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| (S,S)-2,6-BIS(4-ISOPROPYL-2-OXAZOLIN-2-YL)PYRIDINE Basic information | Reaction |
Product Name: | (S,S)-2,6-BIS(4-ISOPROPYL-2-OXAZOLIN-2-YL)PYRIDINE | Synonyms: | 2,6-Bis[(4S)-4-isopropyl-2-oxazolin-2-yl]pyridine;2,6-Bis((S);-4-isopropyl-4,5-dihydrooxazol-2-yl);2,6-Bis[(4S)-isopropyl-2-oxazolin-2-yl]pyridine,99%e.e.;(-)-2,6-BIS[(4S)-4-(I-PROPYL)-2-OXAZOLIN-2-YL]PYRIDINE;2,6-BIS[(4S)-(-)-ISOPROPYL-2-OXAZOLIN-2-YL]PYRIDINE;2,6-Bis[(4S)-(-)-isopropyl-2-oxazolin-2-yl]pyridine ,99%;(S,S)-2,2'-(2,6-PYRIDINEDIYL)BIS(4-ISOPROPYL-2-OXAZOLINE) | CAS: | 118949-61-4 | MF: | C17H23N3O2 | MW: | 301.38 | EINECS: | | Product Categories: | organic amine;BOX series;Chiral Nitrogen;Asymmetric Synthesis;Synthetic Organic Chemistry | Mol File: | 118949-61-4.mol | ![(S,S)-2,6-BIS(4-ISOPROPYL-2-OXAZOLIN-2-YL)PYRIDINE Structure](CAS/GIF/118949-61-4.gif) |
| (S,S)-2,6-BIS(4-ISOPROPYL-2-OXAZOLIN-2-YL)PYRIDINE Chemical Properties |
Melting point | 155-157 °C(lit.) | alpha | -120° (c 1.0, CH2Cl2) | Boiling point | 457.1±30.0 °C(Predicted) | density | 1.23±0.1 g/cm3(Predicted) | storage temp. | Inert atmosphere,2-8°C | pka | 3.78±0.70(Predicted) | form | crystal | color | white | optical activity | [α]25/D 118°, c = 0.7 in methylene chloride | BRN | 5824976 |
Hazard Codes | Xi | Risk Statements | 36/37/38 | Safety Statements | 26-36 | WGK Germany | 3 | HS Code | 29309090 |
| (S,S)-2,6-BIS(4-ISOPROPYL-2-OXAZOLIN-2-YL)PYRIDINE Usage And Synthesis |
Reaction |
- Ligand used in the dual-catalyst system for highly enantioselective conjugate cyanation of unsaturated imides.
- Ligand for cross-coupling reactions of iodoalkanes with alkyl zinc halides.
- Ligand for asymmetric 1,4-addition reactions of 1,3-dicarbonyl compounds to nitroalkenes.
- Ligand for asymmetric allylation of aldehydes with b-carbonyl allylstannanes.
- Ligand used in the enantioselective Negishi reaction of racemic secondary benzylic halides.
- Ligand for osmium catalyzed enantioselective transfer hydrogenation.
![Reactions of 118949-61-4_1](/NewsImg/2018-05-03/20185313252243622.jpg)
| Chemical Properties | White powder or crystal or chunks | Uses | Used as a ligand to prepare novel ruthenium-pyridine-carboxylate complexes as new catalytic systems for alkene epoxidation. |
| (S,S)-2,6-BIS(4-ISOPROPYL-2-OXAZOLIN-2-YL)PYRIDINE Preparation Products And Raw materials |
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