Hydrocarbon halides

Hydrocarbon halide, or hydrocarbon for short, refers to the product produced during the process of hydrogen atoms replaced by by halogen (fluorine, chlorine, bromine, iodine) in the hydrocarbon molecules. According to the different hydrocarbon groups, it could be divided into categories like aliphatic halogenated hydrocarbons (including saturated and unsaturated halogenated hydrocarbons), aromatic halogenated hydrocarbons. According to the amount of halogen atoms contained in the molecule, it could be divided into categories like halogenated hydrocarbons, dihalogenated hydrocarbons and polyhalogenated hydrocarbons. Most of the halogenated hydrocarbons are liquid. The proportion of Iodinated hydrocarbons, brominated hydrocarbons and polyhalogenated hydrocarbons are all higher than 1. They are insoluble in water and could be dissolved in any proportion with hydrocarbons, they also could dissolve many other organics. The proportion of Hydrocarbon halide would decreases with the increase of the amount of carbon atoms. When there are the same hydrocarbon groups, the boiling point and the proportion of the halogenated hydrocarbons would increase in the order of chlorinated hydrocarbons, brominated hydrocarbons, and iodinated hydrocarbons. In the isomer, the more branches it gets, the lower boiling point it has. Most of these substances are toxic and can burn. And their combustion properties decrease with the increase of the amount of halogen atoms in the compound. When it comes to storage, fire hazard should be managed in A, B, C three categories according to fire risk indicators. When it catch fire, the gas should be treated by the C class of fire treatment, liquid by B class of fire treatment. Eenough attention should be payed to anti-virus.
The amount of naturally occurring halo hydrocarbons is very small, and the majority of halo hydrocarbons are synthesized by halogenation of alkanes, and compounded by unsaturated hydrocarbons. It also could be compounded during the reaction between alcohol with hydrohalic acid.
The amount of Halohydrocarbons are more isomers than corresponding hydrocarbons. Apart from the carbon isomerism, unsaturated bond position isomerization, cis-trans isomerism and optical isomerism, there are halogen atom isomerizations as well.. when the Halogenated hydrocarbon was named, the hydrocarbon plays a rule as the matrix while halogen atom plays as substituents. The position, number and name of halogen should be lined out before the name of the hydrocarbon. At room temperature, apart from methyl chloride, methyl bromide, ethyl chloride, vinyl chloride and others which are gas in room temperature, the halo hydrocarbon is liquid in general and the highly  halogenated hydrocarbon is solid.
Halohydrocarbons is not dissolvable in water, but soluble in a variety of organic solvents, and can be dissolved in a variety of weak polarity and non-polar organic compounds. So it  is a kind of commonly used solvent. The relative density of iodinated hydrocarbons, brominated hydrocarbons and polyhalogenated hydrocarbons are all higher than 1. The boiling point of halogenated hydrocarbons increases with the increasing atomic amount of halogen atoms. The boiling point of the same series of halogenated hydrocarbons increases with increase of the amount of carbon chain. The more branched the isomer, the lower the boiling point would it have (except from fluorinated alkanes).
The chemical property of halogenated hydrocarbons is much more active than paraffin, so  halogenated hydrocarbons can produce a variety of chemical reactions, and turn them into various types of compounds. It has an important position in organic synthesis. Halo hydrocarbon has been applied widely in many trades, apart from being used as a solvent, it also could be used as refrigerant, extinguishing agent, anesthetics and preservatives.
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Structure Chemical Name CAS MF
2-Iodobenzyl chloride 2-Iodobenzyl chloride 59473-45-9 C7H6ClI
1-CHLORO-2-METHYLBUTANE 1-CHLORO-2-METHYLBUTANE 616-13-7 C5H11Cl
1-Iodononane 1-Iodononane 4282-42-2 C9H19I
PERFLUORONONANE PERFLUORONONANE 375-96-2 C9F20
PERFLUOROTETRACOSANE PERFLUOROTETRACOSANE 1766-41-2 C24F50
4-FLUORO-3-IODOTOLUENE 4-FLUORO-3-IODOTOLUENE 452-82-4 C7H6FI
2-Bromoresorcinol 2-Bromoresorcinol 6751-75-3 C6H5BrO2
2-(BROMOVINYL)TRIMETHYLSILANE 2-(BROMOVINYL)TRIMETHYLSILANE 41309-43-7 C5H11BrSi
3,4-Dichlorobenzotrichloride 3,4-Dichlorobenzotrichloride 13014-24-9 C7H3Cl5
1-CHLOROANTHRACENE 1-CHLOROANTHRACENE 4985-70-0 C14H9Cl
1-Bromoicosane 1-Bromoicosane 4276-49-7 C20H41Br
1,8-BIS(BROMOMETHYL)NAPHTHALENE 1,8-BIS(BROMOMETHYL)NAPHTHALENE 2025-95-8 C12H10Br2
PENTACHLOROBENZENE PENTACHLOROBENZENE 608-93-5 C6HCl5
1,5-Diiodopentane 1,5-Diiodopentane 628-77-3 C5H10I2
2,4-DICHLORO-OMEGA-NITROSTYRENE 2,4-DICHLORO-OMEGA-NITROSTYRENE 18984-21-9 C8H5Cl2NO2
1-Ethyl-3,5-difluorobenzene 1-Ethyl-3,5-difluorobenzene 117358-52-8 C8H8F2
2-IODOOCTANE 2-IODOOCTANE 629-27-6 C8H17I
2-CHLOROPHENETHYL BROMIDE 2-CHLOROPHENETHYL BROMIDE 16793-91-2 C8H8BrCl
Hexadecafluoroheptane Hexadecafluoroheptane 335-57-9 C7F16
(3-CHLOROPHENYLETHYNYL)TRIMETHYLSILAN& (3-CHLOROPHENYLETHYNYL)TRIMETHYLSILAN& 227936-62-1 C11H13ClSi
EXO-2-CHLORONORBORNANE EXO-2-CHLORONORBORNANE 765-91-3 C7H11Cl
1-IODO-2,4,5-TRICHLOROBENZENE 1-IODO-2,4,5-TRICHLOROBENZENE 7145-82-6 C6H2Cl3I
TRANS-3-CHLORO-BETA-NITROSTYRENE TRANS-3-CHLORO-BETA-NITROSTYRENE 37888-03-2 C8H6ClNO2
4-Bromo-4'-fluorobiphenyl 4-Bromo-4'-fluorobiphenyl 398-21-0 C12H8BrF
1,2-DIBROMOETHYLENE 1,2-DIBROMOETHYLENE 540-49-8 C2H2Br2
1,2-DIBROMO-1,2-DIPHENYLETHANE 1,2-DIBROMO-1,2-DIPHENYLETHANE 13440-24-9 C14H12Br2
2,4-DIBROMOPENTANE 2,4-DIBROMOPENTANE 19398-53-9 C5H10Br2
9-IODOPHENANTHRENE 9-IODOPHENANTHRENE 17024-12-3 C14H9I
4,4'-DIMETHOXYOCTAFLUOROBIPHENYL 4,4'-DIMETHOXYOCTAFLUOROBIPHENYL 2200-71-7 C14H6F8O2
1-BROMO-2,3,5,6-TETRAMETHYLBENZENE 1-BROMO-2,3,5,6-TETRAMETHYLBENZENE 1646-53-3 C10H13Br
9,10-DICHLOROANTHRACENE 9,10-DICHLOROANTHRACENE 605-48-1 C14H8Cl2
HEXACHLOROBENZENE HEXACHLOROBENZENE 118-74-1 C6Cl6
CIS-4-CHLORO-2-BUTENYLAMINE HYDROCHLORIDE CIS-4-CHLORO-2-BUTENYLAMINE HYDROCHLORIDE 7153-66-4 C4H9Cl2N
3-(CHLOROMETHYL)PENTANE 3-(CHLOROMETHYL)PENTANE 4737-41-1 C6H13Cl
1,1,2-TRIBROMOETHANE 1,1,2-TRIBROMOETHANE 78-74-0 C2H3Br3
1-CHLORO-4-PHENYLBUTANE 1-CHLORO-4-PHENYLBUTANE 4830-93-7 C10H13Cl
1-BROMO-2-METHYLNAPHTHALENE 1-BROMO-2-METHYLNAPHTHALENE 6627-78-7 C11H9Br
ALPHA-HCH ALPHA-HCH 319-84-6 C6H6Cl6
2-BROMODODECANE 2-BROMODODECANE 13187-99-0 C12H25Br
1 2-DIBROMO-4-TERT-BUTYLBENZENE  97 1 2-DIBROMO-4-TERT-BUTYLBENZENE 97 6683-75-6 C10H12Br2
1-BROMO-4-FLUOROBUTANE 1-BROMO-4-FLUOROBUTANE 462-72-6 C4H8BrF
2-Bromo-5-(trifluoromethoxy)toluene 2-Bromo-5-(trifluoromethoxy)toluene 261951-96-6 C8H6BrF3O
1,2-Dibromotetrafluoroethane 1,2-Dibromotetrafluoroethane 124-73-2 C2Br2F4
2-BROMOPHENETOLE 2-BROMOPHENETOLE 583-19-7 C8H9BrO
3,4-DICHLORO-1-BUTENE 3,4-DICHLORO-1-BUTENE 760-23-6 C4H6Cl2
2,6-DICHLORO-OMEGA-NITROSTYRENE 2,6-DICHLORO-OMEGA-NITROSTYRENE 120355-50-2 C8H5Cl2NO2
1-IODO-2-METHYLBUTANE 1-IODO-2-METHYLBUTANE 616-14-8 C5H11I
PENTAERYTHRITYL TETRABROMIDE PENTAERYTHRITYL TETRABROMIDE 623-97-2 C5H8Cl2O3
Difluorochloromethane Difluorochloromethane 75-45-6 CHClF2
VINYL(CHLOROMETHYL)DIMETHYLSILANE VINYL(CHLOROMETHYL)DIMETHYLSILANE 16709-86-7 C5H11ClSi
1,2-Dibromotetrafluorobenzene 1,2-Dibromotetrafluorobenzene 827-08-7 C6Br2F4
1-BROMO-2,4,6-TRI-TERT-BUTYLBENZENE 1-BROMO-2,4,6-TRI-TERT-BUTYLBENZENE 3975-77-7 C18H29Br
4-ETHYNYL-1-FLUORO-2-METHYLBENZENE  97 4-ETHYNYL-1-FLUORO-2-METHYLBENZENE 97 351002-93-2 C9H7F
4-ISOPROPYL BENZYL BROMIDE  97 4-ISOPROPYL BENZYL BROMIDE 97 73789-86-3 C10H13Br
4H,4'H-OCTAFLUOROBIPHENYL 4H,4'H-OCTAFLUOROBIPHENYL 3883-86-1 C12H2F8
CIS-3,4-DICHLOROCYCLOBUTENE CIS-3,4-DICHLOROCYCLOBUTENE 2957-95-1 C4H4Cl2
CIS-1-BROMO-1-PROPENE CIS-1-BROMO-1-PROPENE 590-13-6 C3H5Br
1,1-DICHLOROPROPANE 1,1-DICHLOROPROPANE 78-99-9 C3H6Cl2
2,3,5,6-TETRAFLUORO-P-XYLENE 2,3,5,6-TETRAFLUORO-P-XYLENE 703-87-7 C8H6F4
TRANS-1,4-DIBROMO-2-BUTENE TRANS-1,4-DIBROMO-2-BUTENE 6974-12-5 C4H6Br2
1,1,2,2-TETRABROMOETHANE 1,1,2,2-TETRABROMOETHANE 25167-20-8 C2H2Br4
1-(2-BROMOETHYL)NAPHTHALENE 1-(2-BROMOETHYL)NAPHTHALENE 13686-49-2 C12H11Br
2,2'-BIS(BROMOMETHYL)-1,1'-BIPHENYL 2,2'-BIS(BROMOMETHYL)-1,1'-BIPHENYL 38274-14-5 C14H12Br2
1,2-DIBROMO-1,1,2-TRICHLOROETHANE 1,2-DIBROMO-1,1,2-TRICHLOROETHANE 13749-38-7 C2HBr2Cl3
1,1,1,2,2,3,3-HEPTAFLUORO-5-IODOPENTANE 1,1,1,2,2,3,3-HEPTAFLUORO-5-IODOPENTANE 1513-88-8 C5H4F7I
11-CHLORO-1-UNDECENE 11-CHLORO-1-UNDECENE 872-17-3 C11H21Cl
3,4-DIBROMOHEXANE 3,4-DIBROMOHEXANE 16230-28-7 C6H12Br2
TRANS-3-BROMO-BETA-NITROSTYRENE  97 TRANS-3-BROMO-BETA-NITROSTYRENE 97 115665-95-7 C8H6BrNO2
1-BROMO-3,5-DIFLUOROBENZENE 1-BROMO-3,5-DIFLUOROBENZENE 461-91-6 C4As2F12O
1-BROMOHEPTADECANE 1-BROMOHEPTADECANE 3508-00-7 C17H35Br
6-CHLORO-1-HEXYNE 6-CHLORO-1-HEXYNE 10297-06-0 C6H9Cl
1-CHLORO-5-IODOPENTANE 1-CHLORO-5-IODOPENTANE 60274-60-4 C5H10ClI
Trichlorofluoromethane Trichlorofluoromethane 75-69-4 CCl3F
2-PHENYLBENZYL BROMIDE 2-PHENYLBENZYL BROMIDE 19853-09-9 C13H11Br
Dichlorodifluoromethane Dichlorodifluoromethane 75-71-8 CCl2F2
1-CHLORO-2,2-DIMETHYLPROPANE 1-CHLORO-2,2-DIMETHYLPROPANE 753-89-9 C5H11Cl
1,2-DICHLOROTETRAFLUOROETHANE 1,2-DICHLOROTETRAFLUOROETHANE 76-14-2 C2Cl2F4
Octachloronaphthalene Octachloronaphthalene 2234-13-1 C10Cl8
PERFLUORODIMETHYLCYCLOBUTANE PERFLUORODIMETHYLCYCLOBUTANE 2994-71-0 C6F12
3-CHLORO-3-METHYLPENTANE 3-CHLORO-3-METHYLPENTANE 918-84-3 C6H13Cl
3,3',5,5'-TETRABROMOBIPHENYL 3,3',5,5'-TETRABROMOBIPHENYL 16400-50-3 C12H6Br4
1-BROMO-2-PENTENE  95%  PREDOMINANTLY 1-BROMO-2-PENTENE 95% PREDOMINANTLY 7348-71-2 C5H9Br
2,3,5,6-TETRAFLUORO-4-(TRIFLUOROMETHYL)BENZYL BROMIDE 2,3,5,6-TETRAFLUORO-4-(TRIFLUOROMETHYL)BENZYL BROMIDE 76437-40-6 C8H2BrF7
PERFLUOROPENTADECANE PERFLUOROPENTADECANE 2264-03-1 C15F32
(Z)-2-BROMO-2-BUTENE (Z)-2-BROMO-2-BUTENE 3017-68-3 C4H7Br
1-CHLORO-6-IODOHEXANE 1-CHLORO-6-IODOHEXANE 34683-73-3 C6H12ClI
2,7-DIIODOFLUORENE 2,7-DIIODOFLUORENE 16218-28-3 C13H8I2
2,5-DIBROMOBENZOTRIFLUORIDE 2,5-DIBROMOBENZOTRIFLUORIDE 7657-09-2 C7H3Br2F3
2-(CHLOROMETHYL)NAPHTHALENE 2-(CHLOROMETHYL)NAPHTHALENE 2506-41-4 C11H9Cl
1-Iodoadamantane 1-Iodoadamantane 768-93-4 C10H15I
1,1-DICHLORO-3,3-DIMETHYLBUTANE 1,1-DICHLORO-3,3-DIMETHYLBUTANE 6130-96-7 C6H12Cl2
2-Bromo-1,3-diisopropylbenzene 2-Bromo-1,3-diisopropylbenzene 57190-17-7 C12H17Br
ALLYL(CHLOROMETHYL)DIMETHYLSILANE ALLYL(CHLOROMETHYL)DIMETHYLSILANE 33558-75-7 C6H13ClSi
1-Fluoro-2-(2-nitrovinyl)benzene 1-Fluoro-2-(2-nitrovinyl)benzene 399-25-7 C8H6FNO2
2-BROMOTETRADECANE 2-BROMOTETRADECANE 74036-95-6 C14H29Br
4,4'-DIBROMOOCTAFLUOROBIPHENYL 4,4'-DIBROMOOCTAFLUOROBIPHENYL 10386-84-2 C12Br2F8
(4-FLUOROPHENYLETHYNYL)TRIMETHYLSILANE (4-FLUOROPHENYLETHYNYL)TRIMETHYLSILANE 130995-12-9 C11H13FSi
2-ETHYLHEXYL IODIDE 2-ETHYLHEXYL IODIDE 1653-16-3 C8H17I
1-Fluorooctane 1-Fluorooctane 463-11-6 C8H17F
(3,5-BIS(TRIFLUOROMETHYL)PHENYLETHYNYL)& (3,5-BIS(TRIFLUOROMETHYL)PHENYLETHYNYL)& 618092-28-7 C13H12F6Si
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