아코니트산

아코니트산
아코니트산 구조식 이미지
카스 번호:
499-12-7
한글명:
아코니트산
동의어(한글):
아코니트산;아코니트산(ACONITICACID);프로펜-1,2,3-트리카르복실산
상품명:
Aconitic Acid
동의어(영문):
aconiticaci;ACONITIC ACID;citridinic acid;achilleaic acid;3-carboxyglutaconic acid;3-carboxy-2-pentenedioic acid;1-Propene-1,2,3-tricarboxylic acid;TRAN-1,2,3-PROPENE TRICARBOXYLIC ACID;Aconic acid;(1,2,3-Propenetricarboxylic acid)
CBNumber:
CB5928806
분자식:
C6H6O6
포뮬러 무게:
174.11
MOL 파일:
499-12-7.mol
MSDS 파일:
SDS

아코니트산 속성

녹는점
192°C (rough estimate)
끓는 점
225.05°C (rough estimate)
밀도
1.4285 (rough estimate)
굴절률
1.5860 (estimate)
FEMA
2010 | ACONITIC ACID
용해도
Soluble 16 % in water at 13 ℃, 33% in water at 25 ℃. Decomposes when heated to 200° C. Soluble in alcohol and most perfume and flavor materials, poorly soluble in hydrocarbons (Terpenes, etc.).
물리적 상태
Solid
산도 계수 (pKa)
2.39±0.36(Predicted)
색상
Colorless (white) crystal leaves or plates
냄새
건조하고 구운 뉘앙스가 있는 식물성, 곰팡내, 견과류 향
JECFA Number
627
LogP
0.63
EPA
1-Propene-1,2,3-tricarboxylic acid (499-12-7)

안전

유해 물질 데이터 499-12-7(Hazardous Substances Data)
독성 LD50 intravenous in mouse: 180mg/kg
기존화학 물질 KE-29440

아코니트산 C화학적 특성, 용도, 생산

화학적 성질

Aconitic acid has pleasant, winey, acid taste; almost odorless. Aconitic acid of the trans-configuration can be isolated during the processing of sugarcane by precipitating it as the calcium salt from cane syrup or molasses. The concentration in molasses ranges from 1.8 to 2.5%. Aconitic acid may be synthesized from citric acid by dehydration with sulfuric acid or by catalytic dehydration. The cis-configuration is somewhat unstable and is readily rearranged to the trans form by heating. Trans-aconitic acid is decarboxylated to itaconic acid by heating to 180°F. The cis form occurs in plant and animal tissues as a metabolic intermediate in the Krebs cycle during the isomerization of citric acid to isocitric acid by the action of enzyme aconitase

출처

Reported found in beet root, sugarcane, the leaves and tubers of Aconitum napellus, and other natural products (Pelargonium species).

용도

Aconitic Acid is a flavoring substance which occurs in the leaves and tubers of aconitum napellus l. And other ranunculaceae. Transaconitic acid can be isolated during sugar cane processing, by precipitation as the calcium salt from cane sugar or molasses. It may be synthesized by sulfuric acid dehydration of citric acid but not by the methanesulfonic acid method. It is used in a maximum level, as served, of 0.003% for baked goods, 0.002% for alcoholic beverages, 0.0015% for frozen dairy products, 0.0035% for soft candy, and 0.0005% or less for all other food categories.

정의

ChEBI: A tricarboxylic acid that is prop-1-ene substituted by carboxy groups at positions 1, 2 and 3.

제조 방법

By dehydration of citric acid with concentrated H2SO4: Aconitic acid prepared by this or other methods has the transconfiguration; the cis-isomer is little known. Trans-aconitic acid can be isolated during sugarcane processing by precipitation as the calcium salt from cane sugar or molasses.

아코니트산 준비 용품 및 원자재

원자재

준비 용품


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