LOCHNERINE

LOCHNERINE 구조식 이미지
카스 번호:
522-47-4
상품명:
LOCHNERINE
동의어(영문):
LOCHNERINE;Lochenerine;Luo Ke alkali;(+)-Lochnerine;(+)-Lochenerine;10-O-Methylsarpagine;10-Methoxynormacusine B;10-Methoxysarpagan-17-ol;Sarpagan-17-ol, 10-methoxy-;6,10-Methanoindolo[3,2-b]quinolizine-11-methanol,9-ethylidene-5,6,8,9,10,11,11a,12-octahydro-2-methoxy-,(6S,7R,9E,10R,11R,11aS)-
CBNumber:
CB51442961
분자식:
C20H24N2O2
포뮬러 무게:
324.422
MOL 파일:
522-47-4.mol

LOCHNERINE 속성

녹는점
202.5-203.5°C

안전

LOCHNERINE C화학적 특성, 용도, 생산

개요

This carboline alkaloid has been obtained from Lochnera rosea and is also present in curare (Strychnos toxifera). Early preparations have been designated Alkaloid 'C' and C-Alkaloid T. It has [α]D + 56° (pyridine) or + n° (EtOH) and forms a crystalline picrate with a double melting point of 177-9°C and 243-5°C (dec.). The methiodide is identical with lochneram iodide, m.p. 235-8°C. A characteristic p-toluenesulphonyl derivative has been prepared, m.p. 153-4°C. One primary alcoholic hydroxyl is present and the alkaloid yields the O-acetate as colourless needles, m.p. 243°C; [α]D - 5.6° ± 3.0° (c 0.36, pyridine). The structure is that of O-methylsarpagine.

참고 문헌

Janot, LeMen., Cornpt. rend., 243, 1789 (1956)
Mors et at., Chern. Ind., 173 (1956)
Arnold et at., Helv. Chirn. Acta, 40, 705 (1957)
Arnold et al., ibid, 41, 1505 (1958)
Karrer et at., Angew. Chern., 70,644 (1958)

LOCHNERINE 준비 용품 및 원자재

원자재

준비 용품


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