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| N-(TRIMETHYLSILYL)BIS(TRIFLUOROMETHANESULFONYL)IMIDE Basic information |
| N-(TRIMETHYLSILYL)BIS(TRIFLUOROMETHANESULFONYL)IMIDE Chemical Properties |
Boiling point | 115 °C / 2mmHg | density | 1.543±0.06 g/cm3(Predicted) | storage temp. | Freezer | solubility | soluble in most common organic solvents, commonly
used in dichloromethane, toluene, diethyl ether. | form | clear liquid | pka | -26.49±0.70(Predicted) | color | Colorless to Red to Green |
| N-(TRIMETHYLSILYL)BIS(TRIFLUOROMETHANESULFONYL)IMIDE Usage And Synthesis |
Physical properties | colorless liquid, bp: 115°C(2 Torr). | Uses | Methanesulfonamide, 1,1,1-Trifluoro-
N[(trifluoromethyl)sulfonyl]-
N(trimethylsilyl)-? can be used as Lewis acid catalyst for a variety of organic transformations. | Preparation | It is easily prepared in situ through protodesilation
by mixing commercially available allyltrimethylsilane
(or any TMS enol ether) and Tf2NH. Originally prepared
by mixing Tf2NH with trimethylsilane at low temperature or
mixing AgNTf2 with TMSCl. |
| N-(TRIMETHYLSILYL)BIS(TRIFLUOROMETHANESULFONYL)IMIDE Preparation Products And Raw materials |
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