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| | alpha-Toluenesulfonyl chloride Basic information |
| | alpha-Toluenesulfonyl chloride Chemical Properties |
| Hazard Codes | C | | Risk Statements | 34 | | Safety Statements | 26-36/37/39-45 | | RIDADR | UN 3261 8/PG 2 | | WGK Germany | 3 | | F | 10-21 | | Hazard Note | Corrosive | | TSCA | T | | HazardClass | 8 | | PackingGroup | II | | HS Code | 29049020 |
| | alpha-Toluenesulfonyl chloride Usage And Synthesis |
| Chemical Properties | almost white crystalline powder | | Uses | a-Toluenesulfonyl Chloride inhibits intracellular protein breakdown in the L1210 ascites leukemia in mouse. It also functions as a reagent for the protection of amino groups as benzylsulfonamides which can be cleaved off through reduction. | | Synthesis Reference(s) | The Journal of Organic Chemistry, 16, p. 621, 1951 DOI: 10.1021/jo01144a013
Synthesis, p. 1203, 1992 DOI: 10.1055/s-1992-26333 | | General Description | Phenylmethanesulfonyl chloride is an aliphatic sulfonyl chloride. It reacts with triethylamine in methylene chloride or ether to yield trans-stilbene and cis diphenylethylene sulfone. Its reaction with 1,1-bis(diethylamino)ethane has been studied. Addition of phenylmethanesulfonyl chloride to 1,3-diphenyl-2-pyrrolidinopropene in the presence of water was studied. |
| | alpha-Toluenesulfonyl chloride Preparation Products And Raw materials |
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