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| | 4-(TRIFLUOROMETHYL)-ALPHA,ALPHA,ALPHA-TRIFLUOROACETOPHENONE Basic information |
| Product Name: | 4-(TRIFLUOROMETHYL)-ALPHA,ALPHA,ALPHA-TRIFLUOROACETOPHENONE | | Synonyms: | 4-(TRIFLUOROMETHYL)-A,A,A-TRIFLUOROACETOPHENONE;4-(TRIFLUOROMETHYL)-ALPHA,ALPHA,ALPHA-TRIFLUOROACETOPHENONE;2,2,2-Trifluoro-1-[4-(trifluoromethyl)phenyl]ethan-1-one, 4-(Trifluoroacetyl)benzotrifluoride;2,2,2-TRIFLUORO-1-(4-TRIFLUOROMETHYL-PHENYL)-ETHANONE;2,2,2-TRIFLUORO-4'-(TRIFLUOROMETHYL)ACETOPHENONE;2,2,2-Trifluoro-4'-(trifluoromethyl)acetophenone 98%;2,2,2-Trifluoro-4'-(trifluoromethyl)acetophenone98%;4-(Trifluoromethyl)-α,α,α-trifluoroacetophenone | | CAS: | 74853-66-0 | | MF: | C9H4F6O | | MW: | 242.12 | | EINECS: | | | Product Categories: | | | Mol File: | 74853-66-0.mol |  |
| | 4-(TRIFLUOROMETHYL)-ALPHA,ALPHA,ALPHA-TRIFLUOROACETOPHENONE Chemical Properties |
| Boiling point | 75°C 20mm | | density | 1.417±0.06 g/cm3(Predicted) | | refractive index | 1.415 | | Fp | 55 | | storage temp. | Sealed in dry,Room Temperature | | form | liquid | | color | Almost colourless |
| Hazard Codes | Xi | | Risk Statements | 36/37/38 | | Safety Statements | 26-36/37/39-37/39-24/25 | | RIDADR | 1993 | | Hazard Note | Irritant/Lachrymator | | HazardClass | 3.2 | | PackingGroup | III | | HS Code | 29147000 |
| | 4-(TRIFLUOROMETHYL)-ALPHA,ALPHA,ALPHA-TRIFLUOROACETOPHENONE Usage And Synthesis |
| Uses | 2,2,2-Trifluoro-1-(4-(trifluoromethyl)phenyl)ethanone can be used in the synthesis of tetrahydropyranones through catalytic enantioselective oxa-?hetero-?Diels-?Alder reactions of enones with aryl trifluoromethyl ketones. |
| | 4-(TRIFLUOROMETHYL)-ALPHA,ALPHA,ALPHA-TRIFLUOROACETOPHENONE Preparation Products And Raw materials |
| Raw materials | Benzene, 1-[2,2-difluoro-1-[(trimethylsilyl)oxy]ethenyl]-4-(trifluoromethyl)--->4-TRIFLUOROMETHYLPHENYLMAGNESIUMBROMIDE-->2,2,2-trifluoro-1-[4-(trifluoromethyl)phenyl]ethan-1-ol-->PHENYL TRIFLUOROACETATE-->4-Trifluoromethylphenylboronic acid-->Ethyl trifluoroacetate-->carbon monoxide-->Trifluoroacetic acid-->4-Iodobenzotrifluoride-->Ethyl trifluoropyruvate-->4-(Trifluoromethyl)benzaldehyde-->Trifluoroacetic anhydride | | Preparation Products | Methanesulfonic acid, 1,1,1-trifluoro-, 2,2,2-trifluoro-1-[4-(trifluoromethyl)phenyl]ethyl ester |
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