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J & K SCIENTIFIC LTD.
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010-82848833 400-666-7788 |
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Product Name:1,1'-Bis{(S)-4,5-dihydro-3H-binaphtho[1,2-c:2',1'-e]phosphino}ferrocene, min. 98% (S,S)-f-Binaphane CAS:544461-38-3 Purity:min. 98% Package:100mg;500mg
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Company Name: |
Shanghai Aladdin Bio-Chem Technology Co.,LTD
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400-400-6206333 18521732826 |
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Products Intro: |
Product Name:1,1'-Bis{(S)-4,5-dihydro-3H-binaphtho[1,2-c:2',1'-e]phosphino}ferrocene CAS:544461-38-3 Purity:98% Package:100mg/RMB 2752.90;500mg/RMB 5400.00
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Company Name: |
Tianjin heowns Biochemical Technology Co., Ltd.
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400-638-7771 18920764717 |
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sales@heowns.com |
Products Intro: |
Product Name:1,1'-Bis{(S)-4,5-dihydro-3H-binaphtho[1,2-c:2',1'-e]phosphino}ferrocene CAS:544461-38-3 Purity:98% Package:0.1g
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| (S,S)-F-BINAPHANE Basic information | Reaction |
Product Name: | (S,S)-F-BINAPHANE | Synonyms: | (S,S)-F-BINAPHANE;1,1'-Bis{(S)-4,5-dihydro-3H-binaphtho[1,2-c:2',1'-e]phosphino}ferrocene, Min. 98% (S,S)-f-Binaphane;1,1μ-Bis[(S)-4,5-dihydro-3H-binaphtho[2,1-c:1μ,2μ-e]phosphepino]ferrocene, 1,1μ-Bis[(11bs)-3,5-dihydro-4H-dinaphtho[2,1-c:1μ,2μ-e]phosphenpin-4yl]ferrocene;1,1'-Bis[(S)-4,5-dihydro-3H-binaphtho[1,2-c:2',1'-e]phosphino]ferrocene;1,1'-Bis{(S)-4,5-dihydro-3H-binaphtho[1,2-c:2',1'-e]phosphino}ferrocene (S,S)-f-Binaphane;1,1'-Bis{(S)-4,5-dihydro-3H-binaphtho[1,2-c:2',1'-e]phosphino}ferrocene | CAS: | 544461-38-3 | MF: | C54H32FeP2 | MW: | 798.64 | EINECS: | | Product Categories: | | Mol File: | 544461-38-3.mol | |
| (S,S)-F-BINAPHANE Chemical Properties |
form | Powder | color | yellow-brown | Sensitive | air sensitive, light sensitive |
| (S,S)-F-BINAPHANE Usage And Synthesis |
Reaction |
- Ligand for enantioselective Pd-catalyzed hydrogenation of enesulfonamides [5] and cyclic Nsulfonylimines.
- Enantioselective, asymmetric organocatalyst for cycloaddition of allenoates to C60 fullerene (conversion >90%, ee up to 90%)
- Ligand for Iridium-mediated direct asymmetric reductive amination of acetophenone with phenylhydrazide (conversion >99%; yield >94%; ee >94%)
- Ligand used for the palladium-catalyzed, asymmetric, decarboxylative generation and asymmetric allylation of α-imino anions.
- Ligand used in iridium-catalyzed, asymmetric hydrogenation of 6-substituted 3-hydroxypyridinium salts to trans 6-substituted piperidin-3-ols with high enantioselectivities(up to 95% ee).
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| (S,S)-F-BINAPHANE Preparation Products And Raw materials |
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