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Product Name:(S)-(-)-4-[2-(Diphenylphosphino)-1-naphthalenyl]-N-[(R)-1-phenylethyl]-1-phthalazinamine, min. 97% (R,S)-N-PINAP CAS:828927-96-4 Purity:min. 97% Package:1g;250mg
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| (S)-(-)-4-[2-(DIPHENYLPHOSPHINO)-1-NAPHTHALENYL]-N-[-1-PHENYLETHYL]-1-PHTHALAZINAMINE,(S)-N-PINAP Basic information | Reactions |
Product Name: | (S)-(-)-4-[2-(DIPHENYLPHOSPHINO)-1-NAPHTHALENYL]-N-[-1-PHENYLETHYL]-1-PHTHALAZINAMINE,(S)-N-PINAP | Synonyms: | (S)-(-)-4-[2-(DIPHENYLPHOSPHINO)-1-NAPHTHALENYL]-N-[?-1-PHENYLETHYL]-1-PHTHALAZINAMINE,(S)-N-PINAP;(S)-(-)-4-[2-(Diphenylphosphino)-1-naphthalenyl]-N-[(R)-1-phenylethyl]-1-phthalazinaMine (R,S)-N-PINAP;(1S)-4-[2-(diphenylphosphino)-1-naphthalenyl]-N-[(1R)-1-phenylethyl]-1-Phthalazinamine;(S)-4-[2-(DIPHENYLPHOSPHINO)-1-NAPHTHALENYL]-N-[(1R)-1-PHENYLETHYL]-1-PHTHALAZINAMINE;(S)-(-)-4-[2-(Diphenylphosphino)-1-naphthalenyl]-N-[(R)-1-phenylethyl]-1-phthalazinamine;(S)-(-)-4-[2-(Diphenylphosphino)-1-naphthalenyl]-N-[(R)-1-phenylethyl]-1-phthalazinamine,min.97%(S)-N-PINAP;(S)-(-)-4-[2-(Diphenylphosphino)-1-naphthalenyl]-N-[(R)-1-phenylethyl]-1-phthalazinamine, min. 97% (R,S)-N-PINAP;1-Phthalazinamine, 4-[2-(diphenylphosphino)-1-naphthalenyl]-N-[(1R)-1-phenylethyl]-, (1S)- | CAS: | 828927-96-4 | MF: | C38H30N3P | MW: | 559.64 | EINECS: | | Product Categories: | Chiral Phosphine;PINAP Series | Mol File: | 828927-96-4.mol | |
| (S)-(-)-4-[2-(DIPHENYLPHOSPHINO)-1-NAPHTHALENYL]-N-[-1-PHENYLETHYL]-1-PHTHALAZINAMINE,(S)-N-PINAP Chemical Properties |
Melting point | >210°C | alpha | -162° (c 0.54, CHCl3) | Boiling point | 732.0±60.0 °C(Predicted) | pka | 5.35±0.30(Predicted) | form | crystal | color | colorless | Sensitive | air sensitive |
| (S)-(-)-4-[2-(DIPHENYLPHOSPHINO)-1-NAPHTHALENYL]-N-[-1-PHENYLETHYL]-1-PHTHALAZINAMINE,(S)-N-PINAP Usage And Synthesis |
Reactions |
- The PINAP family of P,N ligands is a synthetically more accessible but a similarly performing analog of the QUINAP (15-1777,15-1778) ligand in enantioselective hydroboration, alkyne addition, and azomethine cycloaddition reactions.
- With copper, enantioselective addition of alkynes to aldehydes to synthesize propargylamines.
- With copper, catalytic, enantioselective, conjugate alkyne addition in aqueous media.
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| (S)-(-)-4-[2-(DIPHENYLPHOSPHINO)-1-NAPHTHALENYL]-N-[-1-PHENYLETHYL]-1-PHTHALAZINAMINE,(S)-N-PINAP Preparation Products And Raw materials |
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