1-ADAMANTYL메타크릴레이트
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1-ADAMANTYL메타크릴레이트 속성
- 끓는 점
- 289.3±9.0 °C(Predicted)
- 밀도
- 1.07±0.1 g/cm3(Predicted)
- 굴절률
- 1.50
- 저장 조건
- 2-8°C
- 물리적 상태
- powder to lump to clear liquid
- 색상
- White or Colorless to Almost white or Almost colorless
- InChI
- InChI=1S/C14H20O2/c1-9(2)13(15)16-14-6-10-3-11(7-14)5-12(4-10)8-14/h10-12H,1,3-8H2,2H3
- InChIKey
- MZVABYGYVXBZDP-UHFFFAOYSA-N
- SMILES
- C(OC12CC3CC(CC(C3)C1)C2)(=O)C(C)=C
안전
- 위험 및 안전 성명
- 위험 및 사전주의 사항 (GHS)
HS 번호 | 2916120090 |
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신호 어: | Warning | ||||||||||||||||||||||||||||
유해·위험 문구: |
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예방조치문구: |
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1-ADAMANTYL메타크릴레이트 C화학적 특성, 용도, 생산
개요
1-adamantyl methacrylate is a monomer that has a hydroxy group and a carbonyl group.제조 방법
The preparation of 1-adamantyl methacrylate is as follows:Stirrer, air inlet tube,Dean-Stark type water separator,Necked flask equipped with a stirrer, a thermometer,1-Adamantanol 100 g(0.657 mol),Methoquinone0.581 g,Hydroquinone0.143 g,Methacrylic acid227 g (2.64 mol) andMethylcyclohexaneWas added.After adding 1.61 g (0.0164 mol) of concentrated sulfuric acid,While blowing air at 10 mL / min, the mixture was stirred at a temperature of 100 to 115 ° C. for 4 hours under azeotropy of methylcyclohexane and water.4 hours laterThe conversion of 1-adamantanol was 95.1%.at this pointMethacrylic anhydride10.1 g (0.0657 mol / 2.0 equivalents to residual 1-adamantanol) was added,The mixture was further stirred for 1 hour,The reaction was terminated.The residual amount of 1-adamantanol after the reaction was 0.2%.The reaction solution was cooled to room temperature,313 g of a 20% by mass sodium hydroxide aqueous solution was added dropwise,The organic phase was washed.further,And washed twice with 100 mL of pure water.After distilling off the solvent with an evaporator, distillation under reduced pressure at 1 torr and 90 ° C.,122 g (yield 84.1%) of a colorless transparent liquid was obtained.This liquid was analyzed by GC and GPC.According to GC analysis1-Adamantyl acrylateThe purity of 99.5%.주요 응용
1-Adamantyl Methacrylate is a monomer that has a hydroxy group and a carbonyl group. It is used in the production of polymers, as well as in coatings and adhesives. 1-Adamantyl Methacrylate can be thermally polymerized or crosslinked to form a polymer with high resistance to radiation and heat.This monomer has been used for the fabrication of organic light emitting diodes (OLEDs) and other device applications such as microelectronic circuits, solar cells, and displays.Research
1-Adamantyl methacrylate (AdMA) could be polymerized using the atom transfer radical polymerization (ATRP) method with methyl α-bromoisobutyrate (MBiB), copper(I) bromide (CuBr), copper(II) bromide (CuBr2) and 1,1,4,7,10,10-hexamethyltriethylenetetramine (HMTETA) in toluene at 60?°C, producing well-defined poly(1-adamantyl methacrylate) (PAdMA). The controlled/living radical polymerization of methacrylate monomers bearing bulky ester groups, such as AdMA, which guarantees the generation of well-defined macromolecular architectures such as the block copolymer, graft copolymer and star-shaped polymer on a preparative scale, is still of great interest[1].1-ADAMANTYL메타크릴레이트 준비 용품 및 원자재
원자재
준비 용품
1-ADAMANTYL메타크릴레이트 공급 업체
글로벌( 140)공급 업체
공급자 | 전화 | 이메일 | 국가 | 제품 수 | 이점 |
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Changzhou waston chemical technology Co.,Ltd | +86-051985861892 +8618112881323 |
info@wastonchem.com | China | 250 | 58 |
Shanghai Z&T Chemical Co., Ltd | +86-021-33561011 +8613818804961 |
Sales@ztchemical.com.cn | China | 402 | 58 |
Henan Fengda Chemical Co., Ltd | +86-371-86557731 +86-13613820652 |
info@fdachem.com | China | 20290 | 58 |
Capot Chemical Co.,Ltd. | 571-85586718 +8613336195806 |
sales@capotchem.com | China | 29798 | 60 |
Shanghai Daken Advanced Materials Co.,Ltd | +86-371-66670886 |
info@dakenam.com | China | 18623 | 58 |
Henan Tianfu Chemical Co.,Ltd. | +86-0371-55170693 +86-19937530512 |
info@tianfuchem.com | China | 21663 | 55 |
Fluoropharm Co., Ltd. | +86-0571-85586753; +8613336034509 |
sales@fluoropharm.com | China | 1377 | 60 |
career henan chemical co | +86-0371-86658258 +8613203830695 |
sales@coreychem.com | China | 29890 | 58 |
Shanghai Arbor Chemical Co., Ltd. | 021-60451682 |
act@arborchemical.com | CHINA | 906 | 58 |
QINGDAO HONG JIN CHEMCIAL CO.,LTD. | 532-83657313 |
hjt@hong-jin.com | China | 228 | 58 |
1-ADAMANTYL메타크릴레이트 관련 검색:
5-히드록시-2-아다만타논
1,3-Adamantanediol
7,7'-Dibromo-3,3',5,5'-tetramethyl-1,1'-biadamantane
2-Ethyl-2-adamantanol
2-Adamantanone
2-Adamantone-5-carboxylic acid
1-Adamantylacrylate
5-CHLORO-2-ADAMANTANONE
1,3,5-ADAMANTANETRIOL
3-Hydroxy-1-adamantyl methacrylate
5-Carboxy-2-Aminoadamantane
adamantane-1-sulfonyl chloride
2-(2-methyl)adamantyl-methacrylate,2-ADAMANTYL METHACRYLATE,2-ADAMANTYL METHACRYLATE [133682-15-2] C14H20O2 FW220.31
1-METHYLCYCLOHEXYL ACRYLATE
1-Adamantyl Methacrylate
2-methyl-2-adamantyl methacrylate
2-ETHYL-2-ADAMANTYL METHACRYLATE
2-MTHYL-2-ADAMANTYL METHACRYLATE