시스헥세놀
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시스헥세놀 속성
- 녹는점
- 22.55°C (estimate)
- 끓는 점
- 156-157 °C(lit.)
- 밀도
- 0.848 g/mL at 25 °C(lit.)
- 증기 밀도
- 3.45 (vs air)
- 증기압
- 2.26hPa at 25℃
- 굴절률
- n
20/D 1.44(lit.)
- FEMA
- 2563 | CIS-3-HEXENOL
- 인화점
- 112 °F
- 저장 조건
- Flammables area
- 용해도
- DMSO: 100 mg/mL (998.40 mM)
- 물리적 상태
- 액체
- 산도 계수 (pKa)
- 15.00±0.10(Predicted)
- Specific Gravity
- 0.848 (20/4℃)
- 색상
- APHA: ≤100
- 냄새
- 디프로필렌 글리콜 중 10.00%. 신선한 녹색 컷 잔디 잎 야채 허브 기름진
- ?? ??
- 녹색
- 수용성
- 불용성
- Merck
- 14,4700
- JECFA Number
- 315
- BRN
- 1719712
- 안정성
- 안정적인. 피해야 할 물질에는 강산화제와 강산이 포함됩니다. 가연성.
- LogP
- 1 at 35℃
- CAS 데이터베이스
- 928-96-1(CAS DataBase Reference)
안전
- 위험 및 안전 성명
- 위험 및 사전주의 사항 (GHS)
| 위험품 표기 | F | ||
|---|---|---|---|
| 위험 카페고리 넘버 | 10 | ||
| 안전지침서 | 16 | ||
| 유엔번호(UN No.) | UN 1987 3/PG 3 | ||
| WGK 독일 | 1 | ||
| RTECS 번호 | MP8400000 | ||
| F 고인화성물질 | 10 | ||
| TSCA | Yes | ||
| 위험 등급 | 3 | ||
| 포장분류 | III | ||
| HS 번호 | 29052990 | ||
| 유해 물질 데이터 | 928-96-1(Hazardous Substances Data) | ||
| 독성 | The acute oral LD50 value in rats was reported as 4.70 g/kg (3.82-5.58 g/kg) (Moreno, 1973). The acute dermal LD50 value in rabbits was reported as > 5 g/kg (Moreno, 1973). | ||
| 기존화학 물질 | KE-19874 |
시스헥세놀 C화학적 특성, 용도, 생산
개요
Leaf alcohol exists as a liquid at room temperature with a characteristic odor of green leaves. It is found in green tea, violet leaf oil, and many types of leaves, herbs, and grasses. Leaf alcohol finds applications in perfumery as floral fragrance. Leaf alcohol is also investigated for its antidiabetic activity.화학적 성질
Leaf Alcohol is a colorless liquid with the characteristic odor of freshly cut grass. In small quantities, leaf alcohol occurs in the green parts of nearly all plants. The volatile flavor constituents of green tea contain up to 30%.A stereospecific synthesis of (Z)-3-hexen-1-ol starts with the ethylation of sodium acetylide to 1-butyne, which is reacted with ethylene oxide to give 3-hexyn-1-ol. Selective hydrogenation of the triple bond in the presence of palladium catalysts yields (Z)-3-hexen-1-ol. Biotechnological processes have been developed for its synthesis as a natural flavor compound, for example.
Leaf alcohol is used to obtain natural green top notes in perfumes and flavors. In addition, it is the starting material for the synthesis of (2E,6Z)-2,6-nonadien-l-ol and (2E,6Z)-2,6-nonadien-l-al.
출처
Main constituent of the oil distilled from the infusion of fermented tea leaves. Reported found as the corresponding ester of phenylacetic acid in the oil of Japanese mint (Mentha arvensis); the volatile oil of Thea chinensis contains approximately 26 to 35% 3-hexen-1-ol, whereas larger amounts are reported in the oils of Morus bombysic, Robinia pseudacacia and Raphanus sativus. Probably occurring also in several green leaves and herbs; reported found in the fruit juices of raspberry, grapefruit and others. Also reported in over 200 foods including apple, apricot, banana, citrus peel oils and juices, berries, guava, mango, grapes, pineapple, cabbage, kohlrabi, celery, cucumber, lettuce, leek, peas, sauerkraut, tomato, ginger, peppermint oil, coconut oil, spearmint oil, mustard, parsley, breads, butter, fish, fish oil, cognac, brandy, cider, sherry, grape wines, tea, soybeans, avocado, olive, passion fruit, plum, rose apple, Malay apple, water apple (Syzigium spp.), beans, marjoram, starfruit, broccoli, pear and apple brandies, figs, brussels sprouts, radish, prickly pear, litchi, dill, lovage, pumpkin, corn oil, malt, laurel, kiwifruit and other sources제조 방법
By the reaction of butyne-1 with ethylene oxide and subsequent selective reduction to the eis isomer (Bedoukian, 1967).정의
ChEBI: A primary alcohol that consists of (3Z)-hex-3-ene substituted by a hydroxy group at position 1.일반 설명
cis-3-Hexen-1-ol is one of the key volatile constituents of green leaf volatiles(GLV) that can act as an attractant to various insects. It is emitted by green plants when they are physically damaged.참고 문헌
[1] NPCS Board of Consultants & Engineers, Industrial Alcohol of Technology Handbook, 2010[2] A. Shirwaikar, K. Rajendran and C. Kumar, Oral Antidiabetic Activity of Annona squamosa Leaf Alcohol Extract in NIDDM Rats, Pharmaceutical Biology, 2004, vol. 42, 30-35
시스헥세놀 준비 용품 및 원자재
원자재
아세틸화나트륨
에틸 아세틸렌
나트륨
헥신(1-)-3-올
헥신(3-)
트리페닐포스핀
리튬
암모니아(가스)
TRANS-3-HEXEN-1-OL
5,6-디하이드로-2-메틸-2H-피란
(E)-4-헥센-1-올
TRANS-3-HEXEN-1-OL
준비 용품
cis-3-Hexenyl formate
FEMA 3498
1-HEXEN-3-YL ACETATE
cfs-3-trans-2-Hexenyl propionate(mixtme)
cis-3-Hexenai
cis-3-Hexenyl 2-methylbutanoate
CIS-3-HEXENYL BUTYRATE
노난디엔(트란스,시스-2,6)-1-올
CIS-3-HEXENOIC ACID
3-시스-헥세닐메틸카보네이트
CIS-5,8,11,14,17-EICOSAPENTAENOIC ACID METHYL ESTER
cis-3-Hexenyl benzoate
(Z)-1-메톡시헥스-3-엔
시스헥세놀 공급 업체
글로벌( 519)공급 업체
| 공급자 | 전화 | 이메일 | 국가 | 제품 수 | 이점 |
|---|---|---|---|---|---|
| Henan Xiangduo Industry Co., Ltd. | +86-15981848961 +86-15981848961 |
sales@xiangduochem.com | China | 497 | 58 |
| Shandong Deshang Chemical Co., Ltd. | +86-0531-8875-2665 +8613153039501 |
info@deshangchem.com | China | 662 | 58 |
| Hebei Weibang Biotechnology Co., Ltd | +8615531157085 |
abby@weibangbio.com | China | 8810 | 58 |
| Hebei Chuanghai Biotechnology Co,.LTD | +86-13131129325 |
sales1@chuanghaibio.com | China | 5892 | 58 |
| Henan Fengda Chemical Co., Ltd | +86-371-86557731 +86-13613820652 |
info@fdachem.com | China | 20287 | 58 |
| Hebei Zhuanglai Chemical Trading Co.,Ltd | +8613343047651 |
admin@zlchemi.com | China | 3002 | 58 |
| JINING XINHE CHEMICAL CO., LTD | +8615318402391 |
sales@xinhepharma.com | China | 809 | 58 |
| Henan Tianfu Chemical Co.,Ltd. | +86-0371-55170693 +86-19937530512 |
info@tianfuchem.com | China | 21634 | 55 |
| Hangzhou FandaChem Co.,Ltd. | +8615858145714 |
FandaChem@Gmail.com | China | 9209 | 55 |
| Shanxi Naipu Import and Export Co.,Ltd | +86-13734021967 +8613734021967 |
kaia@neputrading.com | China | 1001 | 58 |