ChemicalBook >제품 카탈로그 >화학 시약>유기 시약>포스 핀 리간드>(R)-1-[(1S)-2-(DICYCLOHEXYLPHOSPHINO)FERROCENYL]ETHYLDI-PHENYLPHOSPHINE

(R)-1-[(1S)-2-(DICYCLOHEXYLPHOSPHINO)FERROCENYL]ETHYLDI-PHENYLPHOSPHINE

(R)-1-[(1S)-2-(DICYCLOHEXYLPHOSPHINO)FERROCENYL]ETHYLDI-PHENYLPHOSPHINE 구조식 이미지

카스 번호:: 158923-09-2

상품명:: (R)-1-[(1S)-2-(DICYCLOHEXYLPHOSPHINO)FERROCENYL]ETHYLDI-PHENYLPHOSPHINE

동의어(영문):: OSIPHOS SL-J004-1;JOSIPHOS SL-J004-1;(R)1[(1S)2(di-C-hex;(R)1 (1S)2(DI-C-HEXYLPHOSPHINO)FERROCEN&;(R)-1-[(1S)-2-(DICYCLOHEXYLPHOSPHINO)FERROCENYL]ET;(R)1[(1S)2(di-C-hexylphosphino)ferrocen. ]et-diphenylphosphin;R)-(-)-1-[(S)-2-(Dicyclohexylphosphino)ferrocenyl]ethyldiphe...;(R)-1-[(R)-2-(Dicyclohexylphosphino)ferrocenylethyl]diphenylphosphine;(R)-1-[(SP)-2-(Dicyclohexylphosphino)ferrocenylethyl]diphenylphosphine;(R,R)-1-(DICYCLOHEXYLPHOSPHINO)-2-[1-(DIPHENYLPHOSPHINO)ETHYL]FERROCENE

CBNumber:: CB7211931

분자식:: C36H44FeP210*

포뮬러 무게:: 594.53

MOL 파일:: 158923-09-2.mol

MSDS 파일:: SDS

속성

안전

용도

공급 업체 63

(R)-1-[(1S)-2-(DICYCLOHEXYLPHOSPHINO)FERROCENYL]ETHYLDI-PHENYLPHOSPHINE 속성

알파: -100° ±5° (c 0.5, CHCl3)

저장 조건: under inert gas (nitrogen or Argon) at 2-8°C

물리적 상태: 가루

색상: 오렌지 레드

색상: 오렌지색

안전

위험 및 안전 성명
위험 및 사전주의 사항 (GHS)

위험 카페고리 넘버	36/37/38
안전지침서	26-36/37/39
WGK 독일	3
F 고인화성물질	10
HS 번호	29319090

그림문자(GHS):

신호 어:

Warning

유해·위험 문구:

암호	유해·위험 문구	위험 등급	범주	신호 어	P- 코드
H302	삼키면 유해함	급성 독성 물질 - 경구	구분 4	경고	P264, P270, P301+P312, P330, P501
H315	피부에 자극을 일으킴	피부부식성 또는 자극성물질	구분 2	경고	P264, P280, P302+P352, P321,P332+P313, P362
H319	눈에 심한 자극을 일으킴	심한 눈 손상 또는 자극성 물질	구분 2A	경고	P264, P280, P305+P351+P338,P337+P313P
H335	호흡 자극성을 일으킬 수 있음	특정 표적장기 독성 - 1회 노출;호흡기계 자극	구분 3	경고

예방조치문구:

P261	분진·흄·가스·미스트·증기·...·스프레이의 흡입을 피하시오.
P280	보호장갑/보호의/보안경/안면보호구를 착용하시오.
P301+P312	삼켜서 불편함을 느끼면 의료기관(의사)의 진찰을 받으시오.
P302+P352	피부에 묻으면 다량의 물로 씻으시오.
P305+P351+P338	눈에 묻으면 몇 분간 물로 조심해서 씻으시오. 가능하면 콘택트렌즈를 제거하시오. 계속 씻으시오.

(R)-1-[(1S)-2-(DICYCLOHEXYLPHOSPHINO)FERROCENYL]ETHYLDI-PHENYLPHOSPHINE C화학적 특성, 용도, 생산

화학적 성질

Red crystal

용도

(R)-1-[(S_P)-2-(Dicyclohexylphosphino)ferrocenylethyl]diphenylphosphine can be used as a ligand:

To prepare iridium metal complex (Ir^IJOSIPHOS), which is used as a catalyst in the asymmetric hydrogenation of 2-phenylquinoxaline.
In the preparation of natural products by asymmetric conjugate addition of Grignard reagents to α-substituted cyclic alkenones.

화학 반응

1. Ligand for asymmetric hydroformylation reactions
2. Ligand for asymmetric intramolecular amide arylation
3. Ligand for enantioselective 1,6-conjugate addition of Grignard reagents to linear dienolates
4. Ligand for enantioselective synthesis of vicinal dialkyl arrays
5. Ligand for asymmetric conjugate addition of Grignard reagents to chromones .
Reactions of 158923-09-2

일반 설명

sold in collaboration with Solvias AG

(R)-1-[(1S)-2-(DICYCLOHEXYLPHOSPHINO)FERROCENYL]ETHYLDI-PHENYLPHOSPHINE 준비 용품 및 원자재

원자재

준비 용품

(R)-1-[(1S)-2-(DICYCLOHEXYLPHOSPHINO)FERROCENYL]ETHYLDI-PHENYLPHOSPHINE 공급 업체

글로벌( 63)공급 업체

공급자	전화	이메일	국가	제품 수	이점
XINXIANG RUNYU MATERIAL CO., LTD.	+86-13592593621; +8613592593621	sales@runvmat.com	China	432	58
Changzhou Ansciep Chemical Co., Ltd.	+86 519 86305871	sales@ansciepchem.com	CHINA	4242	58
AFINE CHEMICALS LIMITED	+86-0571-85134551	info@afinechem.com	China	15395	58
Dayang Chem (Hangzhou) Co.,Ltd.	571-88938639 +8617705817739	info@dycnchem.com	China	52861	58
Hefei TNJ Chemical Industry Co.,Ltd.	0551-65418684 +8618949823763	sales@tnjchem.com	China	25363	58
Hangzhou MolCore BioPharmatech Co.,Ltd.	+86-057181025280; +8617767106207	sales@molcore.com	China	49739	58
PT CHEM GROUP LIMITED	+86-85511178 +86-85511178	peter68@ptchemgroup.com	China	35426	58
GIHI CHEMICALS CO.,LIMITED	+8618058761490	info@gihichemicals.com	China	49999	58
Shaoxin Catsyn Co., Ltd.	+undefined-0575-82040869 +86-0575-82040869;	sales@catsyn.com	China	6116	58
J & K SCIENTIFIC LTD.	010-82848833 400-666-7788	jkinfo@jkchemical.com	China	96815	76

(R)-1-[(1S)-2-(DICYCLOHEXYLPHOSPHINO)FERROCENYL]ETHYLDI-PHENYLPHOSPHINE 관련 검색:

ETHYLDIPHENYLPHOSPHINE (S)-1-[(1R)-2-(DICYCLOHEXYLPHOSPHINO)FERROCENYL]ETHYLDI-PHENYLPHOSPHINE (R)-1-[(1S)-2-(DICYCLOHEXYLPHOSPHINO)FERROCENYL]ETHYLDI-PHENYLPHOSPHINE 1,3-BIS(DIMETHYLPHOSPHINO)PROPANE DICYCLOHEXYLPHOSPHINE 1,3-BIS(PHOSPHINO)PROPANE TRIISOPROPYLPHOSPHINE TRIHEXYLPHOSPHINE