((E)-3,3-DIMETHOXY-PROPENYL)-BENZENE

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CAS:4364-06-1
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CAS:4364-06-1
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Products Intro: Product Name:((E)-3,3-DIMETHOXY-PROPENYL)-BENZENE
CAS:4364-06-1
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((E)-3,3-DIMETHOXY-PROPENYL)-BENZENE manufacturers

((E)-3,3-DIMETHOXY-PROPENYL)-BENZENE Basic information
Product Name:((E)-3,3-DIMETHOXY-PROPENYL)-BENZENE
Synonyms:(3,3-dimethoxy-1-propenyl)-benzen;(3,3-dimethoxy-1-propenyl)-Benzene;1,1-dimethoxy-3-phenylprop-2-ene;3-phenyl-2-propenaldimethylacetal;((E)-3,3-DIMETHOXY-PROPENYL)-BENZENE;CINNAMIC ALDEHYDE DIMETHYL ACETAL;CINNAMALDEHYDE DIMETHYL ACETAL;beta-(dimethoxymethyl)styrene
CAS:4364-06-1
MF:C11H14O2
MW:178.23
EINECS:224-454-6
Product Categories:
Mol File:4364-06-1.mol
((E)-3,3-DIMETHOXY-PROPENYL)-BENZENE Structure
((E)-3,3-DIMETHOXY-PROPENYL)-BENZENE Chemical Properties
Boiling point 270.46°C (rough estimate)
density 1.0292 (rough estimate)
refractive index 1.5103 (estimate)
form liquid
Odorat 10.00 % in dipropylene glycol. fresh green spicy cinnamon herbal
Odor Typespicy
LogP2.689 (est)
EPA Substance Registry SystemBenzene, (3,3-dimethoxy-1-propenyl)- (4364-06-1)
Safety Information
toxicityThe acute oral LD50 value in rats was reported as 3.7 g/kg (3.3-4.1 g/kg) (Moreno, 1972a). The acute dermal LD50 value in rabbits exceeded 5 g/kg (Moreno, 1972b).
MSDS Information
((E)-3,3-DIMETHOXY-PROPENYL)-BENZENE Usage And Synthesis
Chemical PropertiesAlmost colorless oily liquid. B.P. 239° C. Sp.Gr. 1.02. Fresh-green, spicy-herbaceous Cassia-cinnamon type odor, more Cassia-like than the Diethyl acetal, yet less harsh than the aldehyde. Sweet spicy -herbaceous taste, but not nearly as sweet as the alciehyde.
OccurrenceHas apparently not been reported to occur in nature.
Uses(E)-Cinnamaldehyde Dimethyl Acetal is synthesized from trans-cinnamaldehyde (C442020) and is used for the preparation of benzyl(aryl)triazoles and their selective human aromatase (cytochrome P 450 19A1) inhibitory activity.
Uses((E)-3,3-DIMETHOXY-PROPENYL)-BENZENE is used as a lasting topnote ingredient in many types of “modem” fragrances, not only in copies of successful French perfumes, but also in general as a novelty along with aldehydic-floral or Oriental-spicy or sweet-woody fragrance types. It forms interesting topnotes with alifatic aldehydes in Rose-Jasmin fragrances, and gives pleasant variations of woody-Oakmoss types. Stable in soap and may introduce Cinnamon type odor when used at a sufficiently high level of concentration.
PreparationBy the interaction of cinnamic aldehyde and methanol in the presence of a catalyst or by treating cinnamic aldehyde with trimethyl orthoformate.
Synthesis Reference(s)The Journal of Organic Chemistry, 35, p. 1962, 1970 DOI: 10.1021/jo00831a052
((E)-3,3-DIMETHOXY-PROPENYL)-BENZENE Preparation Products And Raw materials
Tag:((E)-3,3-DIMETHOXY-PROPENYL)-BENZENE(4364-06-1) Related Product Information
((E)-3,3-DIMETHOXY-PROPENYL)-BENZENE A-AMYL CINNAMIC ALDEHYDE DIETHYL ACETAL FEMA 2062 CINNAMALDEHYDE DIETHYL ACETAL Methyl isoeugenol Acrolein dimethyl acetal trans-Cinnamaldehyde RARECHEM AL BP 0138 RARECHEM AL BP 0333 RARECHEM AL BP 0194 RARECHEM AL BP 0119 RARECHEM AL BP 0669 RARECHEM AL BP 0241 SPECS AQ-776/42801261 CINNAMALDEHYDE PROPYLENE GLYCOL ACETAL RARECHEM AL BP 0672 RARECHEM AL BP 0125 RARECHEM AL BP 0727

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