| Company Name: |
Huangshi Jingsheng Biotechnology Co., Ltd.
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| Tel: |
17771199833; 17771199833 |
| Email: |
351013952@qq.com |
| Products Intro: |
Cas:940-71-6
ProductName:Phosphonitrilic chloride trimer
Purity: 99 | Package: 25KG/RMB 300
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| | Phosphonitrilic Chloride Basic information |
| Product Name: | Phosphonitrilic Chloride | | Synonyms: | AKOS BBS-00002918;1,3,5-TRIAZA-2,4,6-TRIPHOSPHORIN-2,2,4,4,6,6-HEXACHLORIDE;1,3,5,2,4,6-TRIAZATRIPHOSPHORINE-2,2,4,4,6,6-HEXACHLORIDE;1,3,5,2,4,6-TRIAZATRIPHOSPHORINE,2,2,4,4,6,6-HEXACHLORO-2,2,4,4,6,6-HEXAHYDRO-;2,2,4,4,6,6-HEXACHLORO-1,3,5,2LAMBDA5,4LAMBDA5,6LAMBDA5-TRIAZATRIPHOSPHININE;AURORA KA-1096;CYCLIC PHOSPHONITRILIC CHLORIDE TRIMER;CYCLOPHOSPHAZENE DICHLORIDE TRIMER | | CAS: | 940-71-6 | | MF: | Cl6N3P3 | | MW: | 347.66 | | EINECS: | 213-376-8 | | Product Categories: | organophosphorus compound;API intermediates | | Mol File: | 940-71-6.mol |  |
| | Phosphonitrilic Chloride Chemical Properties |
| Melting point | 112-115 °C(lit.) | | Boiling point | 127 °C (13 mmHg) | | density | 1.98 g/mL at 25 °C(lit.) | | Water Solubility | Insoluble in water | | solubility | reacts with H2O | | form | crystal | | pka | -12.98±0.10(Predicted) | | Specific Gravity | 1.98 | | color | white | | Sensitive | Moisture Sensitive | | CAS DataBase Reference | 940-71-6(CAS DataBase Reference) | | NIST Chemistry Reference | 1,3,5,2,4,6-Triazatriphosphorine, 2,2,4,4,6,6-hexachloro-2,2,4,4,6,6-hexahydro-(940-71-6) | | EPA Substance Registry System | 1,3,5,2,4,6-Triazatriphosphorine, 2,2,4,4,6,6-hexachloro-2,2,4,4,6,6-hexahydro- (940-71-6) |
| | Phosphonitrilic Chloride Usage And Synthesis |
| Chemical Properties | white crystalline powder | | Uses | Reagent for the synthesis of ″dandelion″ (spherical) dendrimers. Ring-opening polymerization, ligand and/or ligand precursor for transition metals, and the study of P-Cl bond substitution reactions are among the interesting uses for this product. | | Preparation | Hexachlorocyclotriphosphazene
(PNCl2)3 (mp114 ℃, bp 256℃),
which is produced on an industrial scale as
the starting material for the manufacture of
organosubstituted polyphosphazenes. It forms
an almost planar six-membered ring with equal
P?N bond lengths. | | Purification Methods | Purify it by zone melting, by crystallisation from pet.ether, n-hexane or *benzene, and by sublimation. [van der Huizen et al. J Chem Soc, Dalton Trans 1311 1986, Meirovitch et al. J Phys Chem 88 1522 1984, Alcock et al. J Am Chem Soc 106 5561 1984; Winter & van de Grampel J Chem Soc, Dalton Trans 1269 1986.] Phosphoric acid [7664 -38 -2] M 98.0, m 42.3o, pK 1 2.15, pK 2 7.21, pK 3 12.37. Pyrophosphate can be removed from phosphoric acid by diluting with distilled H2O and refluxing overnight. By cooling to 11o and seeding with crystals obtained by cooling a few millilitres in a Dry-ice/acetone bath, 85% orthophosphoric acid crystallises as H3PO4.H2O. The crystals are collected on a sintered glass filter. [Weber & King Inorg Synth I 101 1939.] |
| | Phosphonitrilic Chloride Preparation Products And Raw materials |
| Raw materials | TRICHLORO(TRIMETHYLSILYL)PHOSPHORANIMINE-->2λ5,4λ5,6λ5,8λ5,10λ5-1,3,5,7,9,2,4,6,8,10-Pentazapentaphosphecine, 2,2,4,4,6,6,8,8,10,10-decachloro--->2,2,4,4,6,6,8,8-octachloro-2,2,4,4,6,6,8,8-octahydro-1,3,5,7,2,4,6,8-tetraazatetraphosphocine-->NONAMETHYLTRISILAZANE-->Zinc chloride-->Ammonium chloride-->Ammonia | | Preparation Products | 4-Isopropenylphenol |
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