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ChemicalBook >제품 카탈로그 >(R)-(+)-4-[2-(DIPHENYLPHOSPHINO)-1-NAPHTHALENYL]-N-[-1-PHENYLETHYL]-1-PHTHALAZINAMINE, MIN.(R)-N-PINAP

(R)-(+)-4-[2-(DIPHENYLPHOSPHINO)-1-NAPHTHALENYL]-N-[-1-PHENYLETHYL]-1-PHTHALAZINAMINE, MIN.(R)-N-PINAP

(R)-(+)-4-[2-(DIPHENYLPHOSPHINO)-1-NAPHTHALENYL]-N-[-1-PHENYLETHYL]-1-PHTHALAZINAMINE, MIN.(R)-N-PINAP 구조식 이미지
카스 번호:
828927-97-5
상품명:
(R)-(+)-4-[2-(DIPHENYLPHOSPHINO)-1-NAPHTHALENYL]-N-[-1-PHENYLETHYL]-1-PHTHALAZINAMINE, MIN.(R)-N-PINAP
동의어(영문):
(R,R)-PINAP;4-[2-(Diphenylphosphino)-1-naphthyl]-N-(1-phenylethyl)phthalazin-1-amine;4-(2-diphenylphosphanylnaphthalen-1-yl)-N-[(1R)-1-phenylethyl]phthalazin-1-amine;(R)-4-[2-(DIPHENYLPHOSPHINO)-1-NAPHTHALENYL]-N-[(1R)-1-PHENYLETHYL]-1-PHTHALAZINAMINE;1-Phthalazinamine, 4-[2-(diphenylphosphino)-1-naphthalenyl]-N-[(1R)-1-phenylethyl]-, (1R)-;(R)-(+)-4-[2-(Diphenylphosphino)-1-naphthalenyl]-N-[(R)-1-phenylethyl]-1-phthalazinaMine (R,R)-N-PINAP;(R)-(+)-4-[2-(DIPHENYLPHOSPHINO)-1-NAPHTHALENYL]-N-[-1-PHENYLETHYL]-1-PHTHALAZINAMINE, MIN.(R)-N-PINAP;(R)-(+)-4-[2-(DIPHENYLPHOSPHINO)-1-NAPHTHALENYL]-N-[?-1-PHENYLETHYL]-1-PHTHALAZINAMINE, MIN.(R)-N-PINAP;(R)-(+)-4-[2-(Diphenylphosphino)-1-naphthalenyl]-N-[(R)-1-phenylethyl]-1-phthalazinamine,min.97%(R)-N-PINAP;(R)-(+)-4-[2-(Diphenylphosphino)-1-naphthalenyl]-N-[(R)-1-phenylethyl]-1-phthalazinamine, min. 97% (R,R)-N-PINAP
CBNumber:
CB4505705
분자식:
C38H30N3P
포뮬러 무게:
559.64
MOL 파일:
828927-97-5.mol

(R)-(+)-4-[2-(DIPHENYLPHOSPHINO)-1-NAPHTHALENYL]-N-[-1-PHENYLETHYL]-1-PHTHALAZINAMINE, MIN.(R)-N-PINAP 속성

녹는점
185-188°C
알파
+127.3° (c 0.39, CHCl3)
끓는 점
732.0±60.0 °C(Predicted)
산도 계수 (pKa)
5.35±0.30(Predicted)
물리적 상태
수정 같은
색상
무색의
감도
air sensitive
안전
  • 위험 및 안전 성명
  • 위험 및 사전주의 사항 (GHS)
그림문자(GHS): GHS hazard pictograms
신호 어: Warning
유해·위험 문구:
암호 유해·위험 문구 위험 등급 범주 신호 어 그림 문자 P- 코드
H302 삼키면 유해함 급성 독성 물질 - 경구 구분 4 경고 GHS hazard pictograms P264, P270, P301+P312, P330, P501
H315 피부에 자극을 일으킴 피부부식성 또는 자극성물질 구분 2 경고 GHS hazard pictograms P264, P280, P302+P352, P321,P332+P313, P362
H319 눈에 심한 자극을 일으킴 심한 눈 손상 또는 자극성 물질 구분 2A 경고 GHS hazard pictograms P264, P280, P305+P351+P338,P337+P313P
H335 호흡 자극성을 일으킬 수 있음 특정 표적장기 독성 - 1회 노출;호흡기계 자극 구분 3 경고 GHS hazard pictograms
예방조치문구:
P261 분진·흄·가스·미스트·증기·...·스프레이의 흡입을 피하시오.
P280 보호장갑/보호의/보안경/안면보호구를 착용하시오.
P301+P312 삼켜서 불편함을 느끼면 의료기관(의사)의 진찰을 받으시오.
P302+P352 피부에 묻으면 다량의 물로 씻으시오.
P305+P351+P338 눈에 묻으면 몇 분간 물로 조심해서 씻으시오. 가능하면 콘택트렌즈를 제거하시오. 계속 씻으시오.

(R)-(+)-4-[2-(DIPHENYLPHOSPHINO)-1-NAPHTHALENYL]-N-[-1-PHENYLETHYL]-1-PHTHALAZINAMINE, MIN.(R)-N-PINAP C화학적 특성, 용도, 생산

화학 반응

  1. The PINAP family of P,N ligands is a synthetically more accessible but a similarly performing analog of the QUINAP (15-1777, 15-1778) ligand in enantioselective hydroboration, alkyne addition, and azomethine cycloaddition reactions.
  2. With copper, enantioselective addition of alkynes to aldehydes to synthesize propargylamines.
  3. With copper, catalytic, enantioselective, conjugate alkyne addition in aqueous media.
Reactions of 828927-97-5

(R)-(+)-4-[2-(DIPHENYLPHOSPHINO)-1-NAPHTHALENYL]-N-[-1-PHENYLETHYL]-1-PHTHALAZINAMINE, MIN.(R)-N-PINAP 준비 용품 및 원자재

원자재

준비 용품

(R)-(+)-4-[2-(DIPHENYLPHOSPHINO)-1-NAPHTHALENYL]-N-[-1-PHENYLETHYL]-1-PHTHALAZINAMINE, MIN.(R)-N-PINAP 공급 업체

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