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| (R)-3,3'-BIS(TRIPHENYLSILYL)-1,1'-BI-2-& Basic information |
Product Name: | (R)-3,3'-BIS(TRIPHENYLSILYL)-1,1'-BI-2-& | Synonyms: | (R)-3,3'-BIS(TRIPHENYLSILYL)-1,1'-BI-2-&;(R)-3,3μ-Bis(triphenylsilyl)-1,1μ-bi-2-naphthol;(R)-3,3μ-Bis(triphenylsilyl)-1,1μ-binaphthalene-2,2μ-diol;(R)-(+)-3,3'-Bis(triphenylsilyl)-1,1'-bi-2,2'-naphthol;(R)-3,3'-Bis(triphenylsilyl)-1,1'-bi-2-naphthol 96%;(R)-3,3'-Bis(triphenylsilyl)-1,1'-bi-2-naphthol, 99%e.e.;[1,1'-Binaphthalene]-2,2'-diol, 3,3'-bis(triphenylsilyl)-, (1R)-;(1R)-3,3'- bis (triphenylsilyl) [1,1'- binaphthyl ]-2,2'- diol | CAS: | 111822-69-6 | MF: | C56H42O2Si2 | MW: | 803.1 | EINECS: | | Product Categories: | | Mol File: | 111822-69-6.mol | ![(R)-3,3'-BIS(TRIPHENYLSILYL)-1,1'-BI-2-& Structure](CAS/GIF/111822-69-6.gif) |
| (R)-3,3'-BIS(TRIPHENYLSILYL)-1,1'-BI-2-& Chemical Properties |
Melting point | 103-145 °C | density | 1.27±0.1 g/cm3(Predicted) | pka | 8.06±0.50(Predicted) | optical activity | [α]20/D +114°, c = 1 in chloroform |
Safety Statements | 24/25 | WGK Germany | 3 | HS Code | 29319090 |
| (R)-3,3'-BIS(TRIPHENYLSILYL)-1,1'-BI-2-& Usage And Synthesis |
Chemical Properties | White powder | Uses | Precursor to a chiral Bronsted acid (674745) used to catalyze an enantioselective aza Diels-Alder reaction providing bicyclic lactams. Rare earth metal complexes of this chiral binapthol catalyze an intramolecular hydroamination of amino olefins leading to chiral pyrrolidines. |
| (R)-3,3'-BIS(TRIPHENYLSILYL)-1,1'-BI-2-& Preparation Products And Raw materials |
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