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| ETHYL 2-NITROPROPIONATE Basic information |
| ETHYL 2-NITROPROPIONATE Chemical Properties |
Boiling point | 75-76 °C/9 mmHg (lit.) | density | 1.13 g/mL at 25 °C (lit.) | refractive index | n20/D 1.421(lit.) | Fp | 193 °F | pka | 5.98±0.10(Predicted) | Water Solubility | Not miscible in water. | BRN | 774734 | EPA Substance Registry System | Propanoic acid, 2-nitro-, ethyl ester (2531-80-8) |
Hazard Codes | Xi | Risk Statements | 36/37/38 | Safety Statements | 26-36/37/39 | RIDADR | NA 1993 / PGIII | WGK Germany | 3 | TSCA | Yes | HazardClass | IRRITANT |
| ETHYL 2-NITROPROPIONATE Usage And Synthesis |
Uses | Ethyl 2-nitropropionate is used in the preparation of (-)-trans-2,5-dimethylprolineethyl ester via enantioselective Michael reaction methyl vinyl ketone using modified dihydroquinine as catalyst, novel nitrogen-15-labeled nitrone spin trap, 5-ethoxycarbonyl-5-methyl-1-pyrroline N-oxide ([15N]EMPO) for detecting superoxide anion, 2-ethoxycarbonyl-2-nitropentanal. It is used for enantioselective Michael reactions. | Uses | Ethyl 2-nitropropionate was used in the preparation of:
- (?)-trans-2,5-dimethylprolineethyl ester via enantioselective Michael reaction methyl vinyl ketone using modified dihydroquinine as catalyst
- novel nitrogen-15-labeled nitrone spin trap, 5-ethoxycarbonyl-5-methyl-1-pyrroline N-oxide ([15N]EMPO) for detecting superoxide anion
- 2-ethoxycarbonyl-2-nitropentanal
| General Description | Ethyl 2-nitropropionate is a nitro ester. |
| ETHYL 2-NITROPROPIONATE Preparation Products And Raw materials |
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