1-아이오도-4-니트로벤젠
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1-아이오도-4-니트로벤젠 속성
- 녹는점
- 171-173 °C(lit.)
- 끓는 점
- 289 °C772 mm Hg(lit.)
- 인화점
- 100 °C
- CAS 데이터베이스
- 30306-69-5(CAS DataBase Reference)
안전
위험품 표기 | Xn | ||
---|---|---|---|
위험 카페고리 넘버 | 20/21/22-36/37/38 | ||
안전지침서 | 26-37/39 | ||
유엔번호(UN No.) | UN 2811 6.1/PG 2 | ||
WGK 독일 | 3 |
1-아이오도-4-니트로벤젠 C화학적 특성, 용도, 생산
제조 방법
Preparation of 1-iodo-4-nitrobenzene from 4-Nitroaniline.Principle: Diazonium salts undergo a large number of reactions in which the diazo group is lost as molecular nitrogen and is replaced by variety of other groups (e.g. OH, I, Br, Cl, F, CN, NO2, H, SO2H, Ar) which become attached to the aromatic ring.
Reaction:
![Preparation of 1-iodo-4-nitrobenzene from 4-Nitroaniline](https://www.chemicalbook.com/NewsImg/2020-03-19/20203191610912602.png)
Procedure: Take 0.5 g p-nitro aniline, 0.41 ml conc. H2SO4 and 3 ml water in a conical flask. Stir it well and cool to 0-5°C. Add a cold solution of 0.25 g NaNO2 in 0.75 ml distilled water to the above solution. Filter the resultant cold solution, and add the filtrate with stirring to a solution of 1 g KI in 3 ml water taken in a beaker. Filter the product separated out and wash it with water. Dry the product, record the practical yield and re-crystallize it.
Re-crystallization: Dissolve the crude product in minimum amount of ethyl alcohol in a beaker by heating on a water bath. Filter the hot solution and cool the filtrate. The shiny brown crystals of p-iodo nitro benzene separate out. Filter, dry and record the melting point and TLC (using toluene as a solvent).
Synthesis Reference(s)
Journal of the American Chemical Society, 83, p. 1928, 1961 DOI: 10.1021/ja01469a036The Journal of Organic Chemistry, 33, p. 3670, 1968 DOI: 10.1021/jo01273a083
1-아이오도-4-니트로벤젠 준비 용품 및 원자재
원자재
준비 용품
1-아이오도-4-니트로벤젠 공급 업체
글로벌( 41)공급 업체
공급자 | 전화 | 이메일 | 국가 | 제품 수 | 이점 |
---|---|---|---|---|---|
Shaanxi Dideu Medichem Co. Ltd | +86-029-81138252 +86-18789408387 |
1057@dideu.com | China | 2852 | 58 |
CONIER CHEM AND PHARMA LIMITED | +8618523575427 |
sales@conier.com | China | 49391 | 58 |
WinWin Chemical CO., Limited | +86-0577-64498589 +8615325081899 |
sales@win-winchemical.com | China | 14197 | 58 |
Amadis Chemical Company Limited | 571-89925085 |
sales@amadischem.com | China | 131980 | 58 |
Mainchem Co., Ltd. | +86-0592-6210733 |
sale@mainchem.com | China | 32360 | 55 |
Beijing Ouhe Technology Co., Ltd | 010-82967028 13552068683 |
2355560935@qq.com | China | 12458 | 60 |
Chongqing Xingcan Pharmaceutical Technology Co., Ltd. | 15523000485 |
xingcanyaoye@sina.com | China | 1686 | 58 |
Shanghai Synchem Pharma Co., ltd | 21-619849051-1 18521059765 |
synchempharma@aliyun.com | China | 6457 | 55 |
Cool Pharm, Ltd | 18019463053 |
sales@coolpharm.com | China | 13017 | 58 |
Ningbo jinuo chemical co., LTD | 0574-87314919 057487319282 |
info@nbinno.com | China | 7027 | 58 |
1-아이오도-4-니트로벤젠 관련 검색:
1-Iodo-4-nitrobenzene
N,N'-Bis(2,3-dihydroxypropyl)-5-nitro-1,3-benzenedicarboxamide
3-CHLORO-4-IODONITROBENZENE
3,5-DICHLORO-4-IODONITROBENZENE
2,4-Dinitroiodobenzene
3-FLUORO-4-IODONITROBENZENE
2-IODO-5-NITROANISOLE
2-IODO-5-NITROTOLUENE
1-Iodo-4-nitrobenzene
1-Iodo-3-nitrobenzene
1-Iodo-2-nitrobenzene
1,3-DIBROMO-2-IODO-5-NITROBENZENE
4-IODO-2-METHYL-1-NITROBENZENE
5-IODO-2-NITROBENZOIC ACID
5-IODO-2-NITROBENZOTRIFLUORIDE
2-IODO-5-NITROBENZOIC ACID
(R)-3-(2-IODO-5-NITROBENZOYL)-1-(1-METHYL-2-PIPERIDINYLMETHYL)-1H-INDOLE
(2-IODO-5-NITRO-PHENYL)-PHENYL-METHANONE