시스헥세놀

시스헥세놀
시스헥세놀 구조식 이미지
카스 번호:
928-96-1
한글명:
시스헥세놀
동의어(한글):
시스-3-헥센-1-올;시스-3-헥센올;시스헥세놀;시스-3-헥센올(CIS-3-HEXENOL);3-헥센올;잎알코올
상품명:
Leaf alcohol
동의어(영문):
CIS-3-HEXENOL;(Z)-3-Hexen-1-ol;CIS-3-HEXEN-1-OL;(Z)-Hex-3-en-1-ol;(3Z)-3-Hexen-1-ol;Z-3-Hexenol;cis-Hex-3-en-1-ol;FEMA 2563;(z)-3-hexen-1-o;C3 LEAF ALCOHOL
CBNumber:
CB8723819
분자식:
C6H12O
포뮬러 무게:
100.16
MOL 파일:
928-96-1.mol

시스헥세놀 속성

녹는점
22.55°C (estimate)
끓는 점
156-157 °C(lit.)
밀도
0.848 g/mL at 25 °C(lit.)
증기 밀도
3.45 (vs air)
증기압
2.26hPa at 25℃
굴절률
n20/D 1.44(lit.)
FEMA
2563 | CIS-3-HEXENOL
인화점
112 °F
저장 조건
Flammables area
용해도
DMSO: 100 mg/mL (998.40 mM)
물리적 상태
액체
산도 계수 (pKa)
15.00±0.10(Predicted)
Specific Gravity
0.848 (20/4℃)
색상
APHA: ≤100
냄새
디프로필렌 글리콜 중 10.00%. 신선한 녹색 컷 잔디 잎 야채 허브 기름진
?? ??
녹색
수용성
불용성
Merck
14,4700
JECFA Number
315
BRN
1719712
안정성
안정적인. 피해야 할 물질에는 강산화제와 강산이 포함됩니다. 가연성.
LogP
1 at 35℃
CAS 데이터베이스
928-96-1(CAS DataBase Reference)
NIST
3-Hexen-1-ol, (Z)-(928-96-1)
EPA
(Z)-3-Hexen-1-ol (928-96-1)
안전
  • 위험 및 안전 성명
  • 위험 및 사전주의 사항 (GHS)
위험품 표기 F
위험 카페고리 넘버 10
안전지침서 16
유엔번호(UN No.) UN 1987 3/PG 3
WGK 독일 1
RTECS 번호 MP8400000
F 고인화성물질 10
TSCA Yes
위험 등급 3
포장분류 III
HS 번호 29052990
유해 물질 데이터 928-96-1(Hazardous Substances Data)
독성 The acute oral LD50 value in rats was reported as 4.70 g/kg (3.82-5.58 g/kg) (Moreno, 1973). The acute dermal LD50 value in rabbits was reported as > 5 g/kg (Moreno, 1973).
기존화학 물질 KE-19874
그림문자(GHS): GHS hazard pictograms
신호 어: Warning
유해·위험 문구:
암호 유해·위험 문구 위험 등급 범주 신호 어 그림 문자 P- 코드
H226 인화성 액체 및 증기 인화성 액체 구분 3 경고
예방조치문구:
P210 열·스파크·화염·고열로부터 멀리하시오 - 금연 하시오.
P240 용기와 수용설비를 접지 및 접합시키시오.
P241 폭발 방지용 장비[전기적/환기/조명/...]을(를) 사용하시오.
P303+P361+P353 피부(또는 머리카락)에 묻으면 오염된 모든 의복은 벗거나 제거하시오 피부를 물로 씻으시오/샤워하시오.
NFPA 704
2
1 0

시스헥세놀 MSDS


Leaf alcohol

시스헥세놀 C화학적 특성, 용도, 생산

개요

Leaf alcohol exists as a liquid at room temperature with a characteristic odor of green leaves. It is found in green tea, violet leaf oil, and many types of leaves, herbs, and grasses. Leaf alcohol finds applications in perfumery as floral fragrance. Leaf alcohol is also investigated for its antidiabetic activity.

화학적 성질

Leaf Alcohol is a colorless liquid with the characteristic odor of freshly cut grass. In small quantities, leaf alcohol occurs in the green parts of nearly all plants. The volatile flavor constituents of green tea contain up to 30%.
A stereospecific synthesis of (Z)-3-hexen-1-ol starts with the ethylation of sodium acetylide to 1-butyne, which is reacted with ethylene oxide to give 3-hexyn-1-ol. Selective hydrogenation of the triple bond in the presence of palladium catalysts yields (Z)-3-hexen-1-ol. Biotechnological processes have been developed for its synthesis as a natural flavor compound, for example.
Leaf alcohol is used to obtain natural green top notes in perfumes and flavors. In addition, it is the starting material for the synthesis of (2E,6Z)-2,6-nonadien-l-ol and (2E,6Z)-2,6-nonadien-l-al.

출처

Main constituent of the oil distilled from the infusion of fermented tea leaves. Reported found as the corresponding ester of phenylacetic acid in the oil of Japanese mint (Mentha arvensis); the volatile oil of Thea chinensis contains approximately 26 to 35% 3-hexen-1-ol, whereas larger amounts are reported in the oils of Morus bombysic, Robinia pseudacacia and Raphanus sativus. Probably occurring also in several green leaves and herbs; reported found in the fruit juices of raspberry, grapefruit and others. Also reported in over 200 foods including apple, apricot, banana, citrus peel oils and juices, berries, guava, mango, grapes, pineapple, cabbage, kohlrabi, celery, cucumber, lettuce, leek, peas, sauerkraut, tomato, ginger, peppermint oil, coconut oil, spearmint oil, mustard, parsley, breads, butter, fish, fish oil, cognac, brandy, cider, sherry, grape wines, tea, soybeans, avocado, olive, passion fruit, plum, rose apple, Malay apple, water apple (Syzigium spp.), beans, marjoram, starfruit, broccoli, pear and apple brandies, figs, brussels sprouts, radish, prickly pear, litchi, dill, lovage, pumpkin, corn oil, malt, laurel, kiwifruit and other sources

제조 방법

By the reaction of butyne-1 with ethylene oxide and subsequent selective reduction to the eis isomer (Bedoukian, 1967).

정의

ChEBI: A primary alcohol that consists of (3Z)-hex-3-ene substituted by a hydroxy group at position 1.

일반 설명

cis-3-Hexen-1-ol is one of the key volatile constituents of green leaf volatiles(GLV) that can act as an attractant to various insects. It is emitted by green plants when they are physically damaged.

참고 문헌

[1] NPCS Board of Consultants & Engineers, Industrial Alcohol of Technology Handbook, 2010
[2] A. Shirwaikar, K. Rajendran and C. Kumar, Oral Antidiabetic Activity of Annona squamosa Leaf Alcohol Extract in NIDDM Rats, Pharmaceutical Biology, 2004, vol. 42, 30-35

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