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ChemicalBook >> CAS DataBase List >> 1,3,2-Dioxaborolane, 2-(dichloroMethyl)-4,4,5,5-tetraMethyl-

1,3,2-Dioxaborolane, 2-(dichloroMethyl)-4,4,5,5-tetraMethyl-

1,3,2-Dioxaborolane, 2-(dichloroMethyl)-4,4,5,5-tetraMethyl- price.
  • $206 - $3980
  • Product name: 1,3,2-Dioxaborolane, 2-(dichloroMethyl)-4,4,5,5-tetraMethyl-
  • CAS: 83622-41-7
  • MF: C7H13BCl2O2
  • MW: 210.89
  • EINECS:-0
  • MDL Number:MFCD27976342
  • Synonyms:1,3,2-Dioxaborolane, 2-(dichloroMethyl)-4,4,5,5-tetraMethyl-;Dichloromethyl pinacolboronate;Pinacol (dichloromethyl) boronate >=95%;2-(Dichloromethyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane(WS203860);(Dichloromethyl)boronic Acid Pinacol Ester;2-(dichloromethyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane;Pinacol (dichloromethyl) boronate
6 prices
Selected condition:
Brand
  • Biosynth Carbosynth
  • Chemenu
  • JR MediChem
  • Sigma-Aldrich
Package
  • 1g
  • 2g
  • 5G
  • 100g
  • ManufacturerBiosynth Carbosynth
  • Product numberFD137449
  • Product descriptionDichloromethyl pinacolboronate
  • Packaging2g
  • Price$600
  • Updated2021-12-16
  • Buy
  • ManufacturerBiosynth Carbosynth
  • Product numberFD137449
  • Product descriptionDichloromethyl pinacolboronate
  • Packaging5G
  • Price$1000
  • Updated2021-12-16
  • Buy
  • ManufacturerChemenu
  • Product numberCM329406
  • Product description2-(dichloromethyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane 95%+
  • Packaging1g
  • Price$1288
  • Updated2021-12-16
  • Buy
  • ManufacturerJR MediChem
  • Product numberJR6-L9521
  • Product descriptionPinacol (dichloromethyl) boronate
  • Packaging100g
  • Price$3980
  • Updated2021-12-16
  • Buy
  • ManufacturerSigma-Aldrich
  • Product number901062
  • Product descriptionPinacol (dichloromethyl) boronate ≥95%
  • Packaging1g
  • Price$206
  • Updated2024-03-01
  • Buy
  • ManufacturerSigma-Aldrich
  • Product number901062
  • Product descriptionPinacol (dichloromethyl) boronate ≥95%
  • Packaging5g
  • Price$675
  • Updated2024-03-01
  • Buy
Manufacturer Product number Product description Packaging Price Updated Buy
Biosynth Carbosynth FD137449 Dichloromethyl pinacolboronate 2g $600 2021-12-16 Buy
Biosynth Carbosynth FD137449 Dichloromethyl pinacolboronate 5G $1000 2021-12-16 Buy
Chemenu CM329406 2-(dichloromethyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane 95%+ 1g $1288 2021-12-16 Buy
JR MediChem JR6-L9521 Pinacol (dichloromethyl) boronate 100g $3980 2021-12-16 Buy
Sigma-Aldrich 901062 Pinacol (dichloromethyl) boronate ≥95% 1g $206 2024-03-01 Buy
Sigma-Aldrich 901062 Pinacol (dichloromethyl) boronate ≥95% 5g $675 2024-03-01 Buy

Properties

Boiling point :103 °C(Press: 20 Torr)
Density :1.1423
refractive index :n/D 1.4511
form :liquid

Safety Information

Symbol(GHS): GHS hazard pictogramsGHS hazard pictograms
Signal word: Danger
Hazard statements:
Code Hazard statements Hazard class Category Signal word Pictogram P-Codes
H302 Harmful if swallowed Acute toxicity,oral Category 4 Warning GHS hazard pictograms P264, P270, P301+P312, P330, P501
H314 Causes severe skin burns and eye damage Skin corrosion/irritation Category 1A, B, C Danger GHS hazard pictograms P260,P264, P280, P301+P330+ P331,P303+P361+P353, P363, P304+P340,P310, P321, P305+ P351+P338, P405,P501
Precautionary statements:
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P310 Immediately call a POISON CENTER or doctor/physician.

Description

Pinacol (dichloromethyl) boronate is a general reagent that was employed by Prof. Greg C. Fu and coworkers to achieve the iterative synthesis of asymmetric (secondary) alkyl boronate esters. These can be further derivatized through a growing suite of chemical transformations developed in the last decade (cross coupling, oxidation, amination, halogenation) that proceed with stereochemical fidelity.