ChemicalBook >제품 카탈로그 >클로로[(트리-tert-부틸포스핀)-2-(2-아미노비페닐)]팔라듐(II)

클로로[(트리-tert-부틸포스핀)-2-(2-아미노비페닐)]팔라듐(II)

클로로[(트리-tert-부틸포스핀)-2-(2-아미노비페닐)]팔라듐(II) 구조식 이미지

카스 번호:: 1375325-71-5

한글명:: 클로로[(트리-tert-부틸포스핀)-2-(2-아미노비페닐)]팔라듐(II)

동의어(한글):: 클로로[(트리-tert-부틸포스핀)-2-(2-아미노비페닐)]팔라듐(II)

상품명:: Chloro[(tri-tert-butylphosphine)-2-(2-aMinobiphenyl)]palladiuM(II)

동의어(영문):: P(tBu)3 Pd G2;tBu3PPdG2 catalyst;P(t-Bu)3 Palladacycle Gen.2;Chloro[(tri-t-butylphosphine)-2-(2-aminobiphenyl)]palladium(II);Chloro(tri-t-butylphosphine)(2'-amino-1,1'-biphenyl-2-yl)pal...;Chloro(tri-tert-butylphosphine)(2'-aminobiphenylyl)palladium(II);Chloro(tri-tert-butylphosphine)(2’-aminobiphenylyl)palladium(II);Chloro[(tri-tert-butylphosphine)-2-(2-aMinobiphenyl)]palladiuM(II);Chloro[(tri-tert-butylphosphine)(2-aminobiphenyl-2-yl)palladium(II);Chloro[(tri-tert-butylphosphine)-2-(2-aminobiphenyl)]palladium(II)>

CBNumber:: CB42673226

분자식:: C24H37ClNPPd

포뮬러 무게:: 512.41

MOL 파일:: 1375325-71-5.mol

MSDS 파일:: SDS

속성

안전

용도

공급 업체 123

클로로[(트리-tert-부틸포스핀)-2-(2-아미노비페닐)]팔라듐(II) 속성

녹는점: 158-160°C

물리적 상태: 가루

색상: 노란색

InChI: InChI=1S/C12H9N.C12H27P.ClH.Pd/c13-12-9-5-4-8-11(12)10-6-2-1-3-7-10;1-10(2,3)13(11(4,5)6)12(7,8)9;;/h1-6,8-9,13H;1-9H3;1H;/q-2;;;+2

InChIKey: CCFGXRYKSYUWKT-UHFFFAOYSA-N

SMILES: P([Pd+2]1(NC2=CC=CC=C2C2=CC=CC=[C-]12)[Cl-])(C(C)(C)C)(C(C)(C)C)C(C)(C)C

안전

위험 및 안전 성명
위험 및 사전주의 사항 (GHS)

WGK 독일	3
HS 번호	2931.90.6000

그림문자(GHS):

신호 어:

Warning

유해·위험 문구:

암호	유해·위험 문구	위험 등급	범주	신호 어	그림 문자	P- 코드
H315	피부에 자극을 일으킴	피부부식성 또는 자극성물질	구분 2	경고		P264, P280, P302+P352, P321,P332+P313, P362
H319	눈에 심한 자극을 일으킴	심한 눈 손상 또는 자극성 물질	구분 2A	경고		P264, P280, P305+P351+P338,P337+P313P

예방조치문구:

P264	취급 후에는 손을 철저히 씻으시오.
P264	취급 후에는 손을 철저히 씻으시오.
P280	보호장갑/보호의/보안경/안면보호구를 착용하시오.

클로로[(트리-tert-부틸포스핀)-2-(2-아미노비페닐)]팔라듐(II) C화학적 특성, 용도, 생산

용도

P(t-Bu)₃ Pd G2 (Chloro[(tri-tert-butylphosphine)-2-(2-aminobiphenyl)] palladium(II), Pd/P(t-Bu)₃) may be used as catalyst in the following studies:

Synthesis of sterically hindered biaryls (tetra-ortho-substituted), via cross-coupling reactions of aryl chlorides.
Stille cross-couplings reactions of aryl chloride.
Synthesis of chloropeptin I, via Stille cross-coupling reaction.
Heck reaction.
Negishi cross-coupling reactions.

주요 응용

Catalyst for the Suzuki Coupling of brominated 2,1-borazaronaphthalenes and potassium organotrifluoroborates.

일반 설명

P(t-Bu)₃ Pd G2 (Chloro[(tri-tert-butylphosphine)-2-(2-aminobiphenyl)] palladium(II)) is a second generation (G2) precatalyst containing a biphenyl-based ligand. Product participates in various palladium catalyzed cross-coupling reactions, C-C, C-N and C-O bond formation reactions, and Suzuki-Miyaura coupling reactions. It generates active Pd catalyst at room temperature in the presence of weak phosphate or carbonate bases. It has been proposed as an active catalyst for use in Stille reactions of aryl halides (bromides and chlorides).

클로로[(트리-tert-부틸포스핀)-2-(2-아미노비페닐)]팔라듐(II) 준비 용품 및 원자재

원자재

준비 용품

클로로[(트리-tert-부틸포스핀)-2-(2-아미노비페닐)]팔라듐(II) 공급 업체

글로벌( 123)공급 업체

공급자	전화	이메일	국가	제품 수	이점
Wuhan Huahan Dingcheng New Material Technology Co., Ltd	+undefined-027-81388558 +undefined086-1878077615	huahandingcheng@sina.com	China	342	58
XINXIANG RUNYU MATERIAL CO., LTD.	+86-13592593621; +8613592593621	sales@runvmat.com	China	432	58
Henan Fengda Chemical Co., Ltd	+86-371-86557731 +86-13613820652	info@fdachem.com	China	20294	58
Shanghai Daken Advanced Materials Co.,Ltd	+86-371-66670886	info@dakenam.com	China	18655	58
career henan chemical co	+86-0371-86658258 +8613203830695	sales@coreychem.com	China	29888	58
Accela ChemBio Inc.	+1-858-6993322	info@accelachem.com	United States	19447	58
Shanghai Worldyang Chemical Co.,Ltd.	+86-021-56795779 +8613651600618	sales@worldyachem.com	China	1080	58
Jinan Liheng Biotechnology Co., Ltd.	15865262812	info@lihengpharm.com	CHINA	938	58
Richest Group Ltd	18017061086	oled@richest-group.com	CHINA	5601	58
Antai Fine Chemical Technology Co.,Limited	18503026267	info@antaichem.com	CHINA	9641	58

클로로[(트리-tert-부틸포스핀)-2-(2-아미노비페닐)]팔라듐(II) 관련 검색:

CHLORO[1,3-BIS(2,6-DI-I-PROPYLPHENYL)IMIDAZOL-2-YLIDENE]COPPER(I) CHLORO(1,5-CYCLOOCTADIENE)(PENTAMETHYLCYCLOPENTADIENYL)RUTHENIUM (II) tBuXPhos-Pd-G3 cataCXium A-Pd-G2 Methanesulfonato(tricyclohexylphosphine)(2'-aMino-1,1'-biphenyl-2-yl)palladiuM(II) dichloroMethane adduct P(t-Bu)3 Pd G4 Chloro[(tricyclohexylphosphine)-2-(2'-aminobiphenyl)]palladium(II) XPhos Pd G2 SPhos Pd G2 RuPhos Pd G2 Chloro[tri(p-tolyl)phosphine]gold(I),97% XantPhos-Pd-G2 Chloro[(S)-(-)-2,2'-bis(di-p-tolylphosphino)-1,1'-binaphthyl](p-cymene)ruthenium(II)chloride (2-BIPHENYL)DI-TERT-BUTYLPHOSPHINE GOLD& Chloro[(R)-(+)-5,5'-bis(diphenylphosphino)-4,4'-bi-1,3-benzodioxole](p-cymene)ruthenium(II) chloride [RuCl(p-cymene)((R)-segphos)]Cl BrettPhosPalladacycle Chloro[tri(o-tolyl)phosphine]gold(I) Chloro{[(1R,2R)-(-)-2-amino-1,2-diphenylethyl](4-toluenesulfonyl)amido}(mesitylene)ruthenium(II), min. 90% RuCl[(R,R)-Tsdpen(mesitylene)