ChemicalBook >제품 카탈로그 >화학 시약>유기 시약>다환 화합물>9-Anthraceneboronic 산

9-Anthraceneboronic 산

9-Anthraceneboronic 산 구조식 이미지

카스 번호:: 100622-34-2

한글명:: 9-Anthraceneboronic 산

동의어(한글):: 9-Anthraceneboronic산

상품명:: 9-Anthraceneboronic acid

동의어(영문):: Anthracen-9-ylboronic acid;ANTHRACENE-9-BORONIC ACID;9-Anthracenylboronic acid;DKI84;9-Boronoanthracene;9-anthracene-boronic;9-Anthracenylboronic;9-Anthrylboronicacid;9-Anthraceneboronicl;9-AnthraceneboronicAci

CBNumber:: CB5142419

분자식:: C14H11BO2

포뮬러 무게:: 222.05

MOL 파일:: 100622-34-2.mol

속성

안전

용도

공급 업체 385

9-Anthraceneboronic 산 속성

녹는점: 203-250 °C

끓는 점: 479.5±28.0 °C(Predicted)

밀도: 1.26±0.1 g/cm3(Predicted)

저장 조건: Keep in dark place,Sealed in dry,Room Temperature

용해도: 메탄올에 용해됨

물리적 상태: 결정질 고체

산도 계수 (pKa): 8.53±0.30(Predicted)

색상: 흰색에서 황갈색까지

BRN: 3301031

InChI: InChI=1S/C14H11BO2/c16-15(17)14-6-5-12-7-10-3-1-2-4-11(10)8-13(12)9-14/h1-9,16-17H

InChIKey: VHHDLIWHHXBLBK-UHFFFAOYSA-N

SMILES: C1=C2C(C=C3C(=C2)C=CC=C3)=CC=C1B(O)O

CAS 데이터베이스: 100622-34-2(CAS DataBase Reference)

안전

위험 및 안전 성명
위험 및 사전주의 사항 (GHS)

위험품 표기	T
위험 카페고리 넘버	36/37/38-25
안전지침서	26-36-45
유엔번호(UN No.)	UN 2811 6.1/PG 3
WGK 독일	3
TSCA	No
위험 등급	IRRITANT
위험 등급	6.1
포장분류	Ⅲ
HS 번호	29319090

그림문자(GHS):

신호 어:

Danger

유해·위험 문구:

암호	유해·위험 문구	위험 등급	범주	신호 어	그림 문자	P- 코드
H301	삼키면 유독함	급성 독성 물질 - 경구	구분 3	위험		P264, P270, P301+P310, P321, P330,P405, P501

예방조치문구:

P301+P310

삼켰다면 즉시 의료기관(의사)의 진찰을 받으시오.

NFPA 704

	1
3		0

9-Anthraceneboronic 산 C화학적 특성, 용도, 생산

개요

9-Anthraceneboronic acid is a boronic acid compound mainly used as an organic synthesis and reaction reagent. The addition of 9-Anthraceneboronic acid introduces a borate ester bond and an anthracene functional group into ordinary polyvinyl alcohol, which can be used to prepare the composite material poly(vinyl alcohol) anthraceneboronic acid (PVA-ABA), which is suitable for sustainable engineering applications due to its high mechanical strength and toughness, good water resistance, chemical durability, and ease of recycling. It can also be used to prepare stimuli-responsive polymeric materials and highly efficient luminescent materials.

화학적 성질

Tan solid

용도

suzuki reaction

Synthesis

9-bromoanthracence (10.0 g, 38.9 mmol) was dissolved in an anhydrous THF solution (500 mL) and stirred at ?78C. Then, 1.6 M n-BuLi (29.3 mL,46.7 mmol) was added. Triethyl borate (9.3 mL, 54.5 mmol) was added to the reaction after 30 min. After the reaction, the solution was acidified with 2 N HCl solution at room temperature and extracted with ethyl acetate and water. The organic layer was dried with anhydrous MgSO4 and filtered. The solution was evaporated. The residue was dissolved in hexane and added to ethyl acetate. The precipitate was filtered and washed with hexane to obtain a beige compound 9-Anthraceneboronic acid (7.70 g, 89 percent).

Purification Methods

Crystallise the boronic acid from dilute HCl (m 180-184o). The disodium salt has m 209-213o. [Beilstein 16 IV 1679.]

참고 문헌

[1] Qizhou Sang and Zixing Shi*. “Waterproof, Chemically Durable, and Closed-Loop Recyclable Poly(vinyl alcohol) Plastic Enabled by Dynamic Covalent Modification.” ACS Applied Polymer Materials 5 11 (2023): 9403–9412.
[2] Zhiyong Liu. “Integrating Boronic Esters and Anthracene into Covalent Adaptable Networks toward Stimuli-Responsive Elastomers.” Polymers (2022).

9-Anthraceneboronic 산 준비 용품 및 원자재

원자재

붕산트리에틸 9-브로모안트라센 붕산트리메틸

준비 용품

9-브로 모-10-(2-naphthyl) anthracene 1,3,5-Tri(anthracen-9-yl)benzene

9-Anthraceneboronic 산 공급 업체

글로벌( 385)공급 업체

공급자	전화	이메일	국가	제품 수	이점
Springchem New Material Technology Co.,Limited	+86-021-62885108 +8613917661608	info@spring-chem.com	China	2068	57
Shaanxi LuyuanBiomedicine Co., LTD	+86-13991827389 +86-13991827389	sxlysw@sxlysw.com.cn	China	110	58
Shengyan (Shanghai) New Material Co., Ltd.	+86-021-37596312 +8613585706261	ken@syanchem.com	China	172	58
SHANGHAI KEAN TECHNOLOGY CO., LTD.	+8613817748580	cooperation@kean-chem.com	China	40066	58
Hebei Yanxi Chemical Co., Ltd.	+8617531190177	peter@yan-xi.com	China	5857	58
Hebei Xinsheng New Material Technology Co., LTD.	+86-16632316109	xinshengkeji@xsmaterial.com	China	1085	58
Henan Fengda Chemical Co., Ltd	+86-371-86557731 +86-13613820652	info@fdachem.com	China	20284	58
Hebei Zhuanglai Chemical Trading Co Ltd	+86-16264648883 +86-16264648883	niki@zlchemi.com	China	2691	58
Capot Chemical Co.,Ltd.	+86-（0）57185586718 +86-13336195806	sales@capot.com	China	29791	60
Shanghai Daken Advanced Materials Co.,Ltd	+86-371-66670886	info@dakenam.com	China	18751	58

9-Anthraceneboronic 산 관련 검색:

붕산 아연 스테아르산 시트르산 엽산 붕불화수소산 아세트산 붕산 안트라센 [10-(1-Naphthalenyl)-9-anthracenyl] boronic 산 1-나프탈렌붕산 (10-Phenylanthracen-9-yl) boronic 산 9-Anthraceneboronic 산 9-phenanthrenylboronic acid Hyaluronic acid Ascoric Acid 10-BROMOANTHRACENE-9-BORONIC ACID 2-Anthraceneboronic Acid (contains varying amounts of Anhydride) THIANTHRENE-1-BORONIC ACID