피부(또는 머리카락)에 묻으면 오염된 모든 의복은 벗거나 제거하시오 피부를 물로 씻으시오/샤워하시오.
P304+P340
흡입하면 신선한 공기가 있는 곳으로 옮기고 호흡하기 쉬운 자세로 안정을 취하시오.
P305+P351+P338
눈에 묻으면 몇 분간 물로 조심해서 씻으시오. 가능하면 콘택트렌즈를 제거하시오. 계속 씻으시오.
P310
즉시 의료기관(의사)의 진찰을 받으시오.
삼켰다면 즉시 의료기관(의사)의 도움을 받으시오.
P321
(…) 처치를 하시오.
P330
입을 씻어내시오.
P363
다시 사용전 오염된 의류는 세척하시오.
P370+P378
화재 시 불을 끄기 위해 (Section 5. 폭발, 화재시 대처방법의 적절한 소화제)을(를) 사용하시오.
P391
누출물을 모으시오.
P403+P235
환기가 잘 되는 곳에 보관하고 저온으로 유지하시오.
P405
밀봉하여 저장하시오.
P411
보관 시 ...℃/...℉를 넘지 않도록 하시오.
P420
격리하여 보관하시오.
P501
...에 내용물 / 용기를 폐기 하시오.
테트랄린하이드로퍼옥사이드 C화학적 특성, 용도, 생산
화학적 성질
Hydroperoxide is formed by the oxidation of tetralin, a
DuPont product, and used as a turpentine replacement. The
technical grade hydroperoxide is a liquid and will have a
residual odor of benzene/menthol. No rapid reaction
occurs with air or water. Most alkyl monohydroperoxides
are liquid, the explosivity of the lower members (e.g.,
methyl hydroperoxide or possibly due to traces of the
dialkyl peroxides) decreasing with increasing chain length
and branching. Tetralin hydroperoxide explodes on superheating
the liquid. Its interaction with strong reducing
agents, like lithium tetrahydroaluminate, is vigorously
exothermic (13d).
용도
Tetralin hydroperoxide has been prepared by the oxidation of
tetralin in the presence of cobalt naphthenate, manganese
stearate, and ceric stearate or naphthenate. Tetralin hydroperoxide,
produced by the oxidation of tetralin, may be
separated from reaction products by formation of its sodium
salt. The kinetics of the liquid-phase oxidation of tetralin
have been studied . Chen and Lin used tetralin hydroperoxide
as an intermediate in the hydroxylation of tetralin to
tetralol in rat liver homogenate.
일반 설명
Hydroperoxide formed by the oxidation of tetralin, a DuPont product, used as a turpentine replacement. The technical grade hydroperoxide is a liquid and will have a residual odor of benzene/menthol.
반응 프로필
Most alkyl monohydroperoxides are liquid, the explosivity of the lower members (e.g., methyl hydroperoxide, or possibly due to traces of the dialkyl peroxides) decreasing with increasing chain length and branching [Bretherick 2nd ed. 1979 p. 10]. 1,2,3,4-tetrahydro-1-naphthyl hydroperoxide explodes on superheating the liquid [Hock et al. Ber. 1933. pp. 66, 61]. It's interaction with strong reducing agents, like lithium tetrahydroaluminate, is vigorously exothermic.
Purification Methods
Crystallise the tetralin hydroperoxide from hexane, toluene at -30o (m 54.0-54.5o). The oxygen content should be ~9.70%. [Knight & Swern Org Synth Coll Vol 1V 895 1963.]
