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| DICHLORO[(R)-(+)-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHYL]RUTHENIUM (II) Basic information | Reaction |
Product Name: | DICHLORO[(R)-(+)-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHYL]RUTHENIUM (II) | Synonyms: | Dichloro〔(R)-(+)-2,2-bis(diphenylphosphino)-1,1-binaphthyl)ruthenium(Ⅱ);Dichloro[(R)-(+)-2,2'-bis(diphenylphosphino)-1, 1'-binaphthyl]ruthenium(II), min. 95%;[(R)-BINAP]RUCL2;[(R)-(+)-2,2'-Bis-(diphenylphosphino)-1,1'-binaphthyl] ruthenium dichloride;Dichloro[(R)-(+)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl]rutheniuM(II),95% [(R)-BINAP]RuCl2;Dichloro [(R)-(+)-2,2'-bis(diphenylphosphino)-1,1'-binaphathyl] rutheniuM(II);(R)-[2,2′-Bis(diphenylphosphino)-1,1′-binaphthyl]dichlororutheniuM;Dichloro[(R)-(+)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl]rutheniuM(II),(R-BINAP)RuCl2 | CAS: | 132071-87-5 | MF: | C44H32Cl2P2Ru | MW: | 794.65 | EINECS: | 623-973-9 | Product Categories: | Ru;Catalysts for Organic Synthesis;Classes of Metal Compounds;Homogeneous Catalysts;Metal Complexes;Ru (Ruthenium) Compounds;Synthetic Organic Chemistry;Transition Metal Compounds | Mol File: | 132071-87-5.mol | ![DICHLORO[(R)-(+)-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHYL]RUTHENIUM (II) Structure](CAS/GIF/132071-87-5.gif) |
| DICHLORO[(R)-(+)-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHYL]RUTHENIUM (II) Chemical Properties |
Melting point | >300 ºC | storage temp. | under inert gas (nitrogen or Argon) at 2-8°C | form | Powder | color | orange | Sensitive | air sensitive | InChIKey | YEKBVMDAGDTOQB-UHFFFAOYSA-L | SMILES | C1(C2C3C=CC=CC=3C=CC=2P(C2=CC=CC=C2)C2=CC=CC=C2)C2C=CC=CC=2C=CC=1P(C1=CC=CC=C1)C1C=CC=CC=1.[Ru](Cl)Cl |
| DICHLORO[(R)-(+)-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHYL]RUTHENIUM (II) Usage And Synthesis |
Reaction |
- Enantioselective catalyst for the asymmetric hydrogenation of α,β-unsaturated olefins.
- Efficient catalyst for the asymmetric reduction of carbonyl groups, such as β-ketoesters.
| Uses | (R)?-?[2,?2''-?Bis(diphenylphosphin?o)?-?1,?1''-?binaphthyl]?dichlororuthenium is a catalyst used in the synthesis of helicobacter pylori lipopolysaccharide structures displaying anti-inflammatory activiy. |
| DICHLORO[(R)-(+)-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHYL]RUTHENIUM (II) Preparation Products And Raw materials |
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