AMMONIUM IRON (III) HEXACYANOFERRATE (II) manufacturers and suppliers

AMMONIUM IRON (III) HEXACYANOFERRATE (II) suppliers

AMMONIUM IRON (III) HEXACYANOFERRATE (II)

CAS:: 25869-00-5

MF:: C6H4Fe2N7

MW:: 285.84

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Properties

RTECS: LJ8140000

Water Solubility: Soluble in water and mineral acids. Insoluble in alkali.

Merck: 14,7910

Exposure limits: ACGIH: TWA 1 mg/m3
NIOSH: IDLH 25 mg/m3; TWA 1 mg/m3

LogP: -0.250 (est)

Safety Information

Hazard statements: H402-H412

Risk Statements: 20/21/22

Safety Statements: 22-36/37/39

TSCA: Yes

Toxicity: LD50 orally in mice: >5 g/kg (Pearce)

Use

AMMONIUM IRON (III) HEXACYANOFERRATE (II) is an inorganic cyanide. Inorganic cyanides react slowly with water to evolve gaseous hydrogen cyanide (HCN). Acids cause the rapid evolution of HCN; carbon dioxide from the air is sufficiently acidic to liberate HCN from solutions of cyanides. Inorganic cyanides are incompatible with isocyanates, nitrides, and peroxides. Cyanides have been known to initiate polymerization reactions of epoxides. Cyanides form compounds with metal salts; heat and hydrogen production may accompany these reactions. Some cyanides can detonate when exposed to shock, heat, or friction. In the presence of strong acids or acid fumes may release highly toxic fumes of cyanides.

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