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ChemicalBook >> CAS DataBase List >> Phosphorus trichloride

Phosphorus trichloride

Phosphorus trichloride price.
  • $30.3 - $762
  • Product name: Phosphorus trichloride
  • CAS: 7719-12-2
  • MF: Cl3P
  • MW: 137.33
  • EINECS:231-749-3
  • MDL Number:MFCD00011438
  • Synonyms:phosphore(trichlorurede)(french) ;phosphorouschloride ;Phosphoroustrichloride ;Phosphortrichlorid;Phosphorus chloride (cl6p2);Phosphorus chloride (pcl3);phosphoruschloride(cl6p2) ;phosphoruschloride(pcl3)
12 prices
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  • Alfa Aesar
  • Sigma-Aldrich
  • Strem Chemicals
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  • 10g
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  • 100g
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  • ManufacturerAlfa Aesar
  • Product number044436
  • Product descriptionPhosphorus(III) chloride, 98% min
  • Packaging50g
  • Price$30.3
  • Updated2023-06-20
  • Buy
  • ManufacturerAlfa Aesar
  • Product number044436
  • Product descriptionPhosphorus(III) chloride, 98% min
  • Packaging250g
  • Price$75.2
  • Updated2023-06-20
  • Buy
  • ManufacturerAlfa Aesar
  • Product number022988
  • Product descriptionPhosphorus(III) chloride, 99.997% (metals basis)
  • Packaging25g
  • Price$288
  • Updated2023-06-20
  • Buy
  • ManufacturerAlfa Aesar
  • Product number022988
  • Product descriptionPhosphorus(III) chloride, 99.997% (metals basis)
  • Packaging100g
  • Price$762
  • Updated2023-06-20
  • Buy
  • ManufacturerSigma-Aldrich
  • Product number157791
  • Product descriptionPhosphorus trichloride 99%
  • Packaging50g
  • Price$59.9
  • Updated2024-03-01
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  • ManufacturerSigma-Aldrich
  • Product number157791
  • Product descriptionPhosphorus trichloride 99%
  • Packaging250g
  • Price$73.2
  • Updated2024-03-01
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  • ManufacturerSigma-Aldrich
  • Product number310115
  • Product descriptionPhosphorus trichloride 99.999% trace metals basis
  • Packaging25g
  • Price$121
  • Updated2024-03-01
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  • ManufacturerSigma-Aldrich
  • Product number157791
  • Product descriptionPhosphorus trichloride 99%
  • Packaging1kg
  • Price$165
  • Updated2024-03-01
  • Buy
  • ManufacturerSigma-Aldrich
  • Product number310115
  • Product descriptionPhosphorus trichloride 99.999% trace metals basis
  • Packaging100g
  • Price$189.6
  • Updated2024-03-01
  • Buy
  • ManufacturerStrem Chemicals
  • Product number93-1587
  • Product descriptionPhosphorus(III) chloride, 98+%
  • Packaging250g
  • Price$71
  • Updated2024-03-01
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  • ManufacturerStrem Chemicals
  • Product number93-1588
  • Product descriptionPhosphorus(III) chloride (99.998%-P) PURATREM
  • Packaging10g
  • Price$90
  • Updated2024-03-01
  • Buy
  • ManufacturerStrem Chemicals
  • Product number93-1588
  • Product descriptionPhosphorus(III) chloride (99.998%-P) PURATREM
  • Packaging50g
  • Price$357
  • Updated2024-03-01
  • Buy
Manufacturer Product number Product description Packaging Price Updated Buy
Alfa Aesar 044436 Phosphorus(III) chloride, 98% min 50g $30.3 2023-06-20 Buy
Alfa Aesar 044436 Phosphorus(III) chloride, 98% min 250g $75.2 2023-06-20 Buy
Alfa Aesar 022988 Phosphorus(III) chloride, 99.997% (metals basis) 25g $288 2023-06-20 Buy
Alfa Aesar 022988 Phosphorus(III) chloride, 99.997% (metals basis) 100g $762 2023-06-20 Buy
Sigma-Aldrich 157791 Phosphorus trichloride 99% 50g $59.9 2024-03-01 Buy
Sigma-Aldrich 157791 Phosphorus trichloride 99% 250g $73.2 2024-03-01 Buy
Sigma-Aldrich 310115 Phosphorus trichloride 99.999% trace metals basis 25g $121 2024-03-01 Buy
Sigma-Aldrich 157791 Phosphorus trichloride 99% 1kg $165 2024-03-01 Buy
Sigma-Aldrich 310115 Phosphorus trichloride 99.999% trace metals basis 100g $189.6 2024-03-01 Buy
Strem Chemicals 93-1587 Phosphorus(III) chloride, 98+% 250g $71 2024-03-01 Buy
Strem Chemicals 93-1588 Phosphorus(III) chloride (99.998%-P) PURATREM 10g $90 2024-03-01 Buy
Strem Chemicals 93-1588 Phosphorus(III) chloride (99.998%-P) PURATREM 50g $357 2024-03-01 Buy

Properties

Melting point :-112 °C
Boiling point :74-78 °C(lit.)
Density :1.574 g/mL at 25 °C
vapor density :4.75 (vs air)
vapor pressure :23.32 psi ( 55 °C)
refractive index :n20/D 1.5148(lit.)
Flash point :76°C
storage temp. :Store at RT.
solubility :Soluble in benzene, carbon sulfide, ether, chloroform, carbon tetrachloride.
form :Liquid
color :Yellow
Specific Gravity :approximate 1.6
Odor :Pungent, irritating odor
PH Range :1
Water Solubility :reacts
Sensitive :Moisture Sensitive
Merck :14,7358
BRN :969177
Exposure limits :TLV-TWA 1.12 mg/m3 (0.2 ppm) (ACGIH), 2.8 mg/m3 (0.5 ppm) (OSHA).
Dielectric constant :3.7(18℃)
Stability :Stable, but light sensitive. Incompatible with water, many metals, fluorine, acids, variety of organic materials including acids, alcohols and reducing agents. Reaction with water is violent and yields toxic gas.
CAS DataBase Reference :7719-12-2(CAS DataBase Reference)
NIST Chemistry Reference :Phosphorus trichloride(7719-12-2)
EPA Substance Registry System :Phosphorus trichloride (7719-12-2)

Safety Information

Symbol(GHS): GHS hazard pictogramsGHS hazard pictogramsGHS hazard pictograms
Signal word: Danger
Hazard statements:
Code Hazard statements Hazard class Category Signal word Pictogram P-Codes
H314 Causes severe skin burns and eye damage Skin corrosion/irritation Category 1A, B, C Danger GHS hazard pictograms P260,P264, P280, P301+P330+ P331,P303+P361+P353, P363, P304+P340,P310, P321, P305+ P351+P338, P405,P501
H373 May cause damage to organs through prolonged or repeated exposure Specific target organ toxicity, repeated exposure Category 2 Warning P260, P314, P501
Precautionary statements:
P260 Do not breathe dust/fume/gas/mist/vapours/spray.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P303+P361+P353 IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P314 Get medical advice/attention if you feel unwell.

Description

Phosphorus(III) chloride is used as a reagent in organic synthesis. It is utilized in the conversion of primary alcohol and secondary alcohol to alkyl chlorides. It acts as a precursor to phosphorous pentachloride, phosphorous oxychloride, thiophosphoryl chloride and triphenylphosphine. It is also used to prepare phosphite esters, which is used Horner-Wadsworth-Emmons reactions.

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