Catalyst and Auxiliary

The catalyst can change the reaction rate in the chemical reaction, and the composition and the quality of the catalyst can be kept constant after the reaction. The catalyst that accelerates the reaction is called the positive catalyst, slows down called Negative Catalyst or slow agent. It said catalyst is a positive catalyst for the general correction. This kind of catalyst in the industry, especially the organic chemical industry used more, and has great significance, Such as sulfuric acid prepared by contacting, ammonia, hydrolysis of the ester and polysaccharide, Oil Hydrogenation, etc. Commonly used catalysts are mainly metal, metal oxide and inorganic acid. If the catalyst is solid, the substance of the reaction is gas, to form a multi-phase catalytic reaction, this catalyst, sometimes called catalyst or contact agent. The catalyst is generally selective, it can only make a reaction or a certain type of reaction to speed up. But some reaction can be used for a variety of catalysts, such as the hydrogenation reaction can often be platinum, palladium, nickel, should be carefully chosen. In the catalytic reaction, the catalyst is often added cocatalyst known to enhance catalytic action of the catalyst. For example, iron is a catalyst in ammonia industry, adding a small amount of potassium and aluminum can enhance the catalytic effect of iron. The composition and weight of the catalyst and cocatalyst cannot change before and after the reaction. All of the above are inorganic catalysts. The enzyme is a protein, is very important organic catalyst.

There are many kinds of catalyst, catalyst and reaction system according to the phase of the classification, there are two types of homogeneous and heterogeneous catalysts. Heterogeneous catalysts most widely used, there are 3 kinds of gas, liquid and solid state, the variety and application of solid catalyst. The solid catalyst, which is made of metal (nickel, platinum, palladium, chromium, cobalt, titanium, vanadium, etc.) or metal oxide (copper oxide, vanadium pentoxide, lead oxide), is dispersed and deposited on the carrier in order to obtain a good dispersion effect and increase the specific surface area. The catalyst requires reliable activity, stability, selectivity, long working life, not easy to poisoning and over-burning, easy to regenerate. In order to improve the catalytic efficiency, the pure metal catalysts are made into alloy catalysts (such as nickel aluminium alloy) and composite catalysts (ZieglerNatta). The composite catalyst is composed of main catalyst and co-catalyst. In the new efficient catalysts also add other components. The production and development of high efficiency catalyst have promoted the development of polymer materials, and produced much polymer function and structure material ,which is new generation of high performance and high added value.

With the extensive application of catalyst and a number of new catalysts, we can make a lot of new chemical reactions to achieve industrialization, in order to provide an increasing number of chemical products; also can make some of the original chemical reaction conditions have been improved, in order to improve the production efficiency and product quality, make full use of resources. The important subject in the field of modern chemistry and chemical research is to select and develop more and better catalyst for the new generation. But the role of a catalyst is not beneficial to humans, such as combustion products of supersonic jet fuel as a catalyst can cause the stratosphere (10 to 50 km altitude) decomposition of ozone in the atmosphere, to the sun's ultraviolet absorption decreased, resulting in some areas of skin cancer patients increased. Is developing a new supersonic jet fuel, its combustion products will not become a catalyst,which will cause the ozone decomposition catalyst in the stratosphere.

Additives are added in the industrial and agricultural production, especially in the chemical production of some of the auxiliary chemicals, its role is to improve the production process, improve product quality and yield, or to give the product a unique application performance.

Additive are large class of important chemical in the production of auxiliary raw materials, they can give a special performance to product, improve use of finished products; and can accelerate the chemical reaction rate, improve product yield; they can save raw materials, improve processing efficiency. Additives are widely used in the chemical industry, especially organic synthesis, synthetic material processing and petroleum refining, pesticide, medicine, dye, paint and other industrial sectors. Additives can be divided into synthesized additives and processing additives. Synthetic additives are used in monomer synthesis and polymerization of a variety of auxiliary agents in resin, fiber, rubber, etc. They include catalysts, initiators, solvents, dispersants, emulsifiers, polymerization inhibitors, regulators, termination agents, etc. Processing aid refers to the auxiliary chemicals used in the manufacture of raw rubber, plastics processing, chemical fiber spinning and spinning process, including plasticizers, heat stabilizers, antioxidants, light stabilizers , flame retardants, blowing agents, lubricants, mold release agents, curing agents, accelerators, softeners, anti-scorching agents, surfactants, oils, fillers, etc. In these additives, many of them are dangerous chemicals, Such as benzoyl peroxide, azobisisobutyronitrile, hydrogen peroxide - ferrous blue, alkyl aluminum chloride, titanium and other initiators, catalysts are inflammable and explosive materials, should be required to "chemical Dangerous Goods Safety Management Regulations", for storage, transportation, operation and use.

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Structure Chemical Name CAS MF
α,ω-DiforMyl poly(ethylene glycol) α,ω-DiforMyl poly(ethylene glycol)
α-Allyl-ω-forMyl poly(ethylene glycol) α-Allyl-ω-forMyl poly(ethylene glycol)
CALCOFLUOR WHITE RWP CALCOFLUOR WHITE RWP 8066-05-5 C14H17NNa2O6S
Carbomer 940 Carbomer 940 76050-42-5 (C3H4O2)n
Poly(β-pinene) resin Poly(β-pinene) resin
POLYMETHACRYLATE POLYMETHACRYLATE 25086-15-1 (C5H8O2.C4H6O2)x
POLY(ACRYLIC ACID-CO-ACRYLAMIDE), POTASSIUM SALT POLY(ACRYLIC ACID-CO-ACRYLAMIDE), POTASSIUM SALT 31212-13-2 C6H8KNO3
TRIETHYLENE GLYCOL MONOTETRADECYL ETHER TRIETHYLENE GLYCOL MONOTETRADECYL ETHER 26826-30-2 C20H42O4
POLYOXYETHYLENE 25 PROPYLENE GLYCOL STEARATE POLYOXYETHYLENE 25 PROPYLENE GLYCOL STEARATE 37231-60-0 C23H46O4
Acrylic acid maleic acid copolymer Acrylic acid maleic acid copolymer 29132-58-9 C7H8O6
Poly(ethyleneglycol) 2-[ethyl[(heptadecafluorooctyl)sulfonyl]amino]ethyl ether Poly(ethyleneglycol) 2-[ethyl[(heptadecafluorooctyl)sulfonyl]amino]ethyl ether 29117-08-6 C14H14F17NO4S
Fluorescent brightener HDT-1 Fluorescent brightener HDT-1
Antioxidant HS-911 Antioxidant HS-911
Fluorescent brightener HL Fluorescent brightener HL
Fluorescent brightener PS-1 Fluorescent brightener PS-1
N,N,N',N'-Tetraphenyl diaminomethane N,N,N',N'-Tetraphenyl diaminomethane C25H22N2
METHYL GLUCETH-20 METHYL GLUCETH-20 68239-42-9 C15H30O10
SODIUM STYRENE/ACRYLATES COPOLYMER SODIUM STYRENE/ACRYLATES COPOLYMER 9010-92-8 C12H14O2
IRGANOX 1141 IRGANOX 1141 134701-20-5 C24H42O
POLY(2-ACRYLAMIDO-2-METHYL-1-PROPANESULFONIC ACID-CO-ACRYLONITRILE) POLY(2-ACRYLAMIDO-2-METHYL-1-PROPANESULFONIC ACID-CO-ACRYLONITRILE) 54640-82-3 C10H16N2O4S
POLY(VINYL ACETATE-CO-BUTYL MALEATE-CO-ISOBORNYL ACRYLATE) POLY(VINYL ACETATE-CO-BUTYL MALEATE-CO-ISOBORNYL ACRYLATE) 136392-68-2 C29H46O8
Methoxy Poly(ethyl glycol) α-broMoisobutyrate (MPEGBiB) Methoxy Poly(ethyl glycol) α-broMoisobutyrate (MPEGBiB)
4-arM Poly(ethylene glycol) aldehyde 4-arM Poly(ethylene glycol) aldehyde
Novel 2-arM Methoxypoly(ethylene glycol) carboxylic acid Novel 2-arM Methoxypoly(ethylene glycol) carboxylic acid
Novel 2-arM Methoxypoly(ethylene glycol) succiniMidyl ester Novel 2-arM Methoxypoly(ethylene glycol) succiniMidyl ester
α,ω-Dialkynyl poly(ethylene glycol) α,ω-Dialkynyl poly(ethylene glycol)
α,ω-DisucciniMidyl poly(ethylene glycol) α,ω-DisucciniMidyl poly(ethylene glycol)
α-Allyl-ω-Mercapto poly(ethylene glycol) α-Allyl-ω-Mercapto poly(ethylene glycol)
POLYSULFONE POLYSULFONE 25154-01-2 (C15H16O2.C12H8Cl2O2S)x
POLY(METHYLENE-CO-GUANIDINE), HYDROCHLORIDE POLY(METHYLENE-CO-GUANIDINE), HYDROCHLORIDE 55295-98-2 C3H8ClN5O
POLY(MELAMINE-CO-FORMALDEHYDE), BUTYLATED POLY(MELAMINE-CO-FORMALDEHYDE), BUTYLATED 68002-25-5 C4H8N6O
POLYETHYLENE, CHLORINATED POLYETHYLENE, CHLORINATED 64754-90-1
POLY(ETHYLENE-CO-METHACRYLIC ACID) POLY(ETHYLENE-CO-METHACRYLIC ACID) 25053-53-6 C6H10O2
STYRENE/ALLYL ALCOHOL COPOLYMER STYRENE/ALLYL ALCOHOL COPOLYMER 25119-62-4 C11H14O
PORAPAK P   (100-120 MESH ASTM)  FOR GC PORAPAK P (100-120 MESH ASTM) FOR GC 9052-95-3 C28H30
DUOLITE C-26 ION-EXCHANGE RESIN DUOLITE C-26 ION-EXCHANGE RESIN 68441-33-8 (C10H10.C8H8.Na)x
TRIPHENYLPHOSPHINE RESIN, 1% DVB; 100-200 MESH; 1-1.5 MMOL/G TRIPHENYLPHOSPHINE RESIN, 1% DVB; 100-200 MESH; 1-1.5 MMOL/G
POLY(STYRENE-CO-METHYL METHACRYLATE) POLY(STYRENE-CO-METHYL METHACRYLATE) 25034-86-0 C13H16O2
Petroleum resins Petroleum resins 64742-16-1
Fluorescent brightener  140 Fluorescent brightener 140 61968-71-6 C14H17NO2
chelate resin chelate resin
STEARETH-10 ALLYL ETHER/ACRYLATES COPOLYMER STEARETH-10 ALLYL ETHER/ACRYLATES COPOLYMER 109292-17-3 C32H60O6
POLYGLYCERYL-10 DIISOSTEARATE POLYGLYCERYL-10 DIISOSTEARATE 63705-03-3 C39H80O7
Fluorescent Brightener 368 Fluorescent Brightener 368 117313-08-3 C44H77NO12
Fluorescent Brightener BSL Fluorescent Brightener BSL
Fluorescent Brightener BF Fluorescent Brightener BF C1634N12Na2O8S2
Antioxidant AM Antioxidant AM (C15H15N)n
Tris-(2.4-lert-butyl Tris-(2.4-lert-butyl
Fluorescent brightener BSU Fluorescent brightener BSU
Fluorescent brightener CEF Fluorescent brightener CEF
Antioxidant 2088 Antioxidant 2088 C25H44OS2
Fluorescent brightener OB-P Fluorescent brightener OB-P
POLY(PROPYLENE GLYCOL) POLY(PROPYLENE GLYCOL) 25791-96-2 HO(C3H6O)nCH[CH2(OC3H6)nOH]2
gelucire 44-14 gelucire 44-14 121548-04-7
Anticoagulation levelling agent Anticoagulation levelling agent
fluorescent whitening agent DMS fluorescent whitening agent DMS C40H38Na2N12O8
TBBPA carbonate oligomer BC52 TBBPA carbonate oligomer BC52 94334-64-2 C22H18Br4Cl2O4
CASTOR OIL GLYCIDYL ETHER CASTOR OIL GLYCIDYL ETHER 74398-71-3 (C66H116O12)x
ELEMI GUM ELEMI GUM 9000-75-3
NYLON 12 NYLON 12 25038-74-8 C36H69N3O3X2
POLY(ETHYLENE-CO-GLYCIDYL METHACRYLATE) POLY(ETHYLENE-CO-GLYCIDYL METHACRYLATE) 26061-90-5 C9H14O3
DI(PROPYLENE GLYCOL) TERT-BUTYL ETHER DI(PROPYLENE GLYCOL) TERT-BUTYL ETHER 132739-31-2 C10H22O3
INDOLE RESIN, 1% DVB; 0.7-1.4 MMOL/G; 100-200 MESH INDOLE RESIN, 1% DVB; 0.7-1.4 MMOL/G; 100-200 MESH
Poly-tert-butylphenoldisulfide Poly-tert-butylphenoldisulfide 60303-68-6 C10H14Cl2OS2
Insoluble sulfur Insoluble sulfur 9035-99-8 S
Macergo 4000 Macergo 4000
Methacrylic acid, polymer with butyl acrylate and methyl methacrylate Methacrylic acid, polymer with butyl acrylate and methyl methacrylate 25035-69-2 C16H26O6
POLYHYDROXYSTEARIC ACID POLYHYDROXYSTEARIC ACID 27924-99-8 C18H36O3
DEA-C8-18 PERFLUOROALKYLETHYL PHOSPHATE DEA-C8-18 PERFLUOROALKYLETHYL PHOSPHATE 65530-63-4 C11H28F3N2O8P
Antioxidant 719 Antioxidant 719
Fluorescent Brightener VBA Fluorescent Brightener VBA C40H36N12O14S4Na4
Nonylphenoxypolyethanol-iodine complex Nonylphenoxypolyethanol-iodine complex 11096-42-7 C17H28I2O2
Antioxidant ZM-405 Antioxidant ZM-405
Fluorescent whitening agent for plastic Fluorescent whitening agent for plastic
Polyacrylic resin Ⅱ Polyacrylic resin Ⅱ
Polyethylene glycol fatty acid Polyethylene glycol fatty acid
Merrifield resin Merrifield resin
Antioxidant 2246-A Antioxidant 2246-A
Chelating resin Chelating resin
Antioxidant 3.5 methyl ester Antioxidant 3.5 methyl ester C18H28O3
Fluorescent brightener V4BM Fluorescent brightener V4BM
coupling agent NBC-1 coupling agent NBC-1
Rubber aromatic oil Rubber aromatic oil
Fluorescent brightener PSW-201 Fluorescent brightener PSW-201
Fluorescent brightener KOB Fluorescent brightener KOB
Antioxidant 2246-A Antioxidant 2246-A
Polyethylene Glycol(200)di(β-(4(pacetyl phenyl) piperazine))propionate Polyethylene Glycol(200)di(β-(4(pacetyl phenyl) piperazine))propionate 71512-90-8 (C2H4O)n.C18H20N2O3
POLY(N-BUTYL METHACRYLATE) POLY(N-BUTYL METHACRYLATE) 9003-63-8 C8H14O2
POLY(1-DECENE) POLY(1-DECENE) 68649-12-7 [CH2CH[(CH2)7CH3]]n
AMBERLITE IRA-404 AMBERLITE IRA-404 149146-26-9
Polyoxirane-2,3-dicarboxylic  acid Polyoxirane-2,3-dicarboxylic acid 51274-37-4 C4H4O5
POLY(ETHYLENE-CO-ACRYLIC ACID) POLY(ETHYLENE-CO-ACRYLIC ACID) 9010-77-9 C15H24O6X2
Polycarbonate Polycarbonate 25037-45-0 C16H18O5
POLYETHYLENEIMINE POLYETHYLENEIMINE 26658-46-8 C4H9NO
MELAMINE RESIN MELAMINE RESIN 9003-08-1 C4H8N6O
Bis(benzophenone-2-carboxylic acid) polyethylene glycol ester Bis(benzophenone-2-carboxylic acid) polyethylene glycol ester 1246194-73-9 C28H18O5.(C2H4O)n
α-ForMyl-ω-Methacryloyl poly(ethylene glycol) α-ForMyl-ω-Methacryloyl poly(ethylene glycol)
Poly(ethylene glycol) graft aldehyde Poly(ethylene glycol) graft aldehyde
Poly(vinyl alcohol-co-ethylene) Poly(vinyl alcohol-co-ethylene) 25067-34-9 C4H8O
POLY(2-HYDROXYETHYL METHACRYLATE) POLY(2-HYDROXYETHYL METHACRYLATE) 25249-16-5 C6H10O3
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