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| 4-Hydroxyphenylboronic acid pinacol ester Basic information |
Product Name: | 4-Hydroxyphenylboronic acid pinacol ester | Synonyms: | 4-(4,4,5,5-Tetramethyl-1,3,2-dioxaborolan-2-yl)phenol,4-Hydroxybenzeneboronic acid;4-(4,4,5,5-Tetramethyl-1,3,2-D;4-(4,4,5,5-Tetramethyl-1,3,2-dioxaborolan-2-yl)phenol,min.97%;4-(4,4,5,5-TETRAMETHYL-1,3,2-DIOXABOROLAN-2YL) PHE;2-(4-HYDROXYPHENYL)-4,4,5,5-TETRAMETHYL-1,3,2-DIOXABOROLANE;4-HYDROXYBENZENEBORONIC ACID;4-HYDROXYBENZENEBORONIC ACID, PINACOL ESTER;4-HYDROXYPHENYLBORONIC ACID PINACOLATE | CAS: | 269409-70-3 | MF: | C12H17BO3 | MW: | 220.07 | EINECS: | 627-688-0 | Product Categories: | Aryl Boronate Esters;Boronate Esters;Boronic Acids and Derivatives;Chemical Synthesis;Organometallic Reagents;organic or inorganic borate;Boronic acids;B (Classes of Boron Compounds);Boronic Acids Esters;Boronic acid;CHIRAL CHEMICALS | Mol File: | 269409-70-3.mol | ![4-Hydroxyphenylboronic acid pinacol ester Structure](CAS/GIF/269409-70-3.gif) |
| 4-Hydroxyphenylboronic acid pinacol ester Chemical Properties |
Melting point | 113-117 °C (lit.) | Boiling point | 333.8±25.0 °C(Predicted) | density | 1.08±0.1 g/cm3(Predicted) | storage temp. | Keep in dark place,Sealed in dry,Room Temperature | solubility | Acetonitrile, DMSO, Methanol | form | Crystalline Powder | pka | 9.61±0.30(Predicted) | color | Yellow to light brown | Water Solubility | Insoluble | InChI | InChI=1S/C12H17BO3/c1-11(2)12(3,4)16-13(15-11)9-5-7-10(14)8-6-9/h5-8,14H,1-4H3 | InChIKey | BICZJRAGTCRORZ-UHFFFAOYSA-N | SMILES | C1(O)=CC=C(B2OC(C)(C)C(C)(C)O2)C=C1 | CAS DataBase Reference | 269409-70-3(CAS DataBase Reference) |
Hazard Codes | Xi | Risk Statements | 36/37/38 | Safety Statements | 26-36-37/39 | WGK Germany | 3 | TSCA | No | HazardClass | IRRITANT | HS Code | 29319090 |
| 4-Hydroxyphenylboronic acid pinacol ester Usage And Synthesis |
Chemical Properties | yellow to light brown crystalline powder | Uses | 4-Hydroxyphenylboronic acid pinacol ester is widely used in Suzuki coupling chemistry. | Uses | suzuki reaction |
| 4-Hydroxyphenylboronic acid pinacol ester Preparation Products And Raw materials |
Raw materials | 4-Iodophenol-->4-Hydroxyphenylboronic acid-->4-Chlorophenol-->Pinacol-->Pinacolborane-->4-Bromophenol-->4-Aminophenol-->4,4,5,5-Tetramethyl-2-[4-(prop-2-en-1-yloxy)phenyl]-1,3,2-dioxaborolane-->Bis(pinacolato)diboron | Preparation Products | 2-[4-(4,4,5,5-Tetramethyl-1,3,2-dioxaborolan-2-yl)phenoxy]ethanol-->4,4,5,5-tetramethyl-2-(4-((3-methylbenzyl)oxy)phenyl)-1,3,2-dioxaborolane-->4,4,5,5-Tetramethyl-2-[4-(oxan-4-yloxy)phenyl]-1,3,2-dioxaborolane-->tert-butyl 4-[4-(tetramethyl-1,3,2-dioxaborolan-2-yl)phenoxy]piperidine-1-carboxylate |
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