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| 3-Bromo-1,1,1-trifluoroacetone Basic information |
Product Name: | 3-Bromo-1,1,1-trifluoroacetone | Synonyms: | 3-BROMO-1,1,1-TRIFLUORO-2-PROPANONE;3-BROMO-1,1,1-TRIFLUOROACETONE;3-BROMO-1,1,1-TRIFLUOROPANONE;TIMTEC-BB SBB006605;2-Propanone, 3-bromo-1,1,1-trifluoro-;3-Bromo-1,1,1-trifluoropropanone;3-Bromo-1,1,1-trifluoroacetone,min.97%;3-Bromo-1,1,1-trifluoroacetone 98% | CAS: | 431-35-6 | MF: | C3H2BrF3O | MW: | 190.95 | EINECS: | 207-071-9 | Product Categories: | Building Blocks;C3 to C6;Carbonyl Compounds;Chemical Synthesis;Organic Building Blocks;organofluorine compounds;C3 to C6;Carbonyl Compounds;Ketones | Mol File: | 431-35-6.mol | ![3-Bromo-1,1,1-trifluoroacetone Structure](CAS/GIF/431-35-6.gif) |
| 3-Bromo-1,1,1-trifluoroacetone Chemical Properties |
Melting point | <-80°C | Boiling point | 87 °C/743 mmHg (lit.) | density | 1.839 g/mL at 25 °C (lit.) | refractive index | n20/D 1.376(lit.) | Fp | 41 °F | storage temp. | Keep in dark place,Inert atmosphere,2-8°C | form | Liquid | color | Clear colorless to yellow | Specific Gravity | 1.839 | Water Solubility | Immiscible with water. | Sensitive | Lachrymatory | BRN | 1703387 | InChIKey | ONZQYZKCUHFORE-UHFFFAOYSA-N | CAS DataBase Reference | 431-35-6(CAS DataBase Reference) | NIST Chemistry Reference | 1-Bromo-3,3,3-trifluoroacetone(431-35-6) |
Hazard Codes | F,C | Risk Statements | 11-34-37 | Safety Statements | 16-26-36/37/39-45 | RIDADR | UN 2924 3/PG 2 | WGK Germany | 3 | F | 19 | Hazard Note | Corrosive/Flammable/Lachrymatory | HazardClass | 3 | PackingGroup | II | HS Code | 29141900 |
| 3-Bromo-1,1,1-trifluoroacetone Usage And Synthesis |
Chemical Properties | clear colorless to yellowish liquid | Uses | 3-Bromo-1,1,1-trifluoroacetone may be used in the synthesis of:
- 3-nonylthio-1,1,1-trifluoropropan-2-one
- cyclic tetrapeptides containing trifluoromethyl and pentafluoroethyl ketone as zinc binding functional group
- perfluoroalkylated trans-allylic alcohols
| Uses | 1-Bromo-3,3,3-trifluoroacetone is used in the preparation of 3-nonylthio-1,1,1-trifluoropropan-2-one and perfluoroalkylated trans-allylic alcohols. It is involved in the synthesis of cyclic tetrapeptides. Further, it reacts with potassium enolate of ethyl 4,4,4-trifluoroacetoacetate to produce ethyl 2,4-bis(trifluoromethyl)-4-hydroxydihydro-3-furoate. | General Description | 3-Bromo-1,1,1-trifluoroacetone reacts with potassium enolate of ethyl 4,4,4-trifluoroacetoacetate to yield ethyl 2,4-bis(trifluoromethyl)-4-hydroxydihydro-3-furoate. |
| 3-Bromo-1,1,1-trifluoroacetone Preparation Products And Raw materials |
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