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| 2-(DIMETHYLSILYL)PYRIDINE Basic information |
| 2-(DIMETHYLSILYL)PYRIDINE Chemical Properties |
Boiling point | 175-178 °C(Press: 758 Torr) | density | 0.92 | refractive index | n20/D 1.499 | Fp | 41 °C | storage temp. | 2-8°C | solubility | soluble in most common organic solvents. | pka | 5.40±0.12(Predicted) | CAS DataBase Reference | 21032-48-4 |
Hazard Codes | Xi | Risk Statements | 10-36/37/38 | Safety Statements | 36-26 | RIDADR | UN 1993 3/PG 3 | WGK Germany | 3 |
| 2-(DIMETHYLSILYL)PYRIDINE Usage And Synthesis |
Physical properties | bp 68–72 °C/20 mm Hg. | Uses | 2-Pyridyldimethylsilane is reagent used for metal-catalyzed hydrosilylation of alkynes and
alkenes.Presumably because of the presence of catalyst-directing pyridyl group on silicon, 2- pyridyldimethylsilane exhibits greater reactivity in Rh-catalyzed hydrosilylation of alkenes than those of other related hydrosilanes. Moreover, the presence of the basic pyridyl group enables easy product separation and facile catalyst recovery through simple acid/base extraction. | Uses | A useful scaffold for a number of reactions including hydrosilylation, cross-coupling, and olefination. | Preparation | 2-Pyridyldimethylsilane can be prepared by reaction of 2-pyridyllithium
with chlorodimethylsilane in dry Et2O at ?78°Cunder
argon. |
| 2-(DIMETHYLSILYL)PYRIDINE Preparation Products And Raw materials |
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