | 6387 | 58 |
Hubei xin bonus chemical co. LTD | 86-13657291602 |
linda@hubeijusheng.com | CHINA | 22968 | 58 |
Chongqing Chemdad Co., Ltd | +86-023-6139-8061 +86-86-13650506873 |
sales@chemdad.com | China | 39916 | 58 |
Alchem Pharmtech,Inc. | 8485655694 |
sales@alchempharmtech.com | United States | 63711 | 58 |
CONIER CHEM AND PHARMA LIMITED | +8618523575427 |
sales@conier.com | China | 49391 | 58 |
2,3-디클로로-1,4-나프토퀴논 관련 검색:
1,4-나프토퀴논 2,3-디클로로-1,4-나프토퀴논
2,3-DICHLORO-5-NITRO-1,4-NAPHTHOQUINONE
2,3-DICHLORO-6-NITRO-1,4-NAPHTHOQUINONE
2,3-DICHLORO-5,8-DIHYDROXY-1,4-NAPHTHOQUINONE
6,7-Dichloro-1,4-naphthoquinone
5,6-Dichloro-1,4-naphthoquinone
2,6-Dichloro-1,4-naphthoquinone
Dichloro-1,4-naphthoquinone
2,7-Dichloro-1,4-naphthoquinone
2,8-Dichloro-1,4-naphthoquinone
5,8-Dichloro-1,4-naphthoquinone
2,5-Dichloro-1,4-naphthoquinone
1,5-DICHLORO-2,6-NAPHTHOQUINONE
3,4-DICHLORO-[1,2]NAPHTHOQUINONE
RARECHEM BW GC 0014
RARECHEM BW GA 0111
RARECHEM BW GC 0036