사메틸 실란

사메틸 실란
사메틸 실란 구조식 이미지
카스 번호:
75-76-3
한글명:
사메틸 실란
동의어(한글):
사메틸실란;테트라메틸실레인;실레인, 테트라메틸;실레인, 테트라메틸-;테트라메틸 실리케인
상품명:
Tetramethylsilane
동의어(영문):
TMS;Silane, tetramethyl-;(CH3)4Si;Si(CH3)4;TetraMethylsilane, ACS reagent, NMR grade;4MS;CT2050;DKSI045;[for NMR];Four Methylsilane
CBNumber:
CB5854242
분자식:
C4H12Si
포뮬러 무게:
88.22
MOL 파일:
75-76-3.mol
MSDS 파일:
SDS

사메틸 실란 속성

녹는점
-99 °C (lit.)
끓는 점
26-28 °C (lit.)
밀도
0.648 g/mL at 25 °C (lit.)
증기압
11.66 psi ( 20 °C)
굴절률
n20/D 1.358(lit.)
RTECS 번호
VV5706000
인화점
−17 °F
저장 조건
2-8°C
용해도
0.02g/L
물리적 상태
액체
Specific Gravity
0.648
색상
무색의
폭발한계
1.0-37.9%(V)
수용성
0.02G/L(25℃)
Hydrolytic Sensitivity
1: no significant reaction with aqueous systems
Merck
14,9229
BRN
1696908
Dielectric constant
1.9199999999999999
안정성
안정적인. 가연성이 높음 - 공기와 쉽게 폭발성 혼합물을 형성합니다. 끓는점은 실온에 가깝고 인화점은 낮으며 증기압은 높습니다. 산화제와 호환되지 않습니다. 개봉하기 전에 냉장 보관하세요.
InChIKey
CZDYPVPMEAXLPK-UHFFFAOYSA-N
CAS 데이터베이스
75-76-3(CAS DataBase Reference)
NIST
Silane, tetramethyl-(75-76-3)
EPA
Tetramethylsilane (75-76-3)
안전
  • 위험 및 안전 성명
  • 위험 및 사전주의 사항 (GHS)
위험품 표기 Xn,F+
위험 카페고리 넘버 12-48/20/22-40-38-22
안전지침서 36-45-33-3/7-16-9-36/37
유엔번호(UN No.) UN 2810 6.1/PG 3
WGK 독일 3
F 고인화성물질 10
자연 발화 온도 842 °F
TSCA Yes
HS 번호 2931 90 00
위험 등급 3
포장분류 I
유해 물질 데이터 75-76-3(Hazardous Substances Data)
기존화학 물질 2014-3-5848
사고대비 물질 필터링 95
그림문자(GHS): GHS hazard pictograms
신호 어: Danger
유해·위험 문구:
암호 유해·위험 문구 위험 등급 범주 신호 어 그림 문자 P- 코드
H224 극인화성 액체 및 증기 인화성 액체 구분 1 위험
예방조치문구:
P210 열·스파크·화염·고열로부터 멀리하시오 - 금연 하시오.
P403+P233 용기는 환기가 잘 되는 곳에 단단히 밀폐하여 저장하시오.
NFPA 704
4
1 1

사메틸 실란 C화학적 특성, 용도, 생산

화학적 성질

Colorless clear liquid

용도

NMR reference standard. In semiconductor applications (chemical vapor deposition). Tetramethylsilane (TMS) is used as a chemical shift reference for proton, carbon-13, and silicon-29 analysis in organic solvents and is given 0 as its chemical shift position.

정의

ChEBI: Tetramethylsilane is an organosilicon compound that is silane in which the hydrogens have been replaced by methyl groups.

일반 설명

Tetramethylsilane appears as a colorless, mildly acidic volatile liquid. A serious fire hazard. Mildly toxic by ingestion. Emits acrid smoke and fumes when heated to high temperatures. Less dense than water and insoluble in water, but soluble in most organic solvents. Used as an aviation fuel and as an internal standard for nmr analytical instruments.

공기와 물의 반응

Highly flammable. Tetramethylsilane is insoluble in water.

반응 프로필

Hydrides, such as Tetramethylsilane, are reducing agents and react rapidly and dangerously with oxygen and with other oxidizing agents, even weak ones. Thus, they are likely to ignite on contact with alcohols. Hydrides are incompatible with acids, alcohols, amines, and aldehydes.

위험도

Flammable, high fire risk.

건강위험

May cause toxic effects if inhaled or absorbed through skin. Inhalation or contact with material may irritate or burn skin and eyes. Fire will produce irritating, corrosive and/or toxic gases. Vapors may cause dizziness or suffocation. Runoff from fire control or dilution water may cause pollution.

화재위험

HIGHLY FLAMMABLE: Will be easily ignited by heat, sparks or flames. Vapors may form explosive mixtures with air. Vapors may travel to source of ignition and flash back. Most vapors are heavier than air. They will spread along ground and collect in low or confined areas (sewers, basements, tanks). Vapor explosion hazard indoors, outdoors or in sewers. Runoff to sewer may create fire or explosion hazard. Containers may explode when heated. Many liquids are lighter than water.

Purification Methods

Distil it from conc H2SO4 (after shaking with it) or LiAlH4, through a 5ft vacuum-jacketed column packed with glass helices into an ice-cooled condenser, then percolate it through silica gel to remove traces of halide. [Beilstein 4 IV 3875.]

사메틸 실란 준비 용품 및 원자재

원자재

준비 용품


사메틸 실란 공급 업체

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Jiangsu Vcan Advanced Material Co., Ltd.
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Capot Chemical Co.,Ltd.
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Henan Tianfu Chemical Co.,Ltd.
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