이소샤프롤
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이소샤프롤 속성
- 녹는점
- 7.5°C
- 끓는 점
- 77-86 °C3.5 mm Hg(lit.)
- 밀도
- 1.12 g/mL at 25 °C(lit.)
- 굴절률
- n
20/D 1.573(lit.)
- 인화점
- >230 °F
- 저장 조건
- Store at -20°C
- 용해도
- insoluble in H2O; ≥76.4 mg/mL in EtOH; ≥8.8 mg/mL in DMSO
- 물리적 상태
- 기름
- 색상
- 노란색
- 냄새
- 디프로필렌 글리콜 중 10.00%. 달콤한 사사프라스 매콤
- ?? ??
- 매운
- Merck
- 13,5244
- Dielectric constant
- 3.4（21℃）
- LogP
- 3.344 (est)
- CAS 데이터베이스
- 120-58-1(CAS DataBase Reference)
- IARC
- 3 (Vol. 10, Sup 7) 1987
안전
- 위험 및 안전 성명
- 위험 및 사전주의 사항 (GHS)
| 위험품 표기 | Xn | ||
|---|---|---|---|
| 위험 카페고리 넘버 | 22-38 | ||
| 안전지침서 | 36 | ||
| WGK 독일 | 3 | ||
| RTECS 번호 | DA5950000 | ||
| HS 번호 | 29329100 | ||
| 유해 물질 데이터 | 120-58-1(Hazardous Substances Data) | ||
| 독성 | LD50 oral in rat: 1340mg/kg | ||
| 기존화학 물질 | KE-29737 |
이소샤프롤 C화학적 특성, 용도, 생산
개요
Isosafrole has an anise odor. It may be synthesized by alkaline isomerization of safrole using KOH at the boil or an alcoholic NaOH solution at room temperature under pressure.화학적 성질
Isosafrole has an anise-like odor. Use of isosafrole in foods is not permitted in the United States출처
Of the two isomers (cis- and trans-), the trans-form is the more stable and has been isolated in the pure state, probably occurring in the essential oil of ylang-ylang; it has been identified in the oils of Illicium religiosum and Ligusticum acutilobum Sieb. and Zucc.용도
Manufacture of heliotropin, perfumes, flavors, pesticide synergists.제조 방법
From safrole by treatment with potassium or sodium hydroxide in the dry state or alcoholic solution, under pressure or at atmospheric pressure (Arctander, 1969).일반 설명
Colorless fragrant liquid with odor of anise. Used in small quantities in root beer and sarsaparilla flavors.반응 프로필
ISOSAFROLE may react with strong reducing agents.위험도
Questionable carcinogen.Synthesis
iso-SAFROLE is synthesized from Safrole by treatment with Potassium or Sodium hydroxide in dry state or alcoholic solution, under pressure or at atmospheric pressure.신진 대사
On oxidation, isosafrole gives rise initially to an allyl alcohol and another, unidentified, conjugated alcohol, which are further oxidized to the vinyl ketone and piperonyl acrolein, respectively. Condensation of On oxidation, isosafrole gives rise initially to an allyl alcohol and another, unidentified, conjugated alcohol, which are further oxidized to the vinyl ketone and piperonyl acrolein, respectively. Condensation of the vinyl ketone with an amine would then lead to the formation of tertiary aminomethylenedioxypropiophenones (Mannich bases) (McKinney, Oswald, Fishbein & Walker, 1972).이소샤프롤 준비 용품 및 원자재
원자재
준비 용품
이소샤프롤 관련 검색:
사프롤 메틸렌디옥시벤젠 시클로펜타디엔 3,4-(메틸렌디옥시)시나믹엑시드, 퍼도미난틀리 트렌스 이소샤프롤
2-BROMO-4,5-METHYLENEDIOXYCINNAMIC ACID
3,4-(METHYLENEDIOXY)BENZYLIDENEACETONE
1-(3,4-METHYLENEDIOXYPHENYL)-1-PENTEN-3-ONE
N-OCTYL SULPHOXIDE OF ISOSAFROLE,Isosafrole octyl sulfoxide,isosafrole,octylsulfoxid
Sassafras oil
ETHYL 3-(1,3-BENZODIOXOL-5-YL)-2-CYANOACRYLATE
5-(3,4-METHYLENEDIOXYPHENYL)-2,4-PENTADIENOIC ACID
(BENZO[3,4-D]1,3-DIOXOLAN-5-YLMETHYLENE)METHANE-1,1-DICARBONITRILE
ISOSAFROLE SOLUTION 100UG/ML IN METHANOL 1ML
3,4-METHYLENEDIOXYCHALCONE
3-(1,3-BENZODIOXOL-5-YL)-1-(4-METHYLPHENYL)PROP-2-EN-1-ONE
1,5-BIS-(1,3-BENZODIOXOL-5-YL)-3-PENTADIENONE
1-(3,4-METHYLENEDIOXY-PHENYL)-4,4-DIMETHYL-PENT-1-EN-3-ONE