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1-TRIMETHYLSILYLMETHANOL

1-TRIMETHYLSILYLMETHANOL Suppliers list
Company Name: Hebei Mojin Biotechnology Co.,Ltd
Tel: +86-15028179902
Email: angelia@hbmojin.com
Products Intro: Product Name:1-TRIMETHYLSILYLMETHANOL
CAS:3219-63-4
Purity:99% Package:25kg
Company Name: Shanghai Daken Advanced Materials Co.,Ltd
Tel: +86-371-66670886
Email: info@dakenam.com
Products Intro: Product Name:DK264
CAS:3219-63-4
Purity:99% Package:1KG ;10KG ;100KG Remarks:Low M.W.Organic Silanes Professor
Company Name: Hangzhou FandaChem Co.,Ltd.
Tel: +8615858145714
Email: FandaChem@Gmail.com
Products Intro: Product Name:HYDROXYMETHYLTRIMETHYLSILANE
CAS:3219-63-4
Purity:as in COA Package:as customers' requirements
Company Name: ATK CHEMICAL COMPANY LIMITED
Tel: +undefined-21-51877795
Email: ivan@atkchemical.com
Products Intro: Product Name:1-TRIMETHYLSILYLMETHANOL
CAS:3219-63-4
Purity:98% Package:10MG;50MG;100MG,1G,5G,10G.100G
Company Name: Alchem Pharmtech,Inc.
Tel: 8485655694
Email: sales@alchempharmtech.com
Products Intro: Product Name:(Trimethylsilyl)methanol
CAS:3219-63-4
Purity:97+% Package:1g;10g;100g;;1kg Remarks:Z-32646

1-TRIMETHYLSILYLMETHANOL manufacturers

1-TRIMETHYLSILYLMETHANOL Basic information
Product Name:1-TRIMETHYLSILYLMETHANOL
Synonyms:(hydroxymethyl)trimethyl-silan;(trimethylsilyl)-methano;Methanol, (trimethylsilyl)-;Silane, (hydroxymethyl)trimethyl-;TRIMETHYLHYDROXYMETHYLSILANE;(TRIMETHYLSILYL)METHANOL;1-TRIMETHYLSILYLMETHANOL;(HYDROXYMETHYL)TRIMETHYLSILANE
CAS:3219-63-4
MF:C4H12OSi
MW:104.22
EINECS:221-746-5
Product Categories:Si (Classes of Silicon Compounds);Si-(C)4 Compounds;Silicon Compounds (for Synthesis);Synthetic Organic Chemistry
Mol File:3219-63-4.mol
1-TRIMETHYLSILYLMETHANOL Structure
1-TRIMETHYLSILYLMETHANOL Chemical Properties
Melting point <0°C
Boiling point 120-122 °C754 mm Hg(lit.)
density 0.826 g/mL at 25 °C(lit.)
refractive index n20/D 1.419(lit.)
Fp 88 °F
storage temp. 2-8°C
pka15.92±0.10(Predicted)
form clear liquid
color Colorless to Almost colorless
Specific Gravity0.827
Water Solubility Fully miscible in water.
Hydrolytic Sensitivity1: no significant reaction with aqueous systems
BRN 1731486
CAS DataBase Reference3219-63-4(CAS DataBase Reference)
EPA Substance Registry SystemMethanol, (trimethylsilyl)- (3219-63-4)
Safety Information
Hazard Codes Xi
Risk Statements 36/37/38
Safety Statements 26-36
RIDADR UN 1987 3/PG 3
WGK Germany 3
RTECS PC4100000
TSCA Yes
HS Code 2931.90.9010
HazardClass 3
PackingGroup III
MSDS Information
ProviderLanguage
SigmaAldrich English
ALFA English
1-TRIMETHYLSILYLMETHANOL Usage And Synthesis
Uses1-Trimethylsilylmethanol is used as nucleophile to resolve the racemate obtained from enantioselective esterification of naproxen (2-(6-methoxy-2-naphthyl) propionic acid) by lipases. It was also used as a nucleophilic hydroxymethylation agent.
Purification MethodsIf the NMR indicates impurities (should have only two signals), then dissolve it in Et2O, shake this with aqueous 5N NaOH, M H2SO4, saturated aqueous NaCl, dry (MgSO4) and distil it using an efficient column at atmospheric pressure. The 3,5-dinitrobenzoate has m 70-70.5o (from 95% EtOH). [Huang & Wang Acta Chem Sin 23 291 1957, cf. Chem Abstr 52 19911 1958, Speier et al. J Am Chem Soc 81 1844 1959 and Speier et al. J Am Chem Soc 70 1117 1948, Beilstein 4 III 1844, 4 IV 2876.]
1-TRIMETHYLSILYLMETHANOL Preparation Products And Raw materials
Preparation Products(TRIMETHYLSILYL)METHYL TRIFLUOROMETHANESULFONATE-->TRIMETHYLSILYLMETHYL ACETATE
Tag:1-TRIMETHYLSILYLMETHANOL(3219-63-4) Related Product Information
3-BROMO-1-(TRIMETHYLSILYL)-1-PROPYNE TRIMETHYLSILYL DIETHYLPHOSPHONOACETATE (TRIMETHYLSILYL)CYCLOPENTADIENE, MIXTURE OF ISOMERS TRIMETHYLSILYL PROPIONATE TRIMETHYLSILYL TRIFLUOROACETATE 1-TRIMETHYLSILYLMETHANOL (TRIMETHYLSILYL)METHYL TRIFLUOROMETHANESULFONATE 1-(TRIMETHYLSILYL)ETHANOL, 98 (METHOXYMETHYL)TRIMETHYLSILANE (1-ETHOXYVINYL)-TRIMETHYLSILANE ACRYLOXYMETHYLTRIMETHYLSILANE (PHENYLDIMETHYLSILYL)METHYL METHACRYLATE (1-HYDROXYALLYL)TRIMETHYLSILANE 1-TRIETHYLSILYL-4-(TRIETHLYLSILYLOXY)-1-BUTYNE METHACRYLOXYMETHYLTRIMETHYLSILANE (2',5'-bis-O-(tert-butyldimethylsilyl)-beta-ribofuranosyl)-3'-spiro-5''-(4''-amino-1'',2''-oxathiole-2'',2''-dioxide)thymine (1-METHOXYVINYL)TRIMETHYLSILANE TRIMETHYLSILYLMETHYL ACETATE