시클로프로필페닐술파이드
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시클로프로필페닐술파이드 속성
- 끓는 점
- 62-63 °C/1 mmHg (lit.)
- 밀도
- 1.045 g/mL at 25 °C (lit.)
- 굴절률
- n
20/D 1.581(lit.)
- 인화점
- 197 °F
- 물리적 상태
- 투명한 액체
- 색상
- Colorless to Light yellow to Light orange
- BRN
- 2075701
- CAS 데이터베이스
- 14633-54-6(CAS DataBase Reference)
안전
- 위험 및 안전 성명
- 위험 및 사전주의 사항 (GHS)
| 위험품 표기 | Xi | ||
|---|---|---|---|
| 위험 카페고리 넘버 | 36/37/38 | ||
| 안전지침서 | 26-36/37/39 | ||
| 유엔번호(UN No.) | UN 2810 6.1/PG 3 | ||
| WGK 독일 | 3 | ||
| 위험 등급 | 9 | ||
| HS 번호 | 29309090 |
시클로프로필페닐술파이드 C화학적 특성, 용도, 생산
화학적 성질
CLEAR YELLOWISH LIQUID용도
Cyclopropyl phenyl sulfide was used as a reagent in the conversion of a ketone into a spirocyclobutanone.Synthesis Reference(s)
Synthetic Communications, 10, p. 311, 1980 DOI: 10.1080/00397918008062755Synthesis
Phenylthiocyclopropane is easily prepared from 1-phenylthio-3-chloropropane (itself obtained on reaction of 1-bromo- 3-chloropropane and phenylthiolates) and Potassium Amide in liquid ammonia (eq 1).
1,3-Bis(phenylthio)propane reacts with n-Butyllithium in THF to produce Phenylthiocyclopropane on reaction with only 1 equiv n-Buli, or 1-lithio-1-phenylthiocyclopropane (2) if 2 equiv are used (eq 2).
Phenylthiocyclopropane has also been synthesized from 3-tributylstannylpropanal (available from tributylstannyllithium and Acrolein) and trimethylsilyl phenyl sulfide in the presence of Titanium(IV) Chloride as acid catalyst (eq 3), and on substitution of (i) Cyclopropyllithium with Diphenyl Disulfide (eq 4), (ii) cyclopropyl bromide with potassium benzenethiolate (eq 5) or (iii) 1,1-dibromocyclopropane, also with benzenethiolates, and by reduction of α- bromocyclopropyl phenyl sulfide with sodium methanethiolate (eq 6). In addition, cyclopropyl phenyl sulfoxide can be reduced to (1) in more than 70% yield with Chlorotrimethylstannane-benzenethiol (eq 7).
시클로프로필페닐술파이드 준비 용품 및 원자재
원자재
준비 용품
시클로프로필페닐술파이드 공급 업체
글로벌( 163)공급 업체
| 공급자 | 전화 | 이메일 | 국가 | 제품 수 | 이점 |
|---|---|---|---|---|---|
| Henan Fengda Chemical Co., Ltd | +86-371-86557731 +86-13613820652 |
info@fdachem.com | China | 20267 | 58 |
| Capot Chemical Co.,Ltd. | +86-（0）57185586718 +86-13336195806 |
sales@capot.com | China | 29793 | 60 |
| Shanghai Daken Advanced Materials Co.,Ltd | +86-371-66670886 |
info@dakenam.com | China | 18940 | 58 |
| Shanghai Time Chemicals CO., Ltd. | +86-021-57951555 +8617317452075 |
jack.li@time-chemicals.com | China | 1803 | 55 |
| CONIER CHEM AND PHARMA LIMITED | +8618523575427 |
sales@conier.com | China | 49374 | 58 |
| Richest Group Ltd | 18017061086 |
oled@richest-group.com | CHINA | 5600 | 58 |
| Antai Fine Chemical Technology Co.,Limited | 18503026267 |
info@antaichem.com | CHINA | 9636 | 58 |
| Hefei TNJ Chemical Industry Co.,Ltd. | +86-0551-65418671 +8618949823763 |
sales@tnjchem.com | China | 34563 | 58 |
| Dayang Chem (Hangzhou) Co.,Ltd. | 571-88938639 +8617705817739 |
info@dycnchem.com | China | 52849 | 58 |
| CD Chemical Group Limited | +8615986615575 |
info@codchem.com | China | 20342 | 58 |
시클로프로필페닐술파이드 관련 검색:
시클로프로필페닐술파이드
AKOS BRN-0446
CYCLOPROPYLDIPHENYLSULFONIUM TETRAFLUOROBORATE
2,2-DICHLOROCYCLOPROPYL PHENYL SULFONE
2,2-DICHLOROCYCLOPROPYL PHENYL SULFIDE
1-[(4-CHLOROPHENYL)SULFONYL]CYCLOPROPANECARBOXYLIC ACID
1-(3,4-DIMETHYL-BENZENESULFONYL)-CYCLOPROPANECARBOXYLIC ACID
1-(phenylsulfonyl)cyclopropanecarboxylic acid
1-(TRIMETHYLSILYL)CYCLOPROPYL PHENYL SULFIDE
RARECHEM AQ TC 8004
SALOR-INT L168947-1EA
1-[(3,4-difluorophenyl)sulfonyl]cyclopropanecarboxylic acid
1-[(2,4-dimethylphenyl)sulfonyl]cyclopropanecarboxylic acid
1-(PHENYLSULFONYL)CYCLOPROPANECARBONITRILE
2,2-DIACETYL-3-(4-CHLOROPHENYL)-1-(PHENYLSULFONYL)CYCLOPROPANECARBONITRILE
RARECHEM AQ TC 9006
1-((4-CHLOROPHENYL)SULFONYL)CYCLOPROPANECARBONITRILE
RARECHEM AQ TC 8001