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4-Bromophenoxybenzene

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4-Bromophenoxybenzene Basic information
Product Name:4-Bromophenoxybenzene
Synonyms:4-BROMOPHENYL PHENYL ETHER;4-bromophenoxybenzene;4-BROMODIPHENYL OXIDE;p-phenoxybromobenzene;p-Phenoxyphenyl bromide;P-BROMODIPHENYL ETHER;P-BROMOPHENYL PHENYL ETHER;1-BROMO-4-PHENOXY-BENZENE (4-BROMOPHENYL PHENYL ETHER)
CAS:101-55-3
MF:C12H9BrO
MW:249.1
EINECS:202-952-4
Product Categories:Alcohol& Phenol& Ethers;API intermediates;Biphenyl & Diphenyl ether
Mol File:101-55-3.mol
4-Bromophenoxybenzene Structure
4-Bromophenoxybenzene Chemical Properties
Melting point 18 °C (lit.)
Boiling point 305 °C (lit.)
density 1.423 g/mL at 25 °C (lit.)
vapor pressure 1.94 x 10-3 mmHg at 25 °C (subcooled liquid, Tittlemier et al., 2002)
refractive index n20/D 1.607(lit.)
Fp >230 °F
storage temp. 2-8°C
solubility Soluble in ether (Weast, 1986) and many other solvents including 1,4-dioxane, benzene, and toluene.
form Liquid
color Colorless to Almost colorless
BRN 1308972
Henry's Law Constant2.27 at 25 °C (integrated gas-stripping method, GC, Lau et al., 2006)
Stability:Stable. Combustible. Incompatible with strong oxidizing agents.
InChIKeyJDUYPUMQALQRCN-UHFFFAOYSA-N
CAS DataBase Reference101-55-3(CAS DataBase Reference)
NIST Chemistry ReferenceBenzene, 1-bromo-4-phenoxy-(101-55-3)
EPA Substance Registry Systemp-Bromophenyl phenyl ether (101-55-3)
Safety Information
Hazard Codes N,Xn,F
Risk Statements 50/53-67-65-38-11-43-41-22
Safety Statements 60-61-62-36/37/39-26-33-29-16-9
RIDADR UN 3082 9/PG 3
WGK Germany 3
TSCA Yes
HazardClass 9
PackingGroup III
HS Code 29093090
Hazardous Substances Data101-55-3(Hazardous Substances Data)
ToxicityLC50 (24-h) for Daphnia magna 0.46 mg/L (LeBlanc, 1980).
MSDS Information
ProviderLanguage
4-Bromophenoxybenzene English
SigmaAldrich English
ALFA English
4-Bromophenoxybenzene Usage And Synthesis
Description4-Bromophenyl phenyl ether is a brominateddiphenylether and a liquid at common ambient temperatures.Molecular weight=249.10; Boiling point=310.14 ℃;Specific gravity (H2O:1)=1.449 (1.4208 at 20 ℃);Freezing/Melting point=18.72℃; Vapor pressure 50.0015 mmHg at 20℃; Flash point=.110℃. HazardIdentification (based on NFPA-704 M Rating System):Health 1, Flammability 1, Reactivity 0. Poor solubility inwater; solubility=4.8 mg/L at 25℃.
Chemical Propertieslight yellow liquid
DefinitionChEBI: An aromatic ether that is diphenyl ether substituted at position 4 by a bromo group.
General DescriptionLiquid. Freezing point 18°C. Density 1.423 g / cm3. Insoluble or slightly soluble in water.
Air & Water ReactionsInsoluble in water.
Reactivity Profile4-Bromophenoxybenzene oxidizes readily in air to form unstable peroxides that may explode spontaneously [Bretherick 1979 p.151-154, 164].
Fire HazardCombustible.
Potential ExposureVery little information on 4-bromophenyl phenyl ether exists. It is prepared by brominatingdiphenyl ether with Br2 at 95-100℃ in carbontetrachloride.[US EPA, 1986] 4-Bromophenyl phenyl ether hasbeen identified in raw water, in drinking water, and in riverwater.
First aidIf this chemical gets into the eyes, remove anycontact lenses at once and irrigate immediately for at least15 min, occasionally lifting upper and lower lids. Seek medical attention immediately. If this chemical contacts theskin, remove contaminated clothing and wash immediatelywith soap and water. Seek medical attention immediately. Ifthis chemical has been inhaled, remove from exposure,begin rescue breathing (using universal precautions, including resuscitation mask) if breathing has stopped and CPR ifheart action has stopped. Transfer promptly to a medical facility. When this chemical has been swallowed, get medical attention. Give large quantities of water and inducevomiting. Do not make an unconscious person vomit.
Environmental fateBiological. Using settled domestic wastewater inoculum, 4-bromophenyl phenyl ether (5 and 10 mg/L) did not degrade after 28 d of incubation at 25 °C (Tabak et al., 1981).
Chemical/Physical. At influent concentrations of 1.0, 0.1, 0.01, and 0.001 mg/L, the GAC adsorption capacities were 303, 112, 41, and 15 mg/g, respectively (Dobbs and Cohen, 1980).
storageColor Code—Green: General storage may be used.Store away from heat, flames, or oxidizing materials; etherstend to peroxidize when exposed to air formingunstable peroxides that may detonate with extreme violence.
ShippingThe name of this material is not on the DOT listof materials for label and packaging standards. However,based on regulations, it may be classified as anEnvironmentally hazardous substances, liquid, n.o.s. It fallsin Hazard Class 9 and Packing Group III.[20, 21]
Tag:4-Bromophenoxybenzene(101-55-3) Related Product Information
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