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| 2,4,6-Triisopropylbenzene-sulfonyl azide Basic information |
Product Name: | 2,4,6-Triisopropylbenzene-sulfonyl azide | Synonyms: | 2,4,6-Triisopropylbenzenesulphonylazide;2,4,6-Triisopropylbenzenesulfonyl azide, 98%, stab. with ca 10% water;2,4,6-Triisopropylbenzenesulfonyl azide ,90% [stab. With ca 10% water];2,4,6-Triisopropylbenzenesulfonic acid azide;2,4,6-Triisopropylbe;2,4,6-Triisopropylp henylsulfonyl azide;2,4,6-Tris(1-methylethyl)-benzenesulfonyl azide;2,4,6-Triisopropylbenzenesulfonyl azide, stabilized with 10% H2O | CAS: | 36982-84-0 | MF: | C15H23N3O2S | MW: | 309.43 | EINECS: | | Product Categories: | Azidation/Diazo Transfer;C-X Bond Formation (Non-Halogen);Various Azides;Azides;Building Blocks;Chemical Synthesis;Nitrogen Compounds;Organic Building Blocks;Synthetic Reagents | Mol File: | 36982-84-0.mol | |
| 2,4,6-Triisopropylbenzene-sulfonyl azide Chemical Properties |
Melting point | 39-44 °C | refractive index | n20/D1.499 | Fp | 4℃ | storage temp. | 2-8°C | solubility | Chloroform (Slightly), Ethyl Acetate (Slightly) | form | Solid | color | White to Off-White | Water Solubility | Insoluble in water. | BRN | 2391566 | InChIKey | AEMWUHCKKDPRSK-UHFFFAOYSA-N | CAS DataBase Reference | 36982-84-0(CAS DataBase Reference) |
Provider | Language |
ALFA
| English |
| 2,4,6-Triisopropylbenzene-sulfonyl azide Usage And Synthesis |
Chemical Properties | White wet solid | Uses | Reagent for:• ;Stereoselective diversity-oriented synthesis of functionalized saccharides1• ;Meyer′s lactamization2Reagent for synthesis of:• ;Antidote to anthrax lethal factor intoxication3• ;Bacterial RNA polymerase inhibitor4• ;Bicyclic extended dipeptide surrogates5• ;Single enantiomers of mycobacterial keomycolic acids6 | Uses | 2,4,6-Triisopropylbenzenesulfonyl azide is used as a reagent for diazo transfer to ketones, e.g. under phase-transfer conditions, giving better yields of sterically-hindered ?-diazo ketones than other methods. It is also used for azide transfer to potassium enolates (KHMDS) to form the ?-azido derivatives. |
| 2,4,6-Triisopropylbenzene-sulfonyl azide Preparation Products And Raw materials |
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