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ChemicalBook >> CAS DataBase List >>1,4-DINITROBENZENE

1,4-DINITROBENZENE suppliers

1,4-DINITROBENZENE

CAS:
100-25-4
MF:
C6H4N2O4
MW:
168.11

Properties

Melting point:
170-173 °C(lit.)
Boiling point:
183.4 °C34 mm Hg(lit.)
Density 
1.625 g/mL at 25 °C(lit.)
vapor pressure 
2.25 x 10-4 mmHg at 35 °C (Hine et al., 1963)
refractive index 
1.725 (589.3 nm)
Flash point:
150 °C
storage temp. 
Store below +30°C.
solubility 
alcohol: soluble1g in 300ml
form 
Crystals or Powder
color 
Ochre to orange
Water Solubility 
Soluble in water. (0.8 g/L) at 20°C.
Merck 
14,3273
BRN 
1105828
Henry's Law Constant
4.79(x 10-7 atm?m3/mol) at 35 °C (approximate - calculated from water solubility and vapor pressure)
Exposure limits
NIOSH REL: TWA 1, IDLH 50; OSHA PEL: TWA 1 ACGIH TLV: TWA 0.15 ppm for all isomers (adopted).
Stability:
Stable, but may be shock-sensitive. May explode if heated. Incompatible with oxidizing agents, strong bases, nitric acid, many metals, tin oxides.

Safety Information

Symbol(GHS) 
GHS hazard pictogramsGHS hazard pictogramsGHS hazard pictograms
GHS06,GHS08,GHS09
Signal word 
Danger
Hazard statements 
H300+H310+H330-H373-H410
Precautionary statements 
P262-P264-P273-P280-P302+P352+P310-P304+P340+P310
Hazard Codes 
T+,N,T,F
Risk Statements 
26/27/28-33-34-50/53-52/53-39/23/24/25-23/24/25-11
Safety Statements 
28-36/37-45-60-61-16
RIDADR 
UN 3443 6.1/PG 2
OEB
C
OEL
TWA: 1 mg/m3 [skin]
WGK Germany 
3
RTECS 
CZ7525000
TSCA 
Yes
HazardClass 
6.1
PackingGroup 
II
HS Code 
29042090
Toxicity
IC50 (24-h) for river bacteria 1.27 mg/L (Yuan and Lang, 1997).

Use

Crystallise 1,4-dinitrobenzene from EtOH or EtOAc. Dry it under vacuum over P2O5. It can be sublimed in a vacuum. [Beilstein 5 IV 741.]

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