- Indium chloride
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- $30.00 / 1kg
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2024-08-15
- CAS:10025-82-8
- Min. Order: 1kg
- Purity: 0.99
- Supply Ability: 10 tons
- Indium chloride
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- $96.00 / 25KG
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2023-10-10
- CAS:10025-82-8
- Min. Order: 25KG
- Purity: 99.99%
- Supply Ability: 200ton
- Indium chloride
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- $0.00 / 1KG
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2023-09-06
- CAS:10025-82-8
- Min. Order: 1KG
- Purity: 99%
- Supply Ability: 500000kg
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| Indium chloride Chemical Properties |
Melting point | 262 °C (dec.)(lit.) | Boiling point | 300°C | density | 3.46 g/mL at 25 °C(lit.) | vapor pressure | 1Pa at 25℃ | Fp | 300°C subl. | storage temp. | Inert atmosphere,Room Temperature | solubility | Water (Slightly) | form | powder | Specific Gravity | 3.46 | color | White to off-white | Water Solubility | reacts | Sensitive | Hygroscopic | Crystal Structure | AlCl3 type | crystal system | Monoclinic | Merck | 14,4958 | Space group | C2/m | Lattice constant | a/nm | b/nm | c/nm | α/o | β/o | γ/o | V/nm3 | 0.641 | 1.11 | 0.631 | 90 | 109.8 | 90 | 0.422 |
| Exposure limits | ACGIH: TWA 0.1 mg/m3 NIOSH: TWA 0.1 mg/m3 | Stability: | hygroscopic | InChIKey | PSCMQHVBLHHWTO-UHFFFAOYSA-K | LogP | 5.9 at 22℃ | CAS DataBase Reference | 10025-82-8(CAS DataBase Reference) | NIST Chemistry Reference | Indium trichloride(10025-82-8) | EPA Substance Registry System | Indium chloride (InCl3) (10025-82-8) |
Hazard Codes | C | Risk Statements | 36/37/38-34-29-22 | Safety Statements | 26-36/37/39-45 | RIDADR | UN 3260 8/PG 2 | WGK Germany | 3 | RTECS | NL1400000 | F | 3-10 | TSCA | Yes | HazardClass | 8 | PackingGroup | III | HS Code | 28273990 | Hazardous Substances Data | 10025-82-8(Hazardous Substances Data) | Toxicity | MLD s.c. in rats: 10.2 mg/kg; MLD i.v. in rabbits: 0.64 mg/kg, McCord et al., J. Ind. Hyg. Toxicol. 24, 243 (1942) |
| Indium chloride Usage And Synthesis |
Description | Indium chloride is a useful catalyst for aqueous organic reactions including C-C bond formation, aldol reaction, Friedel-Crafts acylation, Diels-Alder reaction and reduction1-4. It is an efficient, mild, Lewis acid for organic synthesis. It is an efficient catalyst for thioacetalization and its chemoselectivity. It can also catalyze the enantioselective ring-opening of meso-aziridines with thiols. Moreover, it can act as a highly efficient catalyst in water for the preparation of furyl glycosides.
| Chemical Properties | white crystalline powder Hygroscopic. Decomposes in
water to InCl3 and In. M.p. 235°C; decomposes below the m.p.,
apparently to InCl3 and InCl; b.p. ~570°C; d 3.65. Rhombic
crystals. | Uses | Indium(III) chloride is used as catalyst for aqueous organic reactions including C-C bond formation, aldol reactions, and reductions and for organic synthesis. | Uses | In electroplating using a solution of the salt with dextrose and NaCN. This solution is stable, though it turns dark on standing and deposits a mud which, however, contains no indium. | Uses | Catalyzes the enantioselective ring-opening of meso-aziridines with thiols.1,2 A highly efficient catalyst in water for the preparation of furyl glycosides.3 | Production Methods |
According to Klemm, metallic In is oxidized in InCl3 in a stream of Cl2, which has been carefully dried with concentrated H2SO4 and P2O5. A thoroughly dried quartz apparatus whose components have been fused or connected by ground joints is used. Chlorination proceeds rather vigorously at first, with a pale glow, and it proceeds through the mono- and dichloride steps. These compounds are melts. The end product of the chlorination, InCl3, sublimes around 600°C as lustrous spangles which appear on the walls of the receiver. The Indium chloride (LnCl3) may be purified by subliming in a stream of N2 (or CO2) to which some Cl2 has been added. The sublimate can cool in a stream of inert, Cl2-free gas to remove excess chlorine.
| General Description | Indium(III) chloride (InCl3) is an indium halide that is a Lewis acid in a variety of organic reactions. | Hazard | See indium. | Purification Methods | The anhydrous salt forms yellow deliquescent crystals which can be sublimed at 600o in the presence of Cl2/N2 (1:1) [does not melt]. It is resublimed in the presence of Cl2/N2 (1:10) and finally heated to 150o to expel excess Cl2. It is soluble in H2O and should be stored in a tightly closed container. [Baxter & Alter J Am Chem Soc 55 1943 1933.] |
| Indium chloride Preparation Products And Raw materials |
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