에키네논

에키네논
에키네논 구조식 이미지
카스 번호:
432-68-8
한글명:
에키네논
동의어(한글):
에키네논
상품명:
ECHINENONE
동의어(영문):
ECHINENONE;Einecs 207-083-4;β,β-Caroten-4-one;?,?-caroten-4-one;all-trans-Echinenone;beta,beta-caroten-4-one;Echinenone (In Solution);9-cis-β,β-Carotene-4-one;9'-cis-β,β-Carotene-4-one;Echinenone (Technical Grade)
CBNumber:
CB4423339
분자식:
C40H54O
포뮬러 무게:
550.86
MOL 파일:
432-68-8.mol
MSDS 파일:
SDS

에키네논 속성

녹는점
178-180°
끓는 점
685.3±25.0 °C(Predicted)
밀도
0.972±0.06 g/cm3(Predicted)
저장 조건
-20°C
용해도
클로로포름(약간 용해됨), 디에틸에테르(약간 용해됨), 메탄올(약간 용해됨)
물리적 상태
고체
물리적 상태
단단한 모양
색상
진한 빨간색에서 매우 진한 빨간색까지
최대 파장(λmax)
λ: 459 nm±5 nm Amax
BRN
2030114
안정성
감광성, 온도 민감성

안전

WGK 독일 3

에키네논 C화학적 특성, 용도, 생산

용도

Echinenone may be used as an external standard for the extraction of carotenoid from plasma samples. It may also been used as an internal standard, added to samples for extraction and quantification.

정의

ChEBI: A carotenone that is beta-carotene in which the 4 position has undergone formal oxidation to afford the corresponding ketone. Isolated as orange-red crystals, it is widely distributed in marine invertebrates.

일반 설명

Echinenone is a carotenoid with a conjugated carbonyl group. Echinenone (4-keto-β-carotene) is a monoketo compound, is an intermediate between β-carotene and canthaxanthin in animals. It is one of the major carotenoids of Anabaena sp., and also present in Micrococcus roseus. It is located in the thylakoid membrane of Anabaena. The conversion of β-carotene to echinenone is catalysed by CrtO, a β-carotene ketolase.

Purification Methods

Purify β,β-caroten-4-one by chromatography on partially deactivated alumina or magnesia, or by using a thin layer plate of silica gel G with 4:1 cyclohexane/diethyl ether as the developing solvent. Recrystallise it from *C6H6/MeOH. Store it in the dark at -20o. The oxime crystallises from *C6H6 with m 208o. [Beilstein 7 III 2858, 7 IV 1881.]

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