ChemicalBook > Product Catalog >Organic Chemistry >Organometallic compounds >Organic iron >(S)-(+)-[(S)-2-Diphenylphosphinoferrocenyl] (N,N-dimethylamino) (2-diphenylphosphinophenyl)methane, min. 97% TANIAPHOS

(S)-(+)-[(S)-2-Diphenylphosphinoferrocenyl] (N,N-dimethylamino) (2-diphenylphosphinophenyl)methane, min. 97% TANIAPHOS

(S)-(+)-[(S)-2-Diphenylphosphinoferrocenyl] (N,N-dimethylamino) (2-diphenylphosphinophenyl)methane, min. 97% TANIAPHOS Suppliers list
Company Name: Zhengzhou Alfa Chemical Co.,Ltd
Tel: +8618530059196
Email: sale04@alfachem.cn
Products Intro: CAS:850444-36-9
Purity:97%+ Package:100g,500g,1kg,50kg,100kg
Company Name: Shaanxi Dideu Medichem Co. Ltd
Tel: +86-029-89586680 +86-18192503167
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Products Intro: Product Name:(S)-(+)-[(S)-2-Diphenylphosphinoferrocenyl] (N,N-dimethylamino) (2-diphenylphosphinophenyl)methane, min. 97% TANIAPHOS
CAS:850444-36-9
Purity:99.00% Package:25kgs/Drum;200kgs/Drum Remarks:ISO 9001:2015 REACH Approved Manufacturer
Company Name: Aladdin Scientific
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Email: sales@aladdinsci.com
Products Intro: Product Name:(2R)-1-[(S)-α-(Dimethylamino)-2-(diphenylphosphino)benzyl]-2-diphenylphosphinoferrocene
CAS:850444-36-9
Purity:99+% Package:$138.9/250mg;Bulk package Remarks:99+%
Company Name: J & K SCIENTIFIC LTD.  
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Products Intro: Product Name:(S)-(-)-[(S)-2-Diphenylphosphinoferrocenyl](N,N-dimethylamino)(2-diphenylphosphinophenyl)methane, min. 97% TANIAPHOS
CAS:850444-36-9
Purity:min. 97% Package:100mg;10g;2g;500mg
Company Name: Beijing HwrkChemical Technology Co., Ltd  
Tel: 010-89508211 18501085097
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Products Intro: Product Name:(SP)-1-[(S)-α-(Dimethylamino)-2-(diphenylphosphino)benzyl]-2-diphenylphosphinoferrocene
CAS:850444-36-9
Purity:99.00% Package:5g;500mg;1g
(S)-(+)-[(S)-2-Diphenylphosphinoferrocenyl] (N,N-dimethylamino) (2-diphenylphosphinophenyl)methane, min. 97% TANIAPHOS Basic information
Reactions
Product Name:(S)-(+)-[(S)-2-Diphenylphosphinoferrocenyl] (N,N-dimethylamino) (2-diphenylphosphinophenyl)methane, min. 97% TANIAPHOS
Synonyms:(S)-(-)-[(S)-2-Diphenylphosphinoferrocenyl](N,N-dimethylamino)(2-
diphenylphosphinophenyl)methane, min. 97% TANIAPHOS
;(S)-(-)-[(S)-2-Diphenylphosphinoferrocenyl](N,N-diMethylaMino)(2-diphenylphosphinophenyl)Methane;97% TANIAPHOS;(S)-1-Diphenylphosphino-2-[(S)-a-(N,N-dimethylamino)-o-(diphenylphosphinophenyl)-methyl]ferrocene;(S)-(-)-[(S)-2-Diphenylphosphinoferrocenyl] (N,N-diMethylaMino) (2-diphenylphosphinophenyl)Methane TANIAPHOS;(SP)-1-[(S)-alpha-(DiMethylaMino)-2-(diphenylphosphino)benzyl]-2-diphenylphosphinoferrocene >=97%, optical purity ee: >=99%;Taniaphos SL-T001-2, (2R)-1-[(S)-(Dimethylamino)[2-(diphenylphosphino)phenyl]methyl]-2-(diphenylphosphino)ferrocene (acc to CAS);(S)-(+)-[(S)-2-Diphenylphosphinoferrocenyl] (N,N-dimethylamino) (2-diphenylphosphinophenyl)methane, min. 97% TANIAPHOS
CAS:850444-36-9
MF:C38H34NP2.C5H5.Fe
MW:687.581
EINECS:
Product Categories:Chiral Phosphine;Ferrocene Series;Taniaphos Series;metallocene
Mol File:850444-36-9.mol
(S)-(+)-[(S)-2-Diphenylphosphinoferrocenyl] (N,N-dimethylamino) (2-diphenylphosphinophenyl)methane, min. 97% TANIAPHOS Structure
(S)-(+)-[(S)-2-Diphenylphosphinoferrocenyl] (N,N-dimethylamino) (2-diphenylphosphinophenyl)methane, min. 97% TANIAPHOS Chemical Properties
alpha -312° ±15° (c 0.5, CHCl3)
storage temp. 2-8°C
form Powder
color orange
Stability:store cold
Safety Information
WGK Germany 3
HS Code 29319090
MSDS Information
(S)-(+)-[(S)-2-Diphenylphosphinoferrocenyl] (N,N-dimethylamino) (2-diphenylphosphinophenyl)methane, min. 97% TANIAPHOS Usage And Synthesis
Reactions
  1. Ligand for the Ru-catalyzed hydrogenation of $-ketoesters, enamides and itaconates.
  2. Ligand for Cu-catalyzed asymmetric conjugate addition of Grignard reagents to cyclic enones.
  3. AgOAc-catalyzed asymmetric amination of glycine Schiff bases with azodicarboxylates. 
Reactions of 850444-36-9
Chemical PropertiesOrange powder
General Descriptionsold in collaboration with Solvias AG
(S)-(+)-[(S)-2-Diphenylphosphinoferrocenyl] (N,N-dimethylamino) (2-diphenylphosphinophenyl)methane, min. 97% TANIAPHOS Preparation Products And Raw materials
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