- 9-BBN TRIFLATE
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- $1.00 / 1KG
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2019-07-10
- CAS:62731-43-5
- Min. Order: 1KG
- Purity: 99%
- Supply Ability: 25kg
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| | 9-BBN TRIFLATE Basic information |
| Product Name: | 9-BBN TRIFLATE | | Synonyms: | 9-BORABICYCLO[3.3.1]NONYL TRIFLUOROMETHANESULFONATE;9-BBN TRIFLATE;9-bbn triflate solution;9-borabicyclo(3.3.1)nonanyl trifluoromethanesulphonate;9-Borabicyclo[3.3.1]nonyl trifluoromethanesulfonate solution;9-BBN TRIFLATE, 0.5M SOLUTION IN HEXANES;9-BBN TRIFLATE SOLUTION, ~0.5 M IN HEXAN E;9-BBN triflate solution, 9-Borabicyclo[3.3.1]nonyl trifluoromethanesulfonate solution | | CAS: | 62731-43-5 | | MF: | C9H14BF3O3S | | MW: | 270.07 | | EINECS: | | | Product Categories: | | | Mol File: | 62731-43-5.mol |  |
| | 9-BBN TRIFLATE Chemical Properties |
| Boiling point | 265.7±50.0 °C(Predicted) | | density | 0.733 g/mL at 25 °C | | Fp | -22 °C | | solubility | sol common inert organic solvents such as Et2O, CH2Cl2, and hexane. | | form | liquid | | BRN | 995656 |
| | 9-BBN TRIFLATE Usage And Synthesis |
| Uses | Reactant for:
- Preparation of a dialkylborenium ion stabilized by an N-heterocyclic carbene
- Mukaiyama aldol addition
- Preparation of porphyrin dimethyldioxanyl tolyl derivative complex
- Preparation of palladium porphyrin complexes
- Boron-mediated β-alkoxy Me ketone aldol addition reactions
| | Application | 9-Bbn triflate can be used to prepare Lewis acids of vinyloxyboranes and boryl nitrify salts; a catalyst for the coupling of silyl enol ethers and acetals; and a catalyst for the isomerization of epoxides to allyl alcohols. | | Preparation | Equimolar amounts of 9-Borabicyclo[3.3.1]nonane and Trifluoromethanesulfonic Acid are mixed in hexane and stirred at 20 °C for 24 h after which time 9-BBN TRIFLATE is isolated by vacuum distillation. | | reaction suitability | reagent type: reductant | | storage | Use in a fume hood; the neat liquid as well as solutions are moisture and air sensitive; therefore the material should be stored and transferred under a dry inert atmosphere. |
| | 9-BBN TRIFLATE Preparation Products And Raw materials |
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