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1,4-Bis(diphenylphosphino)butane

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Products Intro: Product Name:1,4-Bis(diphenylphosphino)butane
CAS:7688-25-7
Purity:99%+HPLC Package:100g;200g;500g;1kg;5kg;10kg;25kg
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Products Intro: Product Name:1,4-Bis(diphenylphosphino)butane
CAS:7688-25-7
Purity:99% Package:1Kg
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CAS:7688-25-7
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CAS:7688-25-7
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Products Intro: Product Name:1,4-Bis(diphenylphosphino)butane
CAS:7688-25-7
Purity:98%(Min,HPLC) Package:1G;1KG;100KG

1,4-Bis(diphenylphosphino)butane manufacturers

1,4-Bis(diphenylphosphino)butane Basic information
Product Name:1,4-Bis(diphenylphosphino)butane
Synonyms:98% DPPB;Tetramethylenebis(diphenylphosphine) DPPB;1,4-Bis(diphenylphosphino)butane, 98% 5GR;1,4-Bis(diphenylphosphiNA)butane;1,4-Bis(diphenylphosphino)buta;1,4-Bis(diphenylphosphino)butane Butane-1,4-diylbis[diphenylphosphine];1,4-Butylenebis(diphenylphosphine);1,4-diphenyl phosphinobutane
CAS:7688-25-7
MF:C28H28P2
MW:426.47
EINECS:231-698-7
Product Categories:Phosphines;Phosphine Ligands;Synthetic Organic Chemistry;Ligand;Achiral Phosphine;Aryl Phosphine;organophosphine ligand
Mol File:7688-25-7.mol
1,4-Bis(diphenylphosphino)butane Structure
1,4-Bis(diphenylphosphino)butane Chemical Properties
Melting point 132-136 °C (lit.)
Boiling point 542.0±33.0 °C(Predicted)
storage temp. Inert atmosphere,Room Temperature
form Crystalline Powder
color White to almost white
Water Solubility Soluble in chloroform. Slightly soluble in water
BRN 706446
InChIInChI=1S/C28H28P2/c1-5-15-25(16-6-1)29(26-17-7-2-8-18-26)23-13-14-24-30(27-19-9-3-10-20-27)28-21-11-4-12-22-28/h1-12,15-22H,13-14,23-24H2
InChIKeyBCJVBDBJSMFBRW-UHFFFAOYSA-N
SMILESP(CCCCP(C1C=CC=CC=1)C1C=CC=CC=1)(C1C=CC=CC=1)C1C=CC=CC=1
CAS DataBase Reference7688-25-7(CAS DataBase Reference)
NIST Chemistry Reference1,4-Bis(diphenylphosphino)butane(7688-25-7)
EPA Substance Registry SystemPhosphine, 1,4-butanediylbis[diphenyl- (7688-25-7)
Safety Information
Hazard Codes Xi,F
Risk Statements 36/38-36/37/38-11
Safety Statements 26-36-37/39-33-16-7/9
WGK Germany 3
10-23
TSCA Yes
HS Code 29319090
MSDS Information
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1,4-Bis(diphenylphosphino)butane Usage And Synthesis
Chemical Propertieswhite to light yellow crystal powde
Uses1,4-Bis(diphenylphosphino)butane is used in Suzuki reaction. It plays an essential role as a ligand in palladium(0)-catalyzed acylcyanation of arylacetylenes and deprotection of allyloxycarbamates. It acts as a ligand for alkylations, isomerization reactions and in organometallic chemistry. Further, it is used in Heck reaction, Negishi coupling and Sonogashira coupling. In addition to this, it is useful in organometallic chemistry.
storageReadily oxidized in solution to the phosphine oxide and should be handled under N2 or Ar. The compound is air-stable in the solid state.
Purification MethodsRecrystallise it from EtOH [Trippett J Chem Soc 4263 1961]. [King J Coord Chem 1 62 1971, Tolman Chem Rev 77 313 1977.]
Tag:1,4-Bis(diphenylphosphino)butane(7688-25-7) Related Product Information
N-(Carboxymethyl)-N-(phosphonomethyl)-glycine 1,3-Diphenyl-2-thiourea Dichlorodiphenylsilane Chlorodiphenylphosphine Diphenylphosphine oxide 1,3-Bis(diphenylphosphino)propane (2S,4S)-(-)-N-BOC-4-Diphenylphosphino-2-diphenylphosphinomethyl-pyrrolidine (2S,4S)-4-Diphenylphosphino 2-diphenylphosphinomethyl pyrrolidine TETRAMETHYLENEBIS(TRIPHENYLPHOSPHONIUM BROMIDE) (-)-DIOP (+)-DIOP 1,4-Bis(diphenylphosphino)butane-palladium(II) chloride (2R,3R)-(+)-BIS(DIPHENYLPHOSPHINO)BUTANE,(2R,3R)-(+)-Bis(diphenylphosphino)butane, (R,R)-CHIRAPHOS (2S,3S)-(-)-BIS(DIPHENYLPHOSPHINO)BUTANE Phenyl phosphine Diphenylphosphine (1R,2R)-(-)-1,2-BIS(DIPHENYLPHOSPHINOMETHYL)CYCLOHEXANE (2R,5R)-(+)-BIS(DIPHENYLPHOSPHINO)HEXANE