벤조(B)플루란텐

벤조(B)플루란텐
벤조(B)플루란텐 구조식 이미지
카스 번호:
205-99-2
한글명:
벤조(B)플루란텐
동의어(한글):
벤조(B)플루란텐;벤즈[e]아세페난트릴렌;2,3-벤조플루오란텐
상품명:
BENZO(B)FLUORANTHENE
동의어(영문):
BBF;BENZ[E]ACEPHENANTHRYLENE;REF;benzo(e)fluoranthene;B[E]F;THOC4;ALY/REF;NSC 89265;Benzo(b)fluor;Benzo(b)uoranthene
CBNumber:
CB5302581
분자식:
C20H12
포뮬러 무게:
252.31
MOL 파일:
205-99-2.mol
MSDS 파일:
SDS

벤조(B)플루란텐 속성

녹는점
163-165 °C(lit.)
끓는 점
481°C(lit.)
밀도
1.1549 (estimate)
증기압
5 x 10-7 mmHg at 20 °C (U.S. EPA, 1982)
굴절률
1.8390 (estimate)
인화점
-18 °C
저장 조건
2-8°C
용해도
대부분의 용매에 용해됨(US EPA, 1985)
산도 계수 (pKa)
>15 (Christensen et al., 1975)
색상
White to Yellow to Green
수용성
25°C에서 1.2μg/L (U.S. EPA, 1980a)
BRN
1872553
Henry's Law Constant
2.47, 5.03, 11.74, 14.90, 20.53, and 36.52 at 10.0, 20.0, 35.0, 40.1, 45.0, and 55.0 °C, respectively (wetted-wall column, ten Hulscher et al., 1992)
안정성
안정적인. 강한 산화제와 호환되지 않습니다.
CAS 데이터베이스
205-99-2(CAS DataBase Reference)
IARC
2B (Vol. 92) 2010
EPA
Benzo[b]fluoranthene (205-99-2)
안전
  • 위험 및 안전 성명
  • 위험 및 사전주의 사항 (GHS)
위험품 표기 T,N,Xn,F,Xi
위험 카페고리 넘버 45-50/53-67-65-38-11-36-39/23/24/25-23/24/25-66-52/53-20
안전지침서 53-45-60-61-62-26-16-9-36/37-7-33-25
유엔번호(UN No.) UN 2811 6.1/PG 3
WGK 독일 3
RTECS 번호 CU1400000
HS 번호 2902.90.9000
위험 등급 6.1(b)
포장분류 III
유해 물질 데이터 205-99-2(Hazardous Substances Data)
독성 LC50 (21-d) for Folsomia fimetaria >3,600 mg/kg (Sverdrup et al., 2002).
그림문자(GHS): GHS hazard pictogramsGHS hazard pictograms
신호 어: Danger
유해·위험 문구:
암호 유해·위험 문구 위험 등급 범주 신호 어 그림 문자 P- 코드
H350 암을 일으킬 수 있음 (노출되어도 암을 일으키지 않는다는 결정적인 증거가 있는 노출경로가 있다면 노출경로 기재) 발암성 물질 구분 1A, 1B 위험 GHS hazard pictograms
H410 장기적 영향에 의해 수생생물에 매우 유독함 수생 환경유해성 물질 - 만성 구분 1 경고 GHS hazard pictograms P273, P391, P501
예방조치문구:
P202 모든 안전 조치 문구를 읽고 이해하기 전에는 취급하지 마시오.
P273 환경으로 배출하지 마시오.
P280 보호장갑/보호의/보안경/안면보호구를 착용하시오.
P308+P313 노출 또는 접촉이 우려되면 의학적인 조치· 조언를 구하시오.
P391 누출물을 모으시오.
P405 밀봉하여 저장하시오.
NFPA 704
0
1 0

벤조(B)플루란텐 C화학적 특성, 용도, 생산

화학적 성질

Benzo(b)fluoranthene is a colorless, needleshaped solid.

물리적 성질

Colorless to pale yellow to yellow-orange needles or crystals from benzene, toluene, ethylbenzene or acetic acid.

용도

Benz[e]acephenanthrylene is a polycyclic aromatic hydrocarbon that was detected in significant levels in airborne polluants, auto exhaust and tobacco and marijuana smoke.

정의

ChEBI: An ortho- and peri-fused polycyclic arene that consists of a benzene ring fused with a acephenanthrylene ring.

일반 설명

Needles or yellow fluffy powder.

공기와 물의 반응

Insoluble in water.

반응 프로필

BENZO(B)FLUORANTHENE can react with strong oxidizing agents. May react with electrophiles, peroxides, nitrogen oxides and sulfur oxides

위험도

Confirmed carcinogen.

건강위험

ACUTE/CHRONIC HAZARDS: When heated to decomposition, BENZO(B)FLUORANTHENE emits acrid smoke and irritating fumes.

화재위험

Flash point data for BENZO(B)FLUORANTHENE are not available; however, BENZO(B)FLUORANTHENE is probably combustible.

Safety Profile

Confirmed carcinogen with experimental carcinogenic and tumorigenic data. Mutation data reported. When heated to decomposition it emits acrid smoke and irritating fumes.

잠재적 노출

There is no commercial production of this compound. Benzo(b)fluoranthene is a chemical substance formed during the incomplete burning of fossil fuel, garbage, in cigarette smoke, or any organic matter and is Benzofluoranthene 399 found in smoke in general; it is carried into the air, where it condenses onto dust particles and is distributed into water and soil and on crops. B(b)F is a PAH and a component of coal tar pitch used in industry as a binder for electrodes. It is also a component of creosote, which is used to preserve wood. PAHs are also found in limited a mounts in bituminous materials and asphalt used for paving, roofing, and insulation. B(b)F has some use as a research chemical. It is available from some specialty chemical firms in low quantities (25 100 mg).

Carcinogenicity

Benzo[b]fluoranthenewas tested for carcinogenicity by dermal application in mice in multiple studies, intraperitoneal injection into mice in multiple studies, and intrapulmonary implantation into rats in one study. In all of these studies, benzo[b]-fluoranthene exhibited a significant carcinogenic activity.

환경귀착

Biological. Ye et al. (1996) investigated the ability of Sphingomonas paucimobilis strain U.S. EPA 505 (a soil bacterium capable of using fluoranthene as a sole source of carbon and energy) to degrade 4, 5, and 6-ringed aromatic hydrocarbons (10 ppm). After 16 h of incubation using a resting cell suspension, only 12.5% of benzo[b]fluoranthene had degraded. It was suggested that degradation occurred via ring cleavage resulting in the formation of polar metabolites and carbon dioxide.
Soil. The reported half-lives for benzo[b]fluoranthene in a Kidman sandy loam and McLaurin sandy loam are 294 and 211 d, respectively (Park et al., 1990).
Photolytic. The atmospheric half-life was estimated to range from 1.43 to 14.3 h (Atkinson, 1987).
Chemical/Physical. Benzo[b]fluoranthene will not hydrolyze because it has no hydrolyzable functional group (Kollig, 1993).

운송 방법

UN2811 Toxic solids, organic, n.o.s., Hazard Class: 6.1; Labels: 6.1—Poisonous materials, Technical Name Required.

비 호환성

Incompatible with oxidizers (chlorates, nitrates, peroxides, permanganates, perchlorates, chlorine, bromine, fluorine, etc.); contact may cause fires or explosions. Keep away from alkaline materials, strong bases, strong acids, oxoacids, epoxides.

폐기물 처리

Residues and sorbent media may be packaged in 17H epoxy-lined drums and disposed of at an EPA-approved site. Destroy by permanganate oxidation, high-temperature incineration with scrubbing equipment, or microwave plasma treatment, if available. Confirm disposal procedures with responsible environmental engineer and regulatory officials.

벤조(B)플루란텐 준비 용품 및 원자재

원자재

준비 용품


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