| | MERCURIC BROMIDE Basic information |
| | MERCURIC BROMIDE Chemical Properties |
| Melting point | 236 °C(lit.) | | Boiling point | 322 °C(lit.) | | density | 6.1 | | vapor pressure | 1 mm Hg ( 136.5 °C) | | Fp | 322-325°C subl. | | storage temp. | Poison room | | solubility | Soluble in hot alcohol, methanol, HCl, HBr | | form | beads | | Specific Gravity | 6.109 | | color | White | | Water Solubility | g/100g solution H2O: 0.3 (0°C), 0.611±0.002 (25°C), 4.7 (100°C) [KRU93]; very soluble hot alcohol, methanol, HCl, HBr; slightly soluble chloroform [MER06] | | Sensitive | Light Sensitive | | Merck | 14,5875 | | Solubility Product Constant (Ksp) | pKsp: 19.21 | | Stability: | Stable, but may be light sensitive. Incompatible with potassium and sodium. | | CAS DataBase Reference | 7789-47-1(CAS DataBase Reference) | | EPA Substance Registry System | Mercury bromide (HgBr2) (7789-47-1) |
| | MERCURIC BROMIDE Usage And Synthesis |
| Description | Mercuric Bromide is a crystalline solid. Molecular weight= 360.41;Boiling point=322℃; Freezing/Melting point=236℃. Hazard Identification (based on NFPA-704 M Rating System): Health 3, Flammability 0, Reactivity 0. Slightly soluble in water. | | Chemical Properties | white crystalline powder | | Chemical Properties | Mercuric Bromide is a crystalline solid | | Uses | Medicine. | | Uses | Mercury(II) bromide is used as a reagent in the Koenigs-Knorr reaction, which forms glycoside linkages on carbohydrates. It is also used to test for the presence of arsenic, as recommended by the Pharmacopoeia. | | Definition | ChEBI: Mercury dibromide is a mercury coordination entity composed of mercury and bromine with the formula HgBr2. | | General Description | White rhombic crystals. Sensitive to light. Slightly soluble in water and denser than water. Severely toxic by inhalation and ingestion. | | Air & Water Reactions | Slightly soluble in water. | | Reactivity Profile | MERCURIC BROMIDE is incompatible with acetylene, ammonia, chlorine dioxide, azides, calcium (amalgam formation), sodium carbide, lithium, rubidium, copper . Reacts with sodium azide to give mercury(II) azide, which is sensitive to shock, friction, and heat. Mixing with hydrazine salts in basic solution produced a heat or shock sensitive yellow precipitate [Annalen, 1899, 305, 191]. Reacts violently with chlorine trifluoride *with ignition often occurring. | | Hazard | Toxic by inhalation, ingestion, and skin
absorption; strong irritant. | | Health Hazard | TOXIC; inhalation, ingestion or skin contact with material may cause severe injury or death. Contact with molten substance may cause severe burns to skin and eyes. Avoid any skin contact. Effects of contact or inhalation may be delayed. Fire may produce irritating, corrosive and/or toxic gases. Runoff from fire control or dilution water may be corrosive and/or toxic and cause pollution. | | Fire Hazard | Non-combustible, substance itself does not burn but may decompose upon heating to produce corrosive and/or toxic fumes. Some are oxidizers and may ignite combustibles (wood, paper, oil, clothing, etc.). Contact with metals may evolve flammable hydrogen gas. Containers may explode when heated. | | Safety Profile | A poison by ingestion,
skin contact, and intraperitoneal routes.
Vigorous reaction with indium at 35OC.
Incompatible with sodmm and potassium.
When heated to decomposition it emits very
toxic fumes of Brand Hg. See also
MERCURY COMPOUNDS and
BROMIDES. | | Synthesis | Five parts of Hg are covered with 60 parts of H2O and allowed
to react at 50 °C (vigorous stirring) with four parts of Br2 , which
is added dropwise as long as no permanent color is formed. The
solution is then brought to a boil, filtered hot, and placed in an ice
bath to induce crystallization. The salt is dried at as low a
temperature as possible. Purification is by careful double or triple
sublimation from a porcelain dish heated on a sand bath and
covered with a Petri dish. When very high purity is required
(e.g., for conductivity measurements), it may be necessary to re -
peat the sublimation several times more.
Hg + Br2 = HgBr2
| | Potential Exposure | This compound has applications in
medicine. | | First aid | If this chemical gets into the eyes, remove any contact lenses at once and irrigate immediately for at least 15 min, occasionally lifting upper and lower lids. Seek medical attention immediately. If this chemical contacts the skin, remove contaminated clothing and wash immediately with soap and water. Seek medical attention immediately. If this chemical has been inhaled, remove from exposure, begin rescue breathing (using universal precautions, including resuscitation mask) if breathing has stopped and CPR if heart action has stopped. Transfer promptly to a medical Mercuric bromide 1683 facility. When this chemical has been swallowed, get medical attention. Give large quantities of water and induce vomiting. Do not make an unconscious person vomit. Medical observation is recommended for 2448 h after breathing overexposure, as pulmonary edema may be delayed. As first aid for pulmonary edema, a doctor or authorized paramedic may consider administering a corticosteroid spray. Antidotes and special procedures for medical personnel: The drug NAP (n-acetyl penicillamine) has been used to treat mercury poisoning, with mixed success. Note to physician: For severe poisoning BAL [British AntiLewisite, dimercaprol, dithiopropanol (C3H8OS2)] has been used to treat toxic symptoms of certain heavy metals poisoning including mercury. Although BAL is reported to have a large margin of safety, caution must be exercised, because toxic effects may be caused by excessive dosage. Most can be prevented by premedication with 1-ephedrine sulfate (CAS: 134-72-5). | | storage | Color Code—Blue: Health Hazard/Poison: Store in a secure poison location. Prior to working with this chemical you should be trained on its proper handling and 1684 Mercuric bromide storage. Store in tightly closed containers in a cool, wellventilated area away from light, heat, and acids. Mercuric bromide must be stored to avoid contact with sodium and potassium, since violent reactions occur. | | Shipping | UN1634 Mercuric bromides, Hazard Class: 6.1;
Labels: 6.1-Poisonous materials | | Purification Methods | Crystallise it from hot saturated ethanolic solution, dry and keep it at 100o for several hours under a vacuum, then sublime it. [Garrett J Am Chem Soc 61 2744 1939.] Its solubility in H2O is 0.6% at 20o, and 22% at 100o; in EtOH it is 30% at 25o; and in MeOH it is 69.6% at 25o. [Wagenknecht & Juza Handbook of Preparative Inorganic Chemistry (Ed. Brauer) Academic Press Vol II p 1109 1965.] POISONOUS. | | Incompatibilities | Violent reaction with active metals;
potassium, sodium. Store away from heat and light |
| | MERCURIC BROMIDE Preparation Products And Raw materials |
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