트리알릴아민
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트리알릴아민 속성
- 녹는점
- -70°C
- 끓는 점
- 150-151 °C (lit.)
- 밀도
- 0.79 g/mL at 25 °C (lit.)
- 증기 밀도
- 4.73 (vs air)
- 증기압
- 90 mm Hg ( 80 °C)
- 굴절률
- n
20/D 1.451(lit.)
- 인화점
- 87 °F
- 저장 조건
- 2-8°C
- 물리적 상태
- 투명한 액체
- 산도 계수 (pKa)
- pK1:8.31(+1) (25°C)
- 색상
- 무색~황색~주황색
- 수용성
- 250g/100mL
- 안정성
- 안정적인. 가연성. 강한 산화제와 호환되지 않습니다.
- InChIKey
- VPYJNCGUESNPMV-UHFFFAOYSA-N
- CAS 데이터베이스
- 102-70-5(CAS DataBase Reference)
안전
- 위험 및 안전 성명
- 위험 및 사전주의 사항 (GHS)
위험품 표기 | C | ||
---|---|---|---|
위험 카페고리 넘버 | 10-20/21/22-34 | ||
안전지침서 | 16-26-36/37/39-45 | ||
유엔번호(UN No.) | UN 2610 3/PG 3 | ||
WGK 독일 | 3 | ||
RTECS 번호 | XX5950000 | ||
TSCA | Yes | ||
위험 등급 | 3 | ||
포장분류 | III | ||
HS 번호 | 29211990 | ||
유해 물질 데이터 | 102-70-5(Hazardous Substances Data) | ||
기존화학 물질 | KE-33958 |
트리알릴아민 C화학적 특성, 용도, 생산
화학적 성질
Triallylamine is a flammble liquid. Triallylamine can be detected at 0.5 ppm and is severely irritating at 75 ppm.용도
Triallylamine is used in organic synthesis.Triallylamine has been proposed as a catalyst for the production of polyesters and as an initiator for the polymerization of butadiene.주요 응용
Triallylamine (TAA) reacts with primary aromatic amines in the presence of a ruthenium catalyst to form 2-ethyl-3-methylquinolines.TAA undergoes hydrozirconation followed by transmetalation with germanium tetrachloride to form 1-aza-5-germa-5-chlorobicyclo[3.3.3]undecane. This compound can react with Grignard or lithium reagents to form the corresponding 5-organo compounds.
The cycloaddition of TAA to fluorinated 1,3,4-oxadiazoles affords octahydro-2,7-methanofuro[3,2-c]pyridines.
생산 방법
Triallylamine is manufactured using allyl chloride and ammonia under heat and pressure. It is used as a solvent and in organic syntheses.일반 설명
A colorless liquid with a fishlike odor. Density 0.800 g / cm3 and insoluble in water. Hence floats on water. Flash point 103°F. Vapors heavier than air. May irritate skin and eyes. Used to make other chemicals.공기와 물의 반응
Flammable. Insoluble in water.반응 프로필
Triallylamine is a strong reducing agent that reacts violently with oxidizing agents. Corrosive towards Al and Zn [Handling Chemicals Safely 1980 p. 912] . Neutralizes acids in exothermic reactions to form salts plus water. May be incompatible with isocyanates, halogenated organics, peroxides, phenols (acidic), epoxides, anhydrides, and acid halides. Flammable gaseous hydrogen may be generated in combination with strong reducing agents, such as hydrides.건강위험
May cause toxic effects if inhaled or ingested/swallowed. Contact with substance may cause severe burns to skin and eyes. Fire will produce irritating, corrosive and/or toxic gases. Vapors may cause dizziness or suffocation. Runoff from fire control or dilution water may cause pollution.화재위험
Flammable/combustible material. May be ignited by heat, sparks or flames. Vapors may form explosive mixtures with air. Vapors may travel to source of ignition and flash back. Most vapors are heavier than air. They will spread along ground and collect in low or confined areas (sewers, basements, tanks). Vapor explosion hazard indoors, outdoors or in sewers. Runoff to sewer may create fire or explosion hazard. Containers may explode when heated. Many liquids are lighter than water.Safety Profile
Poison by skin contact and intraperitoneal routes. Moderately toxic by ingestion and inhalation. An eye and severe skin irritant. Human systemic effects by inhalation: structural or functional changes in trachea or bronchi. Flammable liquid when exposed to heat, flame or oxidlzers. To fight fire, use foam, alcohol foam, fog. When heated to decomposition it emits toxic fumes of NOx. See also AMINES and ALLYL COMPOUNDS.트리알릴아민 준비 용품 및 원자재
원자재
준비 용품
트리알릴아민 공급 업체
글로벌( 214)공급 업체
공급자 | 전화 | 이메일 | 국가 | 제품 수 | 이점 |
---|---|---|---|---|---|
Hebei Mojin Biotechnology Co., Ltd | +8613288715578 |
sales@hbmojin.com | China | 12450 | 58 |
Hebei Guanlang Biotechnology Co,.LTD | +8619930503252 |
daisy@crovellbio.com | China | 5828 | 58 |
Henan Fengda Chemical Co., Ltd | +86-371-86557731 +86-13613820652 |
info@fdachem.com | China | 20294 | 58 |
Hefei TNJ Chemical Industry Co.,Ltd. | +86-0551-65418679 +86-18949832763 |
info@tnjchem.com | China | 2989 | 55 |
career henan chemical co | +86-0371-86658258 +8613203830695 |
sales@coreychem.com | China | 29894 | 58 |
Hubei Jusheng Technology Co.,Ltd. | 18871490254 |
linda@hubeijusheng.com | CHINA | 28180 | 58 |
Hebei Guanlang Biotechnology Co., Ltd. | +86-19930503282 |
alice@crovellbio.com | China | 8822 | 58 |
Xiamen AmoyChem Co., Ltd | +86-592-6051114 +8618959220845 |
sales@amoychem.com | China | 6387 | 58 |
Hubei xin bonus chemical co. LTD | 86-13657291602 |
linda@hubeijusheng.com | CHINA | 22968 | 58 |
Shandong chuangyingchemical Co., Ltd. | 18853181302 |
sale@chuangyingchem.com | CHINA | 5909 | 58 |
트리알릴아민 관련 검색:
알릴아민 티오초산 2,2,6,6-사메틸-4-피페리디놀 싸이오아세트아마이드 오도라틴 (Odoratine) 트리알릴아민
Tributylmethylammonium bromide
1H-TETRAZOLYL-1-ACETIC ACID /TAA,TAA
1H-tetrazole-1-acetic acid
METHYL-TAA-OL,N-Methyl Triacetonamino Alcohol Methyl-TAA-ol
(Z)-2-(tert-Butoxycarbonylprop-2-oxyimino)-2-(2-tritylaminothiazol-4-yl)acetic acid
TAA
1,4-BIS(TRIALLYLAMMONIUM)-2-BUTENE DIBROMIDE
TAA
N,N-DIALLYLACRYLAMIDE
TETRAALLYLAMMONIUM BROMIDE
TAA
TRIS(2-METHYLALLYL)AMINE, 99
5-CCA ATT ACC AGA CAC TAA TGC-3